Pearson eText Organic Chemistry -- Inst...8th EditionPaula Bruice Publisher: PEARSON+ISBN: 9780135213711
Pearson eText Organic Chemistry -- Inst...
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Chapter 1 - Remembering General Chemistry: Electronic Structure And BondingChapter 1.1 - The Structure Of An AtomChapter 1.2 - How The Electrons In An Atom Are DistributedChapter 1.3 - Covalent BondsChapter 1.4 - How The Structure Of A Compound Is RepresentedChapter 1.5 - Atomic OrbitalsChapter 1.6 - An Introduction To Molecular Orbital TheoryChapter 1.7 - How Single Bonds Are Formed In Organic CompoundsChapter 1.9 - How A Triple Bond Is Formed: The Bonds In EthyneChapter 1.11 - The Bonds In Ammonia And In The Ammonium Ion
Chapter 1.12 - The Bonds In WaterChapter 1.13 - The Bond In A Hydrogen HalideChapter 1.14 - Hybridization And Molecular GeometryChapter 1.15 - Summary: Hybridization, Bond Lengths, Bond Strengths, And Bond AnglesChapter 1.16 - Dipole Moments Of MoleculesChapter 2 - Acids And Bases: Central To Understanding Organic ChemistryChapter 2.1 - An Introduction To Acids And BasesChapter 2.2 - Pka And PhChapter 2.3 - Organic Acids And BasesChapter 2.4 - How To Predict The Outcome Of An Acid-base ReactionChapter 2.5 - How To Determine The Position Of EquilibriumChapter 2.6 - How The Structure Of An Acid Affects Its Pka ValueChapter 2.7 - How Substituents Affect The Strength Of An AcidChapter 2.8 - An Introduction To Delocalized ElectronsChapter 2.9 - A Summary Of The Factors That Determine Acid StrengthChapter 2.10 - How Ph Affects The Structure Of An Organic CompoundChapter 2.11 - Buffer SolutionsChapter 2.12 - Lewis Acids And BasesChapter 3 - An Introduction To Organic Compounds: Nomenclature, Physical Properties, And StructureChapter 3.1 - Alkyl GroupsChapter 3.2 - The Nomenclature Of AlkanesChapter 3.3 - The Nomenclature Of CycloalkanesChapter 3.4 - The Nomenclature Of Alkyl HalidesChapter 3.5 - The Nomenclature Of EthersChapter 3.6 - The Nomenclature Of AlcoholsChapter 3.7 - The Nomenclature Of AminesChapter 3.8 - The Structures Of Alkyl Halides, Alcohols, Ethers, And AminesChapter 3.9 - Noncovalent InteractionsChapter 3.10 - The Solubility Of Organic CompoundsChapter 3.11 - Rotation Occurs About Carbon-carbon Single BondsChapter 3.12 - Some Cycloalkanes Have Angle StrainChapter 3.13 - Conformers Of CyclohexaneChapter 3.14 - Conformers Of Monosubstituted CyclohexanesChapter 3.15 - Conformers Of Disubstituted CyclohexanesChapter 4 - Isomers: The Arrangement Of Atoms In SpaceChapter 4.1 - Cis-trans Isomers Result From Restricted RotationChapter 4.2 - Using The E,z System To Distinguish IsomersChapter 4.3 - A Chiral Object Has A Nonsuperimposable Mirror ImageChapter 4.4 - An Asymmetric Center Is A Cause Of Chirality In A MoleculeChapter 4.5 - Isomers With One Asymmetric CenterChapter 4.6 - Asymmetric Centers And StereocentersChapter 4.7 - How To Draw EnantiomersChapter 4.8 - Naming Enantiomers By The R,s SystemChapter 4.9 - Chiral Compounds Are Optically ActiveChapter 4.10 - How Specific Rotation Is MeasuredChapter 4.11 - Enantiomeric ExcessChapter 4.12 - Compounds With More Than One Asymmetric CenterChapter 4.13 - Stereoisomers Of Cyclic CompoundsChapter 4.14 - Meso Compounds Have Asymmetric Centers But Are Optically InactiveChapter 4.15 - How To Name Isomers With More Than