Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 13.6, Problem 15P
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Chapter 13 Solutions
Organic Chemistry (8th Edition)
Ch. 13.1 - Which of the following fragments produced in a...Ch. 13.2 - What distinguishes the mass spectrum of...Ch. 13.2 - What is the most likely m/z value for the base...Ch. 13.3 - Prob. 5PCh. 13.3 - a. Suggest possible molecular formulas for a...Ch. 13.3 - If a compound has a molecular ion with an...Ch. 13.3 - Identify the hydrocarbon that has a molecular ion...Ch. 13.4 - Predict the relative intensities of the molecular...Ch. 13.5 - Which molecular formula has an exact molecular...Ch. 13.5 - Prob. 11P
Ch. 13.6 - Sketch the mass spectrum expected for...Ch. 13.6 - The mass spectra of 1-methoxybutane,...Ch. 13.6 - Primary alcohols have a strong peak at m/z = 31....Ch. 13.6 - Identify the ketones responsible for the mass...Ch. 13.6 - Prob. 16PCh. 13.6 - Using curved arrows, show the principal fragments...Ch. 13.6 - The reaction of (Z)-2-pentene with water and a...Ch. 13.9 - a. Which is higher in energy: electromagnetic...Ch. 13.9 - Prob. 20PCh. 13.13 - Prob. 21PCh. 13.14 - Which occur at a larger wavenumber: a. the C O...Ch. 13.14 - Prob. 23PCh. 13.14 - Prob. 24PCh. 13.14 - Rank the following compounds from highest...Ch. 13.14 - Which shows an O H stretch at a larger...Ch. 13.16 - Prob. 27PCh. 13.16 - a. An oxygen-containing compound shows an...Ch. 13.16 - Prob. 29PCh. 13.16 - For each of the following pair of compounds, name...Ch. 13.17 - Which of the following compounds has a vibration...Ch. 13.17 - Prob. 32PCh. 13.18 - A compound with molecular formula C4H6O gives the...Ch. 13.20 - Prob. 34PCh. 13.20 - Prob. 35PCh. 13.21 - Predict the max of the following compound:Ch. 13.21 - Prob. 37PCh. 13.23 - a. At pH = 7 one of the ions shown here is purple...Ch. 13.23 - Prob. 39PCh. 13.23 - Prob. 40PCh. 13 - In the mass spectrum of the following compounds,...Ch. 13 - Prob. 42PCh. 13 - Draw structures for a saturated hydrocarbon that...Ch. 13 - Rank the following compounds in order of...Ch. 13 - For each of the following pairs of compounds,...Ch. 13 - a. How could you use IR spectroscopy to determine...Ch. 13 - Assuming that the force constant is approximately...Ch. 13 - Norlutin and Enovid are ketones that suppress so...Ch. 13 - In the following boxes, list the types of bonds...Ch. 13 - A mass spectrum shows significant peaks at m/z. =...Ch. 13 - Prob. 51PCh. 13 - Prob. 52PCh. 13 - Prob. 53PCh. 13 - The IR spectrum of a compound with molecular...Ch. 13 - Rank the following compounds from highest...Ch. 13 - Rank the following compounds from highest...Ch. 13 - What peaks in their mass spectra can be used to...Ch. 13 - Prob. 58PCh. 13 - Which one of the following five compounds produced...Ch. 13 - Prob. 60PCh. 13 - Each of the IR spectra shown below is accompanied...Ch. 13 - Prob. 62PCh. 13 - Prob. 63PCh. 13 - How can IR spectroscopy distinguish between...Ch. 13 - Prob. 65PCh. 13 - Prob. 66PCh. 13 - Give approximate wavenumbers for the major...Ch. 13 - Prob. 68PCh. 13 - Which one of the following live compounds produced...Ch. 13 - Phenolphthalein is an acid-base indicator. In...Ch. 13 - Prob. 71PCh. 13 - How can you use UV spectroscopy to distinguish...Ch. 13 - Prob. 73PCh. 13 - The IR and mass spectra for three different...
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- The mass spectrum of a compound with a molecular formula C9H10O is shown below. Which compound would you expect to give rise to the mass spectra shown below? A) Benzyl methyl ketone B) 3-Methyl-2,3-dihydro-benzofuran C) 2-Allylphenol D) Benzenepropanal E) 1-bromo-1-butenearrow_forwardBr show homotopic protons by numbering the homotopic groups. show homotopic carbon nuclei by numbering the homotopic groups.arrow_forward4. How many absorptions will the following compound have in its 1H-NMR spectrum?arrow_forward
- 1. A student exposed R-1-bromo-2-propanol to sodium hydroxide, isolated the optically active product and collected the proton and carbon NMR below. What is the structure of the product? The signal at 3ppm is a quartet. 2. A student exposed R-1-bromo-2-propanol to sodium hydroxide, isolated the optically active product, and collected the proton and carbon NMR below. What is the structure of the product? Which is the hydrogen are diastereotopic?arrow_forwardFCompound 10 is a low-boiling liquid (boiling point 58 "C), that reacts with Br, in CCI, to form a 1,1,2,2-tetra bromide The Mass, RÄCÍTICAL SPECTROSCOPY FCompound 10 is a low-boiling liquid (boiling point 58 "C) that reacts with Br. in CCI, to form a 1,1,2,2-tetra bromiide The R, and 'H NMR spectra, along with "C NMR data ve aiven below Flemental Analysis:C. 48 36. H. 4.06; contains halogen. Mass Spectrum 39 74 50 60 140 150 160 170 180 190 200 30 40 70 80 90 100 110 120 130 mve Infrared Spectrum Wave Number, cm 1 4000 1000 2500 2000 1500 1300 1200 15D0 0 10c0 900 B00 700 15 12 13 14 15 Wavelength, microns " Η NMR ppm. 5 Structurei "C Spectral Data: doublet, 80.4 ppm singlet, 68.3 ppm triplet, 347 ppin 50.0m ude 02000 Brooks/Cole Publishing Company Absorbancearrow_forwardDraw the structure of the compound. Mark the peaks on the spectra.arrow_forward
- Select the compound from each group that matches the HNMR spectrum shown below.arrow_forward3. Determine the structure for C6H₁1Br, based on the proton NMR spectrum shown. Two peaks: each is a 1H, s, that overlap 10 2H, d 1H, m 3H, s N 3H, d 0arrow_forward6. A compound with a molecular formula of C5H100 has the 1H NMR spectrum shown. Which structure shown is consistent with this spectrum? 10 I H -00 8 H ОН II -CO 6 PPM H ОН III H IV -~ OH ОН Varrow_forward
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