Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 3.6, Problem 23P
Give each of the following a systematic name and indicate whether each is a primary, secondary, or tertiary alcohol:
a. CH3CH2CH2CH2CH3OH
b.
c.
d.
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10. How many H-bonds can a secondary alcohol form?
A. 3
B. 1
C. 2
D. 0
3. The reaction of water with alkene to produce an alcohol is a/an
C. Combustion
D. Addition
reaction.
A. Saponification
B. Condensation
Consider the structure of cyclohexene, if it undergoes epoxidation followed by exposure to water, which of the following final product is formed?
a. Cyclohexan-1,2,-diol
b. Cyclohexane
c. Cyclohexanone
d. Hexan-1,-6-dioic acid
Chapter 3 Solutions
Organic Chemistry (8th Edition)
Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structure of a compound with molecular...Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Prob. 6PCh. 3.1 - Draw the structure for each of the following: a....Ch. 3.1 - Name the following compounds: a. CH3OCH2CH3 b....Ch. 3.2 - Prob. 9PCh. 3.2 - Draw the structure for each of the following: a....Ch. 3.2 - Give each substituent on the nine-carbon chain a...Ch. 3.2 - Prob. 14P
Ch. 3.3 - What is each compounds systematic name?Ch. 3.3 - Prob. 16PCh. 3.3 - Prob. 17PCh. 3.3 - Prob. 18PCh. 3.3 - Prob. 19PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 21PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Prob. 25PCh. 3.6 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Draw condensed and skeletal structures for each of...Ch. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 32PCh. 3.9 - Prob. 33PCh. 3.9 - Prob. 34PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.10 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - Prob. 38PCh. 3.10 - Prob. 39PCh. 3.11 - a. Draw all the staggered and eclipsed conformers...Ch. 3.11 - Prob. 41PCh. 3.11 - Using Newman projections, draw the most stable...Ch. 3.12 - The bond angles in a regular polygon with n sides...Ch. 3.12 - Prob. 44PCh. 3.13 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.14 - Using the data in Table 3.9, calculate the...Ch. 3.14 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.15 - Prob. 48PCh. 3.15 - Which has a higher percentage of the...Ch. 3.15 - a. Draw the more stable chair conformer of...Ch. 3.15 - For each of the following disubstituted...Ch. 3.15 - a. Draw Newman projections of the two conformers...Ch. 3.15 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 56PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 66PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 69PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 72PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - What is each compound s systematic name?Ch. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 88PCh. 3 - Using the data obtained in Problem 85, calculate...Ch. 3 - Draw the conformers for the following...
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- The type of intermediate formed when HgSO4/H2SO4/H2O is added to an alkyne is: a.an alcohol b.an aldehyde c.an enol d.a diol e.a ketonearrow_forwardc. CH2-CH2-CH2-CH-CH3 b. C CH3 CH3 d. CH3-CH2-CH-CH,-CH--CH3 CH3 111s C. CH3 12.36 Give the IUPAC name for each of the follov ing d. alkanes. a. CH3-CH,--CH-CH2-CH,-CH3 ČH3 12.39 b. CH3--CH2-CH2-CH-CH3 ČH3 CH c. CH-CH2-CH-CH3 ČH3 CH3 d. CH3-CH-CH2-CH-CH3 CH3 CH3 14.4 12.37 Give the IUPAC name for each of the followi ng alkanes. a. CH3-CH-CH2-CH-CH-CH3 CH3 CH3 CH3 CH3 b. CH3--C-CH,-CH-CH3 CH3 CH3 12 CH3 c. CH3-CH2-C-CH2-CH3 CH2 CH3 CH3 d. CH3-CH2-C-CH2-CH2 CH3 CH2 1. CH3 12.38 Give the IUPAC name for each of the follo ng alkanes. a. CH3-CH2-CH-CH-CH-CH-C CH3 CH2 CH3 CH3arrow_forward13. The ferric chloride (FeCb) solution is used as a test for: a. Alcohols d. Alkyl halides b. Phenols c. Carboxylic Acids e. Alkenesarrow_forward
- 9. Draw the alkene products of the dehydration of the following alcohols: a. 2-Butanol b. 2-Propanolarrow_forward10.The reaction of excess Grignard reagent with an ester of formic acid, HCO2R, gives a. methanol. b.a tertiary alcohol. c. primary alcohol d.secondary alcohol.arrow_forwardConsider the following starting material and choose all of the functional groups that are likely to oxidize in it. a. aldehyde b. secondary alcohol c. alkane d. hemiacetal e. carboxylic acid f. alkenearrow_forward
- 1. Classify each of the following as a primary, secondary, or tertiary alcohol: CH₂CH3 a. b. CH₂CHCH₂CHCH3 T OH Br CH3CH₂CH₂OH CH3 CH3CCH₂CH₂CH3 c. CH₂CH₂COH T CH3 d. OH e. 1-methylcyclopentanolarrow_forwardHow is the alcohol classified? a. primary b. quartenary c. aromatic d. tertiary d. secondaryarrow_forwardAlkenes are not soluble in water because they are a. polar b. hydrophilic c. hydrophobic d. less dense than waterarrow_forward
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