One Asymmetric CenterChapter 4.16 - Nitrogen And Phosphorous Atoms Can Be Asymmetric CentersChapter 4.17 - ReceptorsChapter 5 - Alkenes: Structure, Nomenclature, And An Introduction To Reactivity - Thermodynamics And KineticsChapter 5.1 - Molecular Formulas And The Degree Of UnsaturationChapter 5.2 - The Nomenclature Of AlkenesChapter 5.3 - The Structure Of AlkenesChapter 5.5 - How Alkenes React • Curved Arrows Show The Flow Of ElectronsChapter 5.6 - Thermodynamics: How Much Product Is Formed?Chapter 5.8 - Calculating ??° ValuesChapter 5.9 - Using ??° Values To Determine The Relative Stabilities Of AlkenesChapter 5.10 - Kinetics: How Fast Is The Product Formed?Chapter 5.11 - The Rate Of A Chemical ReactionChapter 5.12 - A Reaction Coordinate Diagram Describes The Energy Changes That Take Place During A ReactionChapter 5.13 - CatalysisChapter 6 - The Reaction Of Alkenes • The Stereochemistry Of Addition ReactionsChapter 6.1 - The Addition Of A Hydrogen Halide To An AlkeneChapter 6.2 - Carbocation Stability Depends On The Number Of Alkyl Groups Attached To The Positively Charged CarbonChapter 6.3 - What Does The Structure Of The Transition State Look Like?Chapter 6.4 - Electrphilic Addition Reactions Are RegioselectiveChapter 6.5 - The Addition Of Water To An AlkeneChapter 6.6 - The Addition Of An Alcohol To An AlkeneChapter 6.7 - A Carbocation Will Rearrange If It Can Form A More Stable CarbocationChapter 6.8 - The Addition Of Borane To An Alkene: Hydroboration-oxidationChapter 6.9 - The Addition Of A Halogen To An AlkeneChapter 6.10 - The Addition Of A Peroxyacid To An AlkeneChapter 6.11 - The Addition Of Ozone To An Alkene: OzonolysisChapter 6.12 - Regioselective, Stereoselective, And Stereospecific ReactionsChapter 6.13 - The Stereochemistry Of Electrophilic Addition ReactionsChapter 6.14 - The Stereochemistry Of Enzyme-catalyzed ReactionsChapter 6.16 - Reactions And SynthesisChapter 7 - The Reaction Of Alkynes • An Introduction To Multistep SynthesisChapter 7.1 - The Nomenclature Of AlkynesChapter 7.2 - How To Name A Compound That Has More Than One Functional GroupChapter 7.3 - The Structure Of AlkynesChapter 7.4 - The Physical Properties Of Unsaturated HydrocarbonsChapter 7.6 - The Addition Of Hydrogen Halides And The Addition Of Halogens To An AlkyneChapter 7.7 - The Addition Of Water To An AlkyneChapter 7.8 - The Addition Of Borane To An Alkyne: Hydroboration-oxidationChapter 7.9 - The Addition Of Hydrogen To An AlkyneChapter 7.10 - A Hydrogen Bonded To An Sp Carbon Is "acidic"Chapter 7.12 - Designing A Synthesis I: An Introduction To Multistep SynthesisChapter 8 - Delocalized Electrons: Their Effect On Stability, Pka, And The Products Of A Reaction • Aromaticity And Electronic Effects: An Introduction To The Reactions Of BenzeneChapter 8.1 - Delocalized Electrons Explain Benzene's StructureChapter 8.4 - How To Draw Resonance ContributorsChapter 8.5 - The Predicted Stabilities Of Resonance ContributorsChapter 8.6 - Delocalization Energy Is The Additional Stability Delocalized Electrons Give To A CompoundChapter 8.7 - Delocalized Electrons Increase StabilityChapter 8.8 - A Molecular Orbital Description Of StabilityChapter 8.9 - Delocalized Electrons Affect Pka ValuesChapter 8.10 - Electronic EffectsChapter 8.11 - Delocalized Electrons Can Affect The Product Of A ReactionChapter 