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(a)
Interpretation:
Given set of compounds has to be ranked from most soluble to least soluble in water.
Concept introduction:
Solubility:
The general rule that in solubility is like dissolve like, in other words, polar compounds dissolve in polar solvents, and non-polar compounds dissolve in non-polar solvents.
Polarity:
The polar solvent such as a water has partial charges that can interact with the partial charges on a polar compound. The negative poles of the solvent molecule surround the positive pole of the polar compound and the positive pole of polar compound. The clustering of the solvent molecules around the polar molecules separates them from each other, which is make them dissolve.
Non-polarity:
The non-polar compounds have no charge; polar solvents are not attached to them. For a non-polar molecule to dissolve in polar solvent, the non-polar molecule would have to push the water molecules apart, disrupting their hydrogen bonding.
(b)
Interpretation:
Given set of compounds has to be ranked from most soluble to least soluble in water.
Concept introduction:
Solubility:
The general rule that in solubility is like dissolve like, in other words, polar compounds dissolve in polar solvents, and non-polar compounds dissolve in non-polar solvents.
Polarity:
The polar solvent such as a water has partial charges that can interact with the partial charges on a polar compound. The negative poles of the solvent molecule surround the positive pole of the polar compound and the positive pole of polar compound. The clustering of the solvent molecules around the polar molecules separates them from each other, which is make them dissolve.
Non-polarity:
The non-polar compounds have no charge; polar solvents are not attached to them. For a non-polar molecule to dissolve in polar solvent, the non-polar molecule would have to push the water molecules apart, disrupting their hydrogen bonding.
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Chapter 3 Solutions
Organic Chemistry (8th Edition)
- Arrange the compounds in increasing order according to its solubility in hexane. CH3CH2OCH3 CH3CH2CH2OH CH3COCH3 CH3COOHarrow_forwardArrange the compounds by their solubility in water. Most soluble in water -OCH3 H-C -OCH₂CH3 CH₂CH₂ -OCH3 CH₂CH₂ -OCH₂CH3 CH₂CH₂ -OCH₂CH₂CH₂ Least soluble in water įarrow_forwardList the following compounds in order of increasing water solubility: a.ethoxyethane b.propanoic acid c.pentane d.1 butanolarrow_forward
- From each pair of compounds, select the one that is more soluble in water.arrow_forwardThe boiling points of various organic compounds are given below. Explain the reasons for the different be points. How do the functional groups of each compound effect their boiling points? 6. Boiling Point 141°C Compound | Propanoic acid 1-propanol 1-propanamine Propanal Propane 97°C 51°C 48°C -42°C bAdd hdrol 7. The compound shown is a common artificial sweetener, Circle and identify the functional groups in the molecule. Which functional groups can undergo hydrolysis? Draw structures to show the complete hydrolysis (either acidic or basic) of the compound. (Hint: hydrolysis may occur in more than one location.) anen HO. NH CH3 NH2 8. a) Valproic acid is an anti-seizure medication often administered in a sodium salt form. Draw out the reaction showing how the sodium salt of valproic acid is formed. Why is the salt form used? etoca) soslom lonoitanutlsgs at (woled pile bos aiolte n anuong le 8,9slicalyrtts mal or lonsis w bus bsCH, - CH, - CH oD mal e (biaE CH - CH, - CH, - CH,…arrow_forwardwhich one of the following is least soluble in water?arrow_forward
- Give detailed Solution with explanation (no need Handwritten answerarrow_forwardRank the following compounds in order of increasing strength of intermolecular forces: CH3CH2CH2CH2CH3 (pentane), CH3CH2CH2CH2OH (1-butanol), and CH3CH2CH2CHO (butanal).arrow_forwardRank the attached compounds in order of increasing water solubility ?arrow_forward
- Which compound has the highest water solubility? H A Darrow_forwardWhich of the following would be LEAST soluble in water? CH3CH₂CH₂CH₂OH CH3CH₂CH₂OH All of these would have about the same solubility in water. heptane O CH3CH₂CH₂CH₂CH₂NH₂arrow_forwardQUESTION 8 Rank the following compounds in decreasing order of water solubility (highest to lowest). see the attached file. CH3CH2CH2CH2OH CH3CH20CH2CH2CH3 CH3CH2OCH2CH2OH CH3CH2OH IVarrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
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