Concept explainers
Which of the following fragments produced in a mass spectrometer will be accelerated through the analyzer tube?
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Organic Chemistry (8th Edition)
- How can you distinguish between following APIS in Mass Spec? Draw possible Mass spectra of ALL APIS and identify each peak H O H. H c-c CH,CH,CH,OH CH3 CH;CH,-C-C-CH CH3 H3C A H3C OH D но CH;CH CH2-C-C-H CH3 B.arrow_forwardWhich of the following compounds appears in the mass spectrum to have a baseline peak at m/z=43, indicating the reason OH B OH OH C Darrow_forwardPlease refer to the image belowarrow_forward
- Kk170.arrow_forwardThe molecular ions of both C5H10S and C6H14O appear at m/z 102 in low-resolution mass spectrometry. Show how determination of the correct molecular formula can be made from the appearance and relative intensity of the M + 2 peak of each compound.arrow_forwardMatch each structure to its mass spectrum.arrow_forward
- The picture shows the given compound that was analyzed through mass spectra where notable peaks were observed. What are the structure of the fragments in the following M/Z. M/Z = 91, M/Z = 43, M/Z=147arrow_forwardWrite molecular formulas for compounds that show the following molecular ions in their high-resolution mass spectra, assuming that C, H, N, and O might be present. The exact atomic masses are: 1.007 83 (1H), 12.000 00 (12C), 14.003 07 (14N), 15.994 91 (16O). (a) M+=98.0844 (b) M+=123.0320arrow_forwardHalogenated compounds are particularly easy to identify by their mass spectra because both chlorine and bromine occur naturally as mixtures of two abundant isotopes. Recall that chlorine occurs as 35Cl (75.8%) and 37Cl (24.2%); and bromine occurs as 79Br (50.7%) and 81Br (49.3%). At what masses do the molecular ions occur for the following formulas? What are the relative percentages of each molecular ion? (a) Bromomethane, CH3Br (b) 1-Chlorohexane, C6H13Clarrow_forward
- The mass spectrum of an unknown compound has a molecular ion peak with a relative intensity of 56.11% an an M+1 peak of 5.70%. How many carbon atoms are in the compound? (Fill in an integer number)arrow_forwardfollowing the data in the mass spectrum, can you help me find the parent peak? and how do you identify the parent peak from the base peak?arrow_forwardMass spectroscopic. What is the isotopic peak pattern of each : Organic compound with 2 bromine atoms. Organic compound with 2 chlorine atoms.arrow_forward
- Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning