Chemistry: Principles and Reactions8th EditionWilliam L. Masterton, Cecile N. Hurley Publisher: Cengage LearningISBN: 9781305079373
Chemistry: Principles and Reactions
Solutions for Chemistry: Principles and Reactions
Problem 1QAP:
One chocolate chip used in making chocolate chip cookies has a mass of 0.324 g. (a) How many...Problem 2QAP:
The meat from one hazelnut has a mass of 0.985 g. (a) What is the mass of a millionth of a mole...Problem 3QAP:
Determine (a) the mass of 0.429 mol of gold. (b) the number of atoms in 0.715 g of gold. (c) the...Problem 5QAP:
A cube of sodium has length 1.25 in. How many atoms are in that cube? (Note: dNa=0.968g/cm3.)Problem 7QAP:
Calculate the molar masses (in grams per mole) of (a) cane sugar, C12H22O11. (b) laughing gas, N2O....Problem 8QAP:
Calculate the molar mass (in grams/mol) of (a) osmium metal, the densest naturally occurring...Problem 9QAP:
Convert the following to moles. (a) 4.00103g of hydrazine, a rocket propellant (b) 12.5 g of tin(II)...Problem 10QAP:
Convert to moles. (a) 128.3 g of sucralose, C12H19O8Cl3, the active ingredient of the artificial...Problem 11QAP:
Calculate the mass in grams of 3.839 moles of (a) hydrazine, a rocket propellant. (b) caffeine,...Problem 12QAP:
Calculate the mass in grams of 1.35 mol of (a) titanium white, TiO2, used as a paint pigment. (b)...Problem 14QAP:
Complete the following table for citric acid, C6H8O7, the acid found in many citrus fruits.Problem 15QAP:
Household ammonia used for cleaning contains about 10 g (two significant figures) of NH3 in 100 mL...Problem 17QAP:
What is the molarity of each ion present in aqueous solutions of the following compounds prepared by...Problem 18QAP:
What is the molarity of each ion present in aqueous solutions of the following compounds prepared by...Problem 19QAP:
How would you prepare from the solid and pure water (a) 0.400 L of 0.155 M Sr(OH)2? (b) 1.75 L of...Problem 20QAP:
Starting with the solid and adding water, how would you prepare 2.00 L of 0.685 M (a) Ni(NO3)2? (b)...Problem 21QAP:
You are asked to prepare a 0.8500 M solution of aluminum nitrate. You find that you have only 50.00...Problem 22QAP:
An experiment calls for a 0.4500 M solution of aluminum carbonate. The storeroom has only 32.00 g of...Problem 24QAP:
Twenty-five mL of a 0.388 M solution of Na2SO4 is mixed with 35.3 mL of 0.229 M Na2SO4. What is the...Problem 25QAP:
Turquoise has the following chemical formula: CuAl6(PO4)4(OH)84H2O. Calculate the mass percent of...Problem 26QAP:
Diazepam is the addictive tranquilizer also known as Valium®. Its simplest formula is C16H13N2OCl....Problem 27QAP:
Small amounts of tungsten (W) are usually added to steel to strengthen and harden the steel. Two...Problem 28QAP:
Allicin is responsible for the distinctive taste and odor of garlic. Its simple formula is C6H10O2S....Problem 29QAP:
The active ingredient in Pepto-Bismo® (an over- the-counter remedy for an upset stomach) is bismuth...Problem 30QAP:
The active ingredient in some antiperspirants is aluminum chlorohydrate, Al2(OH)5Cl. Analysis of a...Problem 31QAP:
Combustion analysis of 1.00 g of the male sex hormone, testosterone, yields 2.90 g of CO2 and 0.875...Problem 32QAP:
Hexachlorophene, a compound made up of atoms of carbon, hydrogen, chlorine, and oxygen, is an...Problem 33QAP:
A compound NiX3 is 19.67% (by mass) nickel. What is the molar mass of the compound? What is the name...Problem 34QAP:
A compound R2O3 is 32.0% oxygen. What is the molar mass of R2O3? What is the element represented by...Problem 35QAP:
Manganese reacts with fluorine to form a fluoride. If 1.873 g of manganese reacts with enough...Problem 36QAP:
Nickel reacts with sulfur to form a sulfide. If 2.986 g of nickel reacts with enough sulfur to form...Problem 37QAP:
Determine the simplest formulas of the following compounds: (a) the food enhancer monosodium...Problem 38QAP:
Determine the simplest formulas of the following compounds: (a) tetraethyl lead, the banned gasoline...Problem 39QAP:
Nicotine is found in tobacco leaf and is mainly responsible for the addictive property of cigarette...Problem 41QAP:
Beta-blockers are a class of drug widely used to manage hypertension. Atenolol, a beta-blocker, is...Problem 42QAP:
Saccharin is the active ingredient in many sweeteners used today. It is made up of carbon, hydrogen,...Problem 43QAP:
Hexamethylenediamine (MM=116.2g/mol), a compound made up of carbon, hydrogen, and nitrogen atoms, is...Problem 45QAP:
Epsom salts are hydrated crystals of magnesium sulfate, MgSO4xH2O.When 6.499 g of Epsom salts are...Problem 46QAP:
Sodium borate decahydrate, Na2B4O710H2O is commonly known as borax. It is used as a deodorizer and...Problem 49QAP:
Write balanced equations for the reaction of sulfur with the following metals to form solids that...Problem 50QAP:
Write balanced equations for the reaction of scandium metal to produce the scandium(III) salt with...Problem 51QAP:
Write a balanced equation for (a) the combustion (reaction with oxygen gas) of glucose, C6H12O6, to...Problem 52QAP:
Write a balanced equation for the reaction between (a) dihydrogen sulfide and sulfur dioxide gases...Problem 53QAP:
Cyanogen gas, C2N2, has been found in the gases of outer space. It can react with fluorine to form...Problem 55QAP:
One way to remove nitrogen oxide (NO) from smoke-stack emissions is to react it with ammonia....Problem 56QAP:
Phosphine gas reacts with oxygen according to the following equation: 4PH3(g)+8O2(g)P4O10(s)+6H2O(g)...Problem 57QAP:
The combustion of liquid chloroethylene, C2H3Cl, yields carbon dioxide, steam, and hydrogen chloride...Problem 58QAP:
Sand is mainly silicon dioxide. When sand is heated with an excess of coke (carbon), pure silicon...Problem 59QAP:
When copper(II) oxide is heated in hydrogen gas, the following reaction takes place....Problem 62QAP:
When corn is allowed to ferment, the fructose in the corn is converted to ethyl alcohol according to...Problem 63QAP:
Consider the hypothetical reaction 8A2B3(s)+3X4(g)4A4X3(s)+12B2(g)When 10.0 g of A2B3(MM=225g/mol)...Problem 64QAP:
Consider the hypothetical reaction 2R2X5+2Z85X2+4RZ4When 25.00 g of Z8(MM=197.4g/mol)react with an...Problem 65QAP:
When solid phosphorus (P4) reacts with oxygen gas, diphosphorus pentoxide is formed. Initially 2.87...Problem 66QAP:
Chlorine and fluorine react to form gaseous chlorine trifluoride. Initially, 1.75 mol of chlorine...Problem 67QAP:
When potassium chlorate is subjected to high temperatures, it decomposes into potassium chloride and...Problem 68QAP:
When iron and steam react at high temperatures, the following reaction takes place....Problem 69QAP:
When solid silicon tetrachloride reacts with water, solid silicon dioxide and hydrogen chloride gas...Problem 70QAP:
The first step in the manufacture of nitric acid by the Ostwald process is the reaction of ammonia...Problem 71QAP:
Tin(IV) chloride is used as an external coating on glass to toughen glass containers. It is prepared...Problem 72QAP:
A student prepares phosphorous acid, H3PO3, by reacting solid phosphorus triiodide with water....Problem 73QAP:
Cisplatin, Pt(NH3)2Cl2, is a chemotherapeutic agent that disrupts the growth of DNA. If the current...Problem 74QAP:
Magnesium ribbon reacts with acid to produce hydro- gen gas and magnesium ions. Different masses of...Problem 75QAP:
Iron reacts with oxygen. Different masses of iron are burned in a constant amount of oxygen. The...Problem 76QAP:
Acetic acid (HC2H3O2) can be prepared by the action of the acetobacter organism on dilute solutions...Problem 78QAP:
The reaction between compounds made up of A (squares), B (circles), and C (triangles) is shown...Problem 79QAP:
Represent the following equation pictorially (see Problem 78), using squares to represent A, circles...Problem 80QAP:
Nitrogen reacts with hydrogen to form ammonia. Represent each nitrogen atom by a square and each...Problem 81QAP:
Consider the following diagram, where atom X is represented by a square and atom Y is represented by...Problem 82QAP:
Box A contains 36 atoms of arsenic (As) and 27 molecules of O2. Box B contains 18 molecules of...Problem 83QAP:
One mol of ammonia reacts with 1.00 mol of oxygen to form nitrogen oxide and water according to the...Problem 84QAP:
Suppose that the atomic mass of C-12 is taken to be 5.000 amu and that a mole is defined as the...Problem 85QAP:
Suppose that Si28(1428Si) is taken as the standard for expressing atomic masses and assigned an...Problem 86QAP:
Answer the questions below, using LT (for is less than), GT (for is greater than), EQ (for is equal...Problem 87QAP:
Determine whether the statements given below are true or false. (a) The mass of an atom can have the...Problem 88QAP:
Chlorophyll, the substance responsible for the green color of leaves, has one magnesium atom per...Problem 89QAP:
By x-ray diffraction it is possible to determine the geometric pattern in which atoms are arranged...Problem 90QAP:
A 5.025-g sample of calcium is burned in air to produce a mixture of two ionic compounds, calcium...Problem 91QAP:
A mixture of potassium chloride and potassium bromide weighing 3.595 g is heated with chlorine,...Problem 92QAP:
A sample of an oxide of vanadium weighing 4.589 g was heated with hydrogen gas to form water and...Problem 93QAP:
A sample of cocaine, C17H21O4N, is diluted with sugar, C12H22O11. When a 1.00-mg sample of this...Browse All Chapters of This Textbook
Chapter 1 - Matter And MeasurementsChapter 2 - Atoms, Molecules, And IonsChapter 3 - Mass Relations In Chemistry; StoichiometryChapter 4 - Reactions In Aqueous SolutionChapter 5 - GasesChapter 6 - Electronic Structure And The Periodic TableChapter 7 - Covalent BondingChapter 8 - ThermochemistryChapter 9 - Liquids And SolidsChapter 10 - Solutions
Chapter 11 - Rate Of ReactionChapter 12 - Gaseous Chemical EquilibriumChapter 13 - Acids And BasesChapter 14 - Equilibria In Acid-base SolutionsChapter 15 - Complex Ion And Precipitation EquilibriaChapter 16 - Spontaneity Of ReactionChapter 17 - ElectrochemistryChapter 18 - Nuclear ReactionsChapter 19 - Complex IonsChapter 20 - Chemistry Of The MetalsChapter 21 - Chemistry Of The NonmetalsChapter 22 - Organic ChemistryChapter 23 - Organic Polymers, Natural And Synthetic
Book Details
Discover all of the fundamental topics of general chemistry with this brief, reader-oriented book. Chemistry: Principles and Reactions, 8e, provides a clear, concise presentation based on the authors' more than 50 years of combined teaching experience. The book includes graded and concept-driven examples as well as examples that focus on molecular reasoning and understanding, as well as "Chemistry: Beyond the Classroom" essays that demonstrate the relevance of the concepts and highlight some of the most up-to-date uses of chemistry. A strong, enhanced art program helps readers visualize chemical concepts. Integrated end-of-chapter questions and Key Concepts correlate to OWLv2, the number 1 online homework and tutorial system for chemistry.
Sample Solutions for this Textbook
We offer sample solutions for Chemistry: Principles and Reactions homework problems. See examples below:
Chapter 1, Problem 1QAPChapter 1, Problem 27QAPChapter 1, Problem 28QAPChapter 2, Problem 1QAPChapter 2, Problem 27QAPChapter 2, Problem 28QAPChapter 2, Problem 36QAPChapter 2, Problem 37QAPChapter 2, Problem 38QAP
Given structural formula- In above structural formula, CH3 group is attached with acetic acid group...Methane is a member of Alkane family that has only 1 carbon atom and general formula for molecular...Chemical name of molecule = silicon disulfide In this chemical compound: Least electronegative atom...Potassium and strontium are metals. Potassium is present in group 1 known as alkali metal group in...Chapter 3, Problem 1QAPChapter 3, Problem 13QAPChapter 3, Problem 18QAPChapter 3, Problem 25QAPChapter 3, Problem 47QAPChapter 3, Problem 48QAPChapter 3, Problem 51QAPChapter 3, Problem 52QAPChapter 3, Problem 