8.12 - Reactions Of DienesChapter 8.13 - Thermodynamic Versus Kinetic ControlChapter 8.14 - The Diels-alder Reaction Is A 1,4-addition ReactionChapter 8.15 - Retrosynthetic Analysis Of The Diels-alder ReactionChapter 8.17 - The Two Criteria For AromaticityChapter 8.18 - Applying The Criteria For AromaticityChapter 8.19 - A Molecular Orbital Description Of AromaticityChapter 8.20 - Aromatic Heterocyclic CompoundsChapter 9 - Substitution And Elimination Reactions Of Alkyl HalidesChapter 9.1 - The Sn2 ReactionChapter 9.2 - Factors That Affect Sn2 ReactionsChapter 9.3 - The Sn1 ReactionChapter 9.4 - Factors That Affect Sn1 ReactionsChapter 9.5 - Competition Between Sn2 And Sn1 ReactionsChapter 9.7 - The E2 ReactionChapter 9.8 - The E1 ReactionChapter 9.9 - Competition Between E2 And E1 ReactionsChapter 9.10 - E2 And E1 Reactions Are StereoselectiveChapter 9.11 - Elimination From Substituted CyclohexanesChapter 9.12 - Predicting The Products Of The Reaction Of An Alkyl Halide With A Nucleophile/baseChapter 9.13 - Benzylic Halides, Allylic Halides, Vinylic Halides, And Aryl HalidesChapter 9.14 - Solvent EffectsChapter 9.15 - Substitution And Elimination Reactions In SynthesisChapter 9.16 - Intermolecular Versus Intramolecular ReactionsChapter 9.17 - Designing A Synthesis Ii: Approaching The ProblemChapter 10 - Reactions Of Alcohols, Ethers, Epoxides, Amines, And Sulfur-containing CompoundsChapter 10.1 - Nucleophilic Substitution Reactions Of Alcohols: Forming Alkyl HalidesChapter 10.2 - Other Methods Used To Convert Alcohols Into Alkyl HalidesChapter 10.3 - Converting An Alcohol Into A Sulfonate EsterChapter 10.4 - Elimination Reactions Of Alcohols: DehydrationChapter 10.5 - Oxidation Of AlcoholsChapter 10.6 - Nucleophilic Substitution Reactions Of EthersChapter 10.7 - Nucleophilic Substitution Reactions Of EpoxidesChapter 10.8 - Arene OxidesChapter 10.9 - Amines Do Not Undergo Substitution Or Elimination ReactionsChapter 10.10 - Quaternary Ammonium Hydroxides Undergo Elimination ReactionsChapter 10.11 - Thiols, Sulfides, And Sulfonium IonsChapter 10.12 - Methylating Agents Used By Chemists Versus Those Used By CellsChapter 11 - Organometallic CompoundsChapter 11.1 - Organolithium And Organomagnesium CompoundsChapter 11.2 - TransmetallationChapter 11.3 - OrganocupratesChapter 11.4 - Palladium-catalyzed Coupling ReactionsChapter 11.5 - Alkene MetathesisChapter 12 - RadicalsChapter 12.2 - The Chlorination And Bromination Of AlkanesChapter 12.3 - Radical Stability Depends On The Number Of Alkyl Groups Attached To The Carbon With The Unpaired ElectronChapter 12.4 - The Distribution Of Products Depends On Probability And ReactivityChapter 12.5 - The Reactivity-selectivity PrincipleChapter 12.6 - Formation Of Explosive PeroxidesChapter 12.7 - The Addition Of Radicals To An AlkeneChapter 12.8 - The Stereochemistry Of Radical Substitution And Radical Addition ReactionsChapter 12.9 - Radical Substitution Of Allylic And Benzylic HydrogensChapter 12.10 - Designing A Synthesis Iii: More Practice With Multistep SynthesisChapter 12.11 - Radical Reactions In Biological SystemsChapter 13 - Mass Spectrometry; Infrared Spectroscopy; Uv/vis SpectroscopyChapter 13.1 - Mass SpectrometryChapter 13.2 - The Mass Spectrum • FragmentationChapter 13.3 - Using The M/z Value Of The Molecular Ion To Calculate