Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 3, Problem 72P

(a)

Interpretation Introduction

Interpretation:

The systematic name for each isomer has to be given.

Concept introduction:

The many of organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix, suffix and root word.

The bond-line structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments.  For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon.  For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

Prefix: Represents the substituent present in the molecule and its position in the root name.

Suffix: Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.  For example alkynes molecules, suffix will be ‘yne’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

Nomenclature of organic molecules: The particular functional group connected into a primary carbon atom, while secondary and tertiary groups in (C2 and C3) place of carbon atoms it is called primary, secondary and tertiary structures.

(b)

Interpretation Introduction

Interpretation:

The common name for each isomer has to be given.

Concept introduction:

The many of organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix, suffix and root word.

The bond-line structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments.  For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon.  For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

Prefix: Represents the substituent present in the molecule and its position in the root name.

Suffix: Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.  For example alkynes molecules, suffix will be ‘yne’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

Nomenclature of organic molecules: The particular functional group connected into a primary carbon atom, while secondary and tertiary groups in (C2 and C3) place of carbon atoms it is called primary, secondary and tertiary structures.

(c)

Interpretation Introduction

Interpretation:

The number of primary alkyl halides has to be given.

Concept introduction:

The many of organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix, suffix and root word.

The bond-line structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments.  For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon.  For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

Prefix: Represents the substituent present in the molecule and its position in the root name.

Suffix: Denotes the presence of functional group if any in the molecule.  It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.  For example alkynes molecules, suffix will be ‘yne’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

Nomenclature of organic molecules: The particular functional group connected into a primary carbon atom, while secondary and tertiary groups in (C2 and C3) place of carbon atoms it is called primary, secondary and tertiary structures.

(d)

Interpretation Introduction

Interpretation:

The number of secondary alkyl halide has to be given.

Concept introduction:

The many of organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix, suffix and root word.

The bond-line structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments.  For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon.  For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

Prefix: Represents the substituent present in the molecule and its position in the root name.

Suffix: Denotes the presence of functional group if any in the molecule.  It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.  For example alkynes molecules, suffix will be ‘yne’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

Nomenclature of organic molecules: The particular functional group connected into a primary carbon atom, while secondary and tertiary groups in (C2 and C3) place of carbon atoms it is called primary, secondary and tertiary structures.

(e)

Interpretation Introduction

Interpretation:

The number of tertiary alkyl halide has to be given.

Concept introduction:

The many of organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix, suffix and root word.

The bond-line structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments.  For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon.  For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

Prefix: Represents the substituent present in the molecule and its position in the root name.

Suffix: Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. For example alkynes molecules, suffix will be ‘yne’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

Nomenclature of organic molecules: The particular functional group connected into a primary carbon atom, while secondary and tertiary groups in (C2 and C3) place of carbon atoms it is called primary, secondary and tertiary structures.

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Students have asked these similar questions
1. Which of the following compounds are isomers of each other? I. 3-hexene II. Cyclohexane III. 2,3-dimethyl-2-butene      IV. 2-methyl-2,3-pentadiene a. I and II b. II and IV c. I, II, III d. I, II, III, IV   2. Which of the following does not contain a carbonyl group? A. CH3CH2CH2COCH2CH3 B. CH3CH2CH2COOCH3 C. CH3CH2CH2CHOHCH2CH3 D. CH3CH2CH2CONH2CH3
Classify each compound as an alkyl halide, a vinyl halide, or an aryl halide.
3. Draw the structure of the following alkenes. Some of these compounds can show isomerism, and some cannot. Indicate which among these can show cis and trans isomers. a. hex-3-ene b. buta-1,3-diene c. 2,3-dimethylpent-2-ene 4. Draw the structure of the following alkenes. Some of these compounds can show isomerism, and some cannot. Indicate which among these can show cis and trans isomers. a. 3-ethylhexa-2,4-diene b. pent-1,3-diene c. 3,7-dichloroocta-2,5-diene

Chapter 3 Solutions

Organic Chemistry (8th Edition)

Ch. 3.3 - What is each compounds systematic name?Ch. 3.3 - Prob. 16PCh. 3.3 - Prob. 17PCh. 3.3 - Prob. 18PCh. 3.3 - Prob. 19PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 21PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Prob. 25PCh. 3.6 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Draw condensed and skeletal structures for each of...Ch. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 32PCh. 3.9 - Prob. 33PCh. 3.9 - Prob. 34PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.10 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - Prob. 38PCh. 3.10 - Prob. 39PCh. 3.11 - a. Draw all the staggered and eclipsed conformers...Ch. 3.11 - Prob. 41PCh. 3.11 - Using Newman projections, draw the most stable...Ch. 3.12 - The bond angles in a regular polygon with n sides...Ch. 3.12 - Prob. 44PCh. 3.13 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.14 - Using the data in Table 3.9, calculate the...Ch. 3.14 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.15 - Prob. 48PCh. 3.15 - Which has a higher percentage of the...Ch. 3.15 - a. Draw the more stable chair conformer of...Ch. 3.15 - For each of the following disubstituted...Ch. 3.15 - a. Draw Newman projections of the two conformers...Ch. 3.15 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 56PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 66PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 69PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 72PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - What is each compound s systematic name?Ch. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 88PCh. 3 - Using the data obtained in Problem 85, calculate...Ch. 3 - Draw the conformers for the following...
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