74QAPChapter 3, Problem 94QAPChapter 4, Problem 1QAPChapter 4, Problem 7QAPChapter 4, Problem 8QAPChapter 4, Problem 9QAPChapter 4, Problem 10QAPChapter 4, Problem 63QAPChapter 4, Problem 74QAPVolume of a gas in a container is equal to the volume of the container. Conversion factor for gallon...The force exerted by gas over a unit surface of area is called pressure of gas. The expression of...As per the given table we have to find the moles and grams of propane gas. First let us calculate...The gas 1 is taken as CO2 and gas 2 as H2 . For both the gases pressure, volume and temperatures are...Below is the expression of ideal gas equation: PV = nRT .......... (1) Here, volume i.e. V, pressure...The gas present in bulb A is N2 and bulb is NH3 . The moles of N2 and NH3 is 1 mol each. In both...Chapter 5, Problem 86QAPThe given tanks are as follows: Here, circles represent CH4 gas, square represents oxygen and...The pressure, volume and temperature of both tanks A and B is 1.38 atm, 750 ml or 0.750 L, and 25 0C...By burning sulfur with oxygen sulfur trioxide can be prepared 2S(s) + 3O2(g) → 2SO3(g) In the 5 g of...Chapter 6, Problem 1QAPChapter 6, Problem 27QAPChapter 6, Problem 28QAPChapter 6, Problem 39QAPChapter 6, Problem 40QAPChapter 6, Problem 42QAPChapter 6, Problem 49QAPChapter 6, Problem 50QAPChapter 6, Problem 67QAPCalculate the total number of valence electrons in molecule CCl4: Total number of valence electrons...Chapter 7, Problem 4QAPChapter 7, Problem 5QAPChapter 7, Problem 6QAPGiven Information: The molecule is Cl2. Here thetotal valence electrons are: 2×7(Cl)=14 and the...Given Information: The ion is BrO-. Here, the total valence electrons are: 7(Br)+6(O)+1(charge)=14....Chapter 7, Problem 17QAPChapter 7, Problem 18QAPChapter 8, Problem 1QAPChapter 8, Problem 5QAPChapter 8, Problem 6QAPChapter 8, Problem 16QAPChapter 8, Problem 35QAPChapter 8, Problem 43QAPChapter 8, Problem 44QAPChapter 8, Problem 72QAPChapter 8, Problem 76QAPChapter 8, Problem 87QAPGiven: P1 = 254 mm Hg T1 = 57 0C = (57+273) K = 330 K T2 = 35 0C = (35+273) K = 308 K and T2 = 45 0C...Chapter 9, Problem 3QAPGiven Information: The phase diagram of compound X is as follows: The triple point is defined as the...Chapter 9, Problem 18QAPNitrogen monoxide ( NO ) The number of valence electrons of both species. Nitrogen (N) has 5 valence...Chapter 9, Problem 61QAPGiven: The volume of one atom is 43πr3 and the volume of the cell is s3. The percentage of the total...Given: Volume = 10.0 L Mass of hydrogen gas = 0.400 g Mass of oxygen gas = 3.2 g Reaction:...Chapter 9, Problem 78QAPChapter 10, Problem 1QAPChapter 10, Problem 9QAPChapter 10, Problem 10QAPChapter 10, Problem 17QAPChapter 10, Problem 18QAPChapter 10, Problem 33QAPChapter 10, Problem 34QAPGiven, Temperature =22 °C Convert temperature from Celsius to Kelvin as follows: T=(22+273) K=295 K...Chapter 10, Problem 40QAPChapter 11, Problem 1QAPChapter 11, Problem 17QAPChapter 11, Problem 19QAPChapter 11, Problem 20QAPChapter 11, Problem 21QAPChapter 11, Problem 22QAPChapter 11, Problem 25QAPChapter 11, Problem 26QAPChapter 11, Problem 27QAPChapter 11, Problem 28QAPGiven Information: Here the chemical reaction is: 2NO(g) + O2(g) → 2NO2(g) Experiment No....Chapter 12, Problem 1QAPThe reaction of the system is as follows: 2A(g)+B(g)→3C(g) The given incomplete data is as follows:...Chapter 12, Problem 10QAPChapter 12, Problem 11QAPChapter 12, Problem 12QAPChapter 12, Problem 14QAPChapter 12, Problem 16QAPChapter 12, Problem 69QAPChapter 12, Problem 71QAPChapter 13, Problem 1QAPChapter 13, Problem 9QAPThe given species is Zn(H2O)3OH+. On reaction with water, it can act as an acid by donating hydrogen...The given species is (CH3)3N. On reaction with water, it can act as a base by accepting hydrogen ion...Chapter 13, Problem 51QAPChapter 13, Problem 52QAPChapter 13, Problem 59QAPChapter 13, Problem 61QAPChapter 13, Problem 62QAPChapter 13, Problem 67QAPChapter 13, Problem 74QAPChapter 13, Problem 98QAPChapter 