Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 3.15, Problem 48P

(a)

Interpretation Introduction

Interpretation:

Given substituted axial and equatorial cyclohexane molecule, whether cis isomer or a trans isomer has to be identified.

Concept introduction:

Stereoisomerism (or) geometric isomerism:

It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

For example the cyclohexane ring has two substituent’s, must take both substituents into account when predicting which of the two chair conformers is more stable, like 1,4-dimethylcyclohexane has presence two methyl groups in 1,4-positions.

Conformers:

The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

(b)

Interpretation Introduction

Interpretation:

Given substituted axial and equatorial cyclohexane molecule, whether cis isomer or a trans isomer has to be identified.

Concept introduction:

Stereoisomerism (or) geometric isomerism:

It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

For example the cyclohexane ring has two substituent’s, must take both substituents into account when predicting which of the two chair conformers is more stable, like 1,4-dimethylcyclohexane has presence two methyl groups in 1,4-positions.

Conformers:

The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

(c)

Interpretation Introduction

Interpretation:

Given substituted axial and equatorial cyclohexane molecule, whether cis isomer or a trans isomer has to be identified.

Concept introduction:

Stereoisomerism (or) geometric isomerism:

It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

For example the cyclohexane ring has two substituent’s, must take both substituents into account when predicting which of the two chair conformers is more stable, like 1,4-dimethylcyclohexane has presence two methyl groups in 1,4-positions.

Conformers:

The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

(d)

Interpretation Introduction

Interpretation:

Given substituted axial and equatorial cyclohexane molecule, whether cis isomer or a trans isomer has to be identified.

Concept introduction:

Stereoisomerism (or) geometric isomerism:

It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

For example the cyclohexane ring has two substituent’s, must take both substituents into account when predicting which of the two chair conformers is more stable, like 1,4-dimethylcyclohexane has presence two methyl groups in 1,4-positions.

Conformers:

The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

(e)

Interpretation Introduction

Interpretation:

Given substituted axial and equatorial cyclohexane molecule, whether cis isomer or a trans isomer has to be identified.

Concept introduction:

Stereoisomerism (or) geometric isomerism:

It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

For example the cyclohexane ring has two substituent’s, must take both substituents into account when predicting which of the two chair conformers is more stable, like 1,4-dimethylcyclohexane has presence two methyl groups in 1,4-positions.

Conformers:

The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

(f)

Interpretation Introduction

Interpretation:

Given substituted axial and equatorial cyclohexane molecule, whether cis isomer or a trans isomer has to be identified.

Concept introduction:

Stereoisomerism (or) geometric isomerism:

It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

For example the cyclohexane ring has two substituent’s, must take both substituents into account when predicting which of the two chair conformers is more stable, like 1,4-dimethylcyclohexane has presence two methyl groups in 1,4-positions.

Conformers:

The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

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Chapter 3 Solutions

Organic Chemistry (8th Edition)

Ch. 3.3 - What is each compounds systematic name?Ch. 3.3 - Prob. 16PCh. 3.3 - Prob. 17PCh. 3.3 - Prob. 18PCh. 3.3 - Prob. 19PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 21PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Prob. 25PCh. 3.6 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Draw condensed and skeletal structures for each of...Ch. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 32PCh. 3.9 - Prob. 33PCh. 3.9 - Prob. 34PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.10 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - Prob. 38PCh. 3.10 - Prob. 39PCh. 3.11 - a. Draw all the staggered and eclipsed conformers...Ch. 3.11 - Prob. 41PCh. 3.11 - Using Newman projections, draw the most stable...Ch. 3.12 - The bond angles in a regular polygon with n sides...Ch. 3.12 - Prob. 44PCh. 3.13 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.14 - Using the data in Table 3.9, calculate the...Ch. 3.14 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.15 - Prob. 48PCh. 3.15 - Which has a higher percentage of the...Ch. 3.15 - a. Draw the more stable chair conformer of...Ch. 3.15 - For each of the following disubstituted...Ch. 3.15 - a. Draw Newman projections of the two conformers...Ch. 3.15 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 56PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 66PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 69PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 72PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - What is each compound s systematic name?Ch. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 88PCh. 3 - Using the data obtained in Problem 85, calculate...Ch. 3 - Draw the conformers for the following...
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