The Molecular FormulaChapter 13.4 - Isotopes In Mass SpectrometryChapter 13.5 - High-resolution Mass Spectrometry Can Reveal Molecular FormulasChapter 13.6 - The Fragmentation Patterns Of Functional GroupsChapter 13.9 - Spectroscopy And The Electromagnetic SpectrumChapter 13.13 - The Position Of Absorption BandsChapter 13.14 - The Position And Shape Of An Absorption Band Is Affected By Electron Delocalization And Hydrogen BondingChapter 13.16 - The Absence Of Absorption BandsChapter 13.17 - Some Vibrations Are Infrared InactiveChapter 13.18 - How To Interpret An Infrared SpectrumChapter 13.20 - The Beer-lambert LawChapter 13.21 - The Effect Of Conjugation On ?maxChapter 13.23 - Some Uses Of Uv/vis SpectroscopyChapter 14 - Nmr SpectroscopyChapter 14.1 - An Introduction To Nmr SpectroscopyChapter 14.4 - The Number Of Signals In 1h Nmr SpectrumChapter 14.5 - The Chemical Shift Tells How Far The Signal Is From The Reference SignalChapter 14.6 - The Relative Positions Of 1h Nmr SignalsChapter 14.7 - The Characteristic Values Of Chemical ShiftsChapter 14.8 - Diamagnetic AnisotropyChapter 14.9 - The Integration Of Nmr Signals Reveals The Relative Number Of Protons Causing Each SignalChapter 14.10 - The Splitting Of Signals Is Described By The N+1 RuleChapter 14.11 - What Causes Splitting?Chapter 14.12 - More Examples Of 1h Nmr SpectraChapter 14.13 - Coupling Constants Identify Coupled ProtonsChapter 14.14 - Splitting Diagrams Explain The Multiplicity Of A SignalChapter 14.15 - Enantiotopic And Diastereotopic HydrogensChapter 14.17 - Protons Bonded To Oxygen And NitrogenChapter 14.20 - 13c Nmr SpectroscopyChapter 14.22 - Two-dimensional Nmr SpectroscopyChapter 15 - Reactions Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 15.1 - The Nomenclature Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 15.2 - The Structures Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 15.4 - How Carboxylic Acids And Carboxylic Acid Derivatives ReactChapter 15.5 - The Relative Reactivities Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 15.6 - Reactions Of Acyl ChloridesChapter 15.7 - Reactions Of EstersChapter 15.8 - Acid-catalyzed Ester Hydrolysis And TransesterificationChapter 15.9 - Hydroxide-ion-promoted Ester HydrolysisChapter 15.10 - Reactions Of Carboxylic AcidsChapter 15.11 - Reactions Of AmidesChapter 15.12 - Acid-catalyzed Amide Hydrolysis And AlcoholysisChapter 15.13 - Hydroxide-ion-promoted Hydrolysis Of AmidesChapter 15.14 - Hydrolysis Of An Imide: A Way To Synthesize A Primary AmineChapter 15.15 - NitrilesChapter 15.16 - Acid AnhydridesChapter 15.17 - Dicarboxylic AcidsChapter 15.18 - How Chemists Activate Carboxylic AcidsChapter 16 - Reactions Of Aldehydes And Ketones • More Reactions Of Carboxylic Acid DerivativesChapter 16.1 - The Nomenclature Of Aldehydes And KetonesChapter 16.2 - The Relative Reactivities Of Carbonyl CompoundsChapter 16.4 - Reactions Of Carbonyl Compounds With Carbon NucleophilesChapter 16.5 - Reactions Of Carbonyl Compounds With Hydride IonChapter 16.6 - More About Reduction ReactionsChapter 16.7 - Chemoselective ReactionsChapter 16.8 - Reactions Of Aldehydes And Ketones With Nitrogen NucleophilesChapter 16.9 - Reactions Of Aldehydes And Ketones With Oxygen NucleophilesChapter 16.10 - Protecting GroupsChapter 16.12 - Reaction Of Aldehydes And Ketones With A PeroxyacidChapter 16.13 - The Wittig Reaction Forms An AlkeneChapter 16.14 - Designing A Synthesis Iv: Disconnections, Synthons, And Synthetic EquivalentsChapter 16.15 - Nucleophilic Addition To ?,?