14, Problem 1QAPChapter 14, Problem 6QAPChapter 14, Problem 9QAPChapter 14, Problem 10QAPChapter 14, Problem 32QAPChapter 14, Problem 34QAPChapter 14, Problem 36QAPChapter 14, Problem 50QAPChapter 14, Problem 74QAPChapter 15, Problem 1QAPChapter 15, Problem 32QAPChapter 15, Problem 34QAPChapter 15, Problem 55QAPThe equation of reaction of iron (II) sulfate with barium hydroxide is shown as follows:...Reason for correct option/s: b. The equation of Ag(NH3)2+ with strong acid is- Ag(NH3)2+(aq)+2H+(aq)...The equilibrium reaction of Mg(OH)2 is as follows: Mg(OH)2(s)⇌Mg2+(aq)+2OH−. The solubility product...Given the reaction is as follows: Zn(NH3)42+(aq)+4OH−(aq)⇌ Zn(OH)42−(aq)+4NH3(aq) For this reaction...Chapter 16, Problem 1QAPChapter 16, Problem 17QAPGiven process is: 4NH3 (g)+5O2(g)→4NO(g)+6H2O(g) The mathematical expression for the standard...Chapter 16, Problem 20QAPGiven process is: 2Cr (s)+3CO2(g)→Cr2O3(s)+3CO(g) The mathematical expression for the standard...Given process is: 2HNO3(l)+3H2S(g)→4H2O(l) + 2NO(g)+3S(s) The mathematical expression for the...Chapter 16, Problem 25QAPChapter 16, Problem 26QAPThe chemical equation corresponding to the reaction between iron ore and hydrogen is given as:...The given reaction is: MnO2(s) ⇌ Mn(s) + O2(g) For the above reaction, the ΔG0 value can be deduced...Given: ΔHf0(H2SO4) = -902.9 kJS0(H2SO4) = 17.14 J/K The dissociation of H2 SO4 can be expressed as...Chapter 17, Problem 1QAPChapter 17, Problem 5QAPChapter 17, Problem 6QAPSO2(g) + I2(aq)→SO3(g) + I-(aq) Determining the oxidation numbers: The oxidation number of I in I2...Chapter 17, Problem 8QAPChapter 17, Problem 9QAPChapter 17, Problem 37QAPChapter 17, Problem 39QAPChapter 17, Problem 73QAPChapter 17, Problem 74QAPChapter 17, Problem 100QAPChapter 18, Problem 1QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Chapter 18, Problem 19QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Given information: Half-life of uranium = 7×108 years The given equation is:...In the given compound, [Fe(C2O4)2(NH3)Cl3-] Oxalate is denoted by the symbol ‘ox’ and its chemical...A ligand is an atom or a group of atoms or an anion having an unshared pair of electrons and thus it...A ligand is an atom or a group of atoms or an anion that has an unshared pair of electrons and thus...Cadmium is a 4d transition metal element and its atomic number is 48. Its electronic configuration...Chapter 19, Problem 41QAPIn case of transition metal cations, the electrons that are present beyond the noble gas are in...Chapter 20, Problem 1QAPChapter 20, Problem 23QAPChapter 20, Problem 24QAPChapter 20, Problem 39QAPGiven Information: (1) A solution of potassium dichromate is made basic with sodium hydroxide. The...The compound has three elements and anion is periodate ion that is, IO4− because in naming of acid...The reaction of sulphate ion (SO42−) to form sulfur dioxide is as follows: SO42−(aq)⇌SO2(g) Balance...Iodine is oxidized to iodate. I2(s)⇌IO3−(aq) Balance the above reaction. Balance all atoms except...Chapter 21, Problem 18QAPAt 25°C, reaction of bromine is: Br2(I)+H2O ⇌ H+(aq)+Br−(aq)+HBrO(aq) Initial concentration: C 0 0 0...Chapter 21, Problem 53QAPChapter 21, Problem 61QAPBalance the reaction as follows: Consider oxidation and reduction reaction separately as given...Chapter 22, Problem 1QAPChapter 22, Problem 25QAPChapter 22, Problem 26QAPChapter 22, Problem 27QAPChapter 22, Problem 28QAPThe dissolved hydrochloric acid first dissociates into its ionic forms under the aqueous medium as...Chapter 22, Problem 60QAPTetrachloroethylene polymer consists of number of monomer unit of 1,1,2,2-tetrachloroethylene. The...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...Cellulose is a polyssaccharide which consists of several units of glucose joined through glycosidic...Chapter 23, Problem 29QAPThe given amino acid is alanine which has the following structure: The structures of the respective...
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