Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 13.6, Problem 12P
Sketch the mass spectrum expected for 1-chloropropane.
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What molecular ions will be present in a mass spectrum of 2-chloropropane,(CH3)2CHCl ?
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Chapter 13 Solutions
Organic Chemistry (8th Edition)
Ch. 13.1 - Which of the following fragments produced in a...Ch. 13.2 - What distinguishes the mass spectrum of...Ch. 13.2 - What is the most likely m/z value for the base...Ch. 13.3 - Prob. 5PCh. 13.3 - a. Suggest possible molecular formulas for a...Ch. 13.3 - If a compound has a molecular ion with an...Ch. 13.3 - Identify the hydrocarbon that has a molecular ion...Ch. 13.4 - Predict the relative intensities of the molecular...Ch. 13.5 - Which molecular formula has an exact molecular...Ch. 13.5 - Prob. 11P
Ch. 13.6 - Sketch the mass spectrum expected for...Ch. 13.6 - The mass spectra of 1-methoxybutane,...Ch. 13.6 - Primary alcohols have a strong peak at m/z = 31....Ch. 13.6 - Identify the ketones responsible for the mass...Ch. 13.6 - Prob. 16PCh. 13.6 - Using curved arrows, show the principal fragments...Ch. 13.6 - The reaction of (Z)-2-pentene with water and a...Ch. 13.9 - a. Which is higher in energy: electromagnetic...Ch. 13.9 - Prob. 20PCh. 13.13 - Prob. 21PCh. 13.14 - Which occur at a larger wavenumber: a. the C O...Ch. 13.14 - Prob. 23PCh. 13.14 - Prob. 24PCh. 13.14 - Rank the following compounds from highest...Ch. 13.14 - Which shows an O H stretch at a larger...Ch. 13.16 - Prob. 27PCh. 13.16 - a. An oxygen-containing compound shows an...Ch. 13.16 - Prob. 29PCh. 13.16 - For each of the following pair of compounds, name...Ch. 13.17 - Which of the following compounds has a vibration...Ch. 13.17 - Prob. 32PCh. 13.18 - A compound with molecular formula C4H6O gives the...Ch. 13.20 - Prob. 34PCh. 13.20 - Prob. 35PCh. 13.21 - Predict the max of the following compound:Ch. 13.21 - Prob. 37PCh. 13.23 - a. At pH = 7 one of the ions shown here is purple...Ch. 13.23 - Prob. 39PCh. 13.23 - Prob. 40PCh. 13 - In the mass spectrum of the following compounds,...Ch. 13 - Prob. 42PCh. 13 - Draw structures for a saturated hydrocarbon that...Ch. 13 - Rank the following compounds in order of...Ch. 13 - For each of the following pairs of compounds,...Ch. 13 - a. How could you use IR spectroscopy to determine...Ch. 13 - Assuming that the force constant is approximately...Ch. 13 - Norlutin and Enovid are ketones that suppress so...Ch. 13 - In the following boxes, list the types of bonds...Ch. 13 - A mass spectrum shows significant peaks at m/z. =...Ch. 13 - Prob. 51PCh. 13 - Prob. 52PCh. 13 - Prob. 53PCh. 13 - The IR spectrum of a compound with molecular...Ch. 13 - Rank the following compounds from highest...Ch. 13 - Rank the following compounds from highest...Ch. 13 - What peaks in their mass spectra can be used to...Ch. 13 - Prob. 58PCh. 13 - Which one of the following five compounds produced...Ch. 13 - Prob. 60PCh. 13 - Each of the IR spectra shown below is accompanied...Ch. 13 - Prob. 62PCh. 13 - Prob. 63PCh. 13 - How can IR spectroscopy distinguish between...Ch. 13 - Prob. 65PCh. 13 - Prob. 66PCh. 13 - Give approximate wavenumbers for the major...Ch. 13 - Prob. 68PCh. 13 - Which one of the following live compounds produced...Ch. 13 - Phenolphthalein is an acid-base indicator. In...Ch. 13 - Prob. 71PCh. 13 - How can you use UV spectroscopy to distinguish...Ch. 13 - Prob. 73PCh. 13 - The IR and mass spectra for three different...
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- Define Mass spectrum of 2-chloropropane [(CH3)2CHCl]arrow_forwardAt what masses do the molecular ions occur? What are the percentages of each molecular ion?arrow_forward4. Halogenated compounds are particularly easy to identify by their mass spectra because chlorine and bromine occur naturally as mixtures of two abundant isotopes. Chlorine occurs as "CI (75.8%) and "CI (24.2%). Ignore the presence of "C isotopes. For the compound, C,H,Cl;: a) At what masses do the molecular ions occur? b)What are the percentages of cach molecular ion?arrow_forward
- Which of the following statements is incorrect? 1.)A conventional mass spectrometer does not employ a spectrophotometric detector. 2.)Conventional mass spectrometry does not always require high purity samples. 3.)A mass spectrum shows no signals due to uncharged species. 4.)A conventional mass spectrometer uses high energy UV radiation.arrow_forwardWhat molecular ions will be present in a mass spectrum of 2-chloropropane ? ( HINT: 1. Calculate the molecular weights using each of the common isotopes of Cl. 2. Write down the molecular formula for 2-choloropropane with the isotopes of chlorine and then calculate the mass of molecular ion , m/z).arrow_forwarda) What is a centroid in mass spectrometry? How is it calculated? b) How does a monoisotopic molecular mass differ from an average molecular mass? c) What are the benefits and limitations of each of these?arrow_forward
- At what masses do the molecular ions occur? What are the percentages of each molecular ion?arrow_forwardCan I get help with this question pleasearrow_forward3. Both methylcycloheptane and ethylcyclohexane have the same molecular mass. Explain how is it possible to distinguish between the two compounds by studying and comparing both their mass spectra.arrow_forward
- Is the compound giving rise to the mass spectrum shown here more likely to contain sulfur, bromine, or chlorine? Explain. 100 80 - 60- 40 20 40 80 120 160 m/z Relative abundance -유arrow_forwardBromine has two naturally occurring isotopes, 79Br , abundance 50.52%, and 81Br, abundance 49.48%. The most stable form of bromine under standard conditions is as the diatomic molecule, Br2 . In a mass spectrum of bromine, at what m/z values would you expect to see peaks and what would you expect the relative height of the peaks to be? What species would account for each peak? Explain.arrow_forwardThe molecular weight of compound D is calculated to be 359.22 g/mol., However, the mass spectrum contains two peakS, with m/z 358.02 and m/z @360.02, in a approximately a 1:1 ratio. Explain this observation. HTML Editorgarrow_forward
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