-unsaturated Aldehydes And KetonesChapter 16.16 - Nucleophilic Addition To ?,?-unsaturated Carboxylic Acid DerivativesChapter 17 - Reactions At The ?-carbonChapter 17.1 - The Aciidity Of An ?-hydrogenChapter 17.2 - Keto-enol TautomersChapter 17.3 - Keto-enol InterconversionChapter 17.4 - Halogenation Of The ?-carbon Of Aldehydes And KetonesChapter 17.5 - Halogenation Of The ?-carbon Of Carboxylic AcidsChapter 17.6 - Forming An Enolate IonChapter 17.7 - Alkylating The ?-carbonChapter 17.8 - Alkylating And Acylating The ?-carbon Via An Enamine IntermediateChapter 17.9 - Alkylating The ?-carbonChapter 17.10 - An Aldol Addition Forms A ?-hydroxyaldehyde Or A ?-hydroxyketoneChapter 17.11 - The Dehydration Of Aldol Addition Products Forms ?,?-unsaturated Aldehydes And KetonesChapter 17.12 - A Crossed Aldol AdditionChapter 17.13 - A Claisen Condensation Forms A ?-keto EsterChapter 17.14 - Other Crossed CondensationsChapter 17.15 - Intramolecular Condensations And Intramolecular Aldol AdditionsChapter 17.16 - The Robinson AnnulationChapter 17.17 - Co2 Can Be Removed From A Carboxylic Acid That Has A Carbonyl Group At The 3-positionChapter 17.18 - The Malonic Ester Synthesis: A Way To Synthesize A Carboxylic AcidChapter 17.19 - The Acetoacetic Ester Synthesis: A Way To Synthesize A Methyl KetoneChapter 17.20 - Designing A Synthesis V: Making New Carbon-carbon BondsChapter 17.21 - Reactions At The ?-carbon In Living SystemsChapter 18 - Reactions Of Benzene And Substituted BenzenesChapter 18.1 - The Nomenclature Of Monosubstituted BenzenesChapter 18.3 - Halogenation Of BenzeneChapter 18.6 - Friedel-crafts Acylation Of BenzeneChapter 18.7 - Friedel-crafts Alkylation Of BenzeneChapter 18.9 - Using Coupling Reactions To Alkylate BenzeneChapter 18.10 - How Some Substituents On A Benzene Ring Can Be Chemically ChangedChapter 18.11 - The Nomenclature Of Disubstituted And Polysubstituted BenzenesChapter 18.12 - The Effect Of Substituents On ReactivityChapter 18.13 - The Effect Of Substituents On OrientationChapter 18.15 - Additional Considerations Regarding Substituent EffectsChapter 18.16 - Designing A Synthesis Vi: The Synthesis Of Monosubstituted And Disubstituted BenzenesChapter 18.17 - The Synthesis Of Trisubstituted BenzenesChapter 18.18 - Synthesizing Substituted Benzenes Using Arenediazonium SaltsChapter 18.19 - AzobenzenesChapter 18.20 - The Mechanism For The Formation Of A Diazonium IonChapter 18.21 - Nucleophilic Aromatic SubstitutionChapter 18.22 - Designing A Synthesis Vii: The Synthesis Of Cyclic CompoundsChapter 19 - More About Amines • Reactions Of Heterocyclic CompoundsChapter 19.1 - More About NomenclatureChapter 19.2 - More About The Acid-base Properties Of AminesChapter 19.3 - Amines React As Bases And As NucleophilesChapter 19.5 - Aromatic Five-membered-ring HeterocyclesChapter 19.6 - Aromatic Six-membered-ring HeterocyclesChapter 19.7 - Some Heterocyclic Amines Have Important Roles In NatureChapter 20 - The Organic Chemistry Of CarbohydratesChapter 20.1 - Classifying CarbohydratesChapter 20.2 - The D And L NotationChapter 20.3 - The Configurations Of AldosesChapter 20.4 - The Configurations Of KetosesChapter 20.5 - The Reactions Of Monosaccharides In Basic SolutionsChapter 20.6 - Oxidation-reduction Reactions Of MonosaccharidesChapter 20.7 - Lengthening The Chain: The Kiliani-fischer SynthesisChapter 20.8 - Shortening The Chain: The Wohl DegradationChapter 20.9 - The Stereochemistry Of Glucose: The Fischer ProofChapter 20.10 - Monosaccharides Form Cyclic HemiacetalsChapter 20.11 - Glucose Is The Most Stable AldohexoseChapter 20.12 - Formation Of GlycosidesChapter 20.14 - Reducing And Nonreducing SugarsChapter 20.15 - DisaccharidesChapter 20.16 - PolysaccharidesChapter 20.17 - Some Naturally Occuring Compounds Derived From CarbohydratesChapter 20.18 - Carbohydrates On Cell SurfacesChapter 21 - Amino Acids, Peptides, And ProteinsChapter 21.1 - The Nomenclature Of Amino AcidsChapter 21.2 - The Configuration Of Amino AcidsChapter 21.3 - Acid-base Properties Of Amino AcidsChapter 21.4 - The Isoelectric PointChapter 21.5 - Separating Amino AcidsChapter 21.6 - Synthesis Of Amiino AcidsChapter 21.7 - Resolution Of Racemic Mixtures Of Amino AcidsChapter 21.8 - Peptide Bonds And Disulfide BondsChapter 21.9 - Some Interesting PeptidesChapter 21.10 - The Strategy Of Peptide Bond Synthesis: N-protection And C-activationChapter 21.11 - Automated Peptide SynthesisChapter 21.13 - How To Determine The Primary Structure Of A Polypeptide Or A ProteinChapter 21.14 - Secondary StructureChapter 21.15 - Tertiary StructureChapter 21.16 - Quaternary StructureChapter 21.17 - Protein DenaturationChapter 22 - Catalysis In Organic Reactions And In Enzymatic ReactionsChapter 22.2 - Acid CatalysisChapter 22.3 - Base CatalysisChapter 22.5 - Metal-ion CatalysisChapter 22.6 - Intramolecular ReactionsChapter 22.7 - Intramolecular CatalysisChapter 22.9 - An Enzyme-catalyzed Reaction That Is Reminiscent Of Acid-catalyzed Amide HydrolysisChapter 22.10 - Another Enzyme-catalyzed Reaction That Is Reminiscent Of Acid-catalyzed Amide HydrolysisChapter 22.11 - An Enzyme-catalyzed Reaction That Involves Two Sequential Sn2 ReactionsChapter 22.12 - An Enzyme-catalyzed Reaction That Is Reminiscent Of The Base-catalyzed Enediol RearrangementChapter 22.13 - Another Enzyme-catalyzed Reaction That Is Reminiscent Of A Retro-aldol AdditionChapter 23 - The Organic Chemistry Of The Coenzymes, Compounds Derived From VitaminsChapter 23.1 - Niacin: The Vitamin Needed For Many Redox ReactionsChapter 23.2 - Riboflavin: Another Vitamin Used In Redox ReactionsChapter 23.3 - Vitamin B1: The Vitamin Needed For Acyl Group TransferChapter 23.5 - Vitamin B6: The Vitamin Needed For Amino Acid TransformationsChapter 23.6 - Vitamin B12: The Vitamin Needed For Certain IsomerizationsChapter 23.7 - Folic Acid: The Vitamin Needed For One-carbon TransferChapter 23.8 - Vitamin K: The Vitamin Needed For Carboxylation Of GlutamateChapter 24 - The Organic Chemistry Of The Metabolic PathwaysChapter 24.3 - The "high-energy" Character Of Phosphoanhydride BondsChapter 24.5 - The Catabolixm Of Fats: Stages 1 And 2Chapter 24.6 - The Catabolixm Of Carbohydrates: Stages 1 And 2Chapter 24.7 - The Fats Of PyruvateChapter 24.8 - The Catabolism Of Proteins: Stages 1 And 2Chapter 24.9 - The Citric Acid Cycle: Stage 3Chapter 24.10 - Oxidative Phosphorylation: Stage 4Chapter 24.12 - GluconeogenesisChapter 24.14 - Amino Acid BiosynthesisChapter 25 - The Organic Chemistry Of LipidsChapter 25.1 - Fatty Acids Are Long-chain Carboxylic AcidsChapter 25.3 - Fats And Oils Are TriglyveridesChapter 25.5 - Phospholipids Are Components Of Cell MembranesChapter 25.6 - Prostaglandins Regulate Physiological ResponsesChapter 25.7 - Terpenes Contain Carbon Atoms In Multiples Of FiveChapter 25.8 - How Terpenes Are BiosynthesizedChapter 25.9 - How Nature Synthesizes CholesterolChapter 25.10 - SteroidsChapter 26 - The Chemistry Of The Nucleic AcidsChapter 26.1 - Nucleosides And NucleotidesChapter 26.3 - The Secondary Structure Of DnaChapter 26.4 - Why Dna Does Not Have A 2'-oh GroupChapter 26.5 - The Biosynthesis Of Dna Is Called ReplicationChapter 26.7 - The Biosynthesis Of Rna Is Called TranscriptionChapter 26.9 - The Biosynthesis Of Proteins Is Called TranslationChapter 26.10 - Why Dna Contains Thymine Instead Of UracilChapter 26.12 - How The Base Sequence Of Dna Is DeterminedChapter 27 - Synthetic PolymersChapter 27.3 - Radical PolymerizationChapter 27.4 - Cationic PolymerizationChapter 27.5 - Anionic PolymerizationChapter 27.6 - Ring-opening PolymerizationChapter 27.8 - Polymerization Of DienesChapter 27.11 - Classes Of Step-growth PolymersChapter 27.12 - Physical Properties Of PolymersChapter 27.13 - Recycling PolymersChapter 28 - Pericyclic ReactionsChapter 28.1 - There Are Three Kinds Of Pericyclic ReactionsChapter 28.2 - Molecular Orbitals And Orbital SymmetryChapter 28.3 - Electrocyclic ReactionsChapter 28.4 - Cycloaddition ReactionsChapter 28.5 - Sigmatropic RearrangementsChapter 28.6 - Pericyclic Reactions In Biological SystemsChapter 28.7 - Summary Of The Selection Rules For Pericyclic Reactions
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Chapter 1, Problem 49PChapter 2, Problem 53PChapter 3, Problem 1PChapter 4, Problem 1PChapter 5, Problem 39PFirst, H+ from HBr attacks carbon with 1H in C=C results to give tertiary carbo cation which then...Chapter 7, Problem 29PReason for correct options: The above compounds all have delocalized electrons, which undergo...DDE (dichlorodiphenyldichloroethylene) is a chemical compound forms as a result of loss of hydrogen...
The given Compound (A) is reaction with methane sulfonyl chloride which gives compound (B). This...When a Iodobenzene is treated with alkene in presence of HeeK Reagent to form the correspondng the...N-bromosuccinimide (NBS) is used for the allylic bromination through radical reaction. Bromination...Chapter 13, Problem 41PThe set of chemically equivalent protons in a compound produces a separate signal in 1H NMR. There...The structure of the compound can be drawn if the name is given and vice-versa. The name of the...Chapter 16, Problem 53PThe name given compound ethyl acetoacetate ends with ate. This means the given compound must contain...Chapter 18, Problem 42PChapter 19, Problem 21PThe product obtained when D-galactose reacts with nitric acid is as follows, Figure 1 HNO3 oxidizes...Chapter 21, Problem 49PChapter 22, Problem 1PChapter 23, Problem 1PAdenosine triphosphate (ATP) is an chemical compound which is involved in many purposes. The process...Dipalmitoylphosphatidylcholine is a surfactant found in the lining of the lungs. This lining...Chapter 26, Problem 18PChapter 27, Problem 24PChapter 28, Problem 23P
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