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Concept explainers
(a)
Interpretation:
The given condensed structure has to be converted into skeletal structure.
Concept introduction:
IUPAC systematic method: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of
Root word represents the longest continuous carbon skeleton of the organic molecule.
Condensed Formula: The molecular formula where the symbols of atoms are listed in order as they appear in the respective molecular structure with bonded dash omitted or limited it is called the condensed structure.
Skeletal formula: It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.
(b)
Interpretation:
The given condensed structure has to be converted into skeletal structure.
Concept introduction:
IUPAC systematic method: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...
Root word represents the longest continuous carbon skeleton of the organic molecule.
Condensed Formula: The molecular formula where the symbols of atoms are listed in order as they appear in the respective molecular structure with bonded dash omitted or limited it is called the condensed structure.
Skeletal formula: It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.
(c)
Interpretation:
The given condensed structure has to be converted into skeletal structure.
Concept introduction:
IUPAC systematic method: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...
Root word represents the longest continuous carbon skeleton of the organic molecule.
Condensed Formula: The molecular formula where the symbols of atoms are listed in order as they appear in the respective molecular structure with bonded dash omitted or limited it is called the condensed structure.
Skeletal formula: It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.
d)
Interpretation:
The given condensed structure has to be converted into skeletal structure.
Concept introduction:
IUPAC systematic method: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...
Root word represents the longest continuous carbon skeleton of the organic molecule.
Condensed Formula: The molecular formula where the symbols of atoms are listed in order as they appear in the respective molecular structure with bonded dash omitted or limited it is called the condensed structure.
Skeletal formula: It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.
(e)
Interpretation:
The given condensed structure has to be converted into skeletal structure.
Concept introduction:
IUPAC systematic method: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...
Root word represents the longest continuous carbon skeleton of the organic molecule.
Condensed Formula: The molecular formula where the symbols of atoms are listed in order as they appear in the respective molecular structure with bonded dash omitted or limited it is called the condensed structure.
Skeletal formula: It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.
f)
Interpretation:
The given condensed structure has to be converted into skeletal structure.
Concept introduction:
IUPAC systematic method: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...
Root word represents the longest continuous carbon skeleton of the organic molecule.
Condensed Formula: The molecular formula where the symbols of atoms are listed in order as they appear in the respective molecular structure with bonded dash omitted or limited it is called the condensed structure.
Skeletal formula: It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.
(g)
Interpretation:
The given condensed structure has to be converted into skeletal structure.
Concept introduction:
IUPAC systematic method: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...
Root word represents the longest continuous carbon skeleton of the organic molecule.
Condensed Formula: The molecular formula where the symbols of atoms are listed in order as they appear in the respective molecular structure with bonded dash omitted or limited it is called the condensed structure.
Skeletal formula: It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.
(h)
Interpretation:
The given condensed structure has to be converted into skeletal structure.
Concept introduction:
IUPAC systematic method: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...
Root word represents the longest continuous carbon skeleton of the organic molecule.
Condensed Formula: The molecular formula where the symbols of atoms are listed in order as they appear in the respective molecular structure with bonded dash omitted or limited it is called the condensed structure.
Skeletal formula: It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.
(i)
Interpretation:
The given condensed structure has to be converted into skeletal structure.
Concept introduction:
IUPAC systematic method: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...
Root word represents the longest continuous carbon skeleton of the organic molecule.
Condensed Formula: The molecular formula where the symbols of atoms are listed in order as they appear in the respective molecular structure with bonded dash omitted or limited it is called the condensed structure.
Skeletal formula: It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.
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Chapter 3 Solutions
Organic Chemistry (8th Edition)
- I have given you a condensed structure. You need to convert it to an accurate bond-line structure. CH3 CH3-CH-CH2-CH-CH₂-C-H 12-CH-CH2₂-C-1 CI Draw (as bond-line structures) isomers of this compound where you only move the chlorine atom. Draw four isomers of the original compound that would have a five carbon chain as the longest chain. [Note: there would be many isomers that will satisfy this. Find any four.] Using the original molecule (and looking at the carbon next to the aldehyde carbonyl) what would be the charge on that carbon if I removed an H atom and left behind the pair of electrons? Circle the best answer Positive Negative Neutral In the space below, draw that structure (from the sentence above) as a bond-line structure. Then, draw a resonance structure for this ion and be sure to add curved arrows to show the movement of electrons.arrow_forwardChange the following condensed structures to skeletal structures: CH,NH(CH),Cн, b. (CH,), C(СH),ОН c. (CH;),CHC1 d. (CH;),CH(CH,),CHO а. 3 е. CH,(CH,),О(СH),C(CH),arrow_forwardProvide a line structure for the following condensed structure: (CH3)2CH(CH2)2CCH(CH3)2CH(CH3)(CH,CH3)(CH2)3CH3arrow_forward
- Convert the following condensed formulas into skeletal structures. a. CH3CONHCH3b. CH3COCH2Brc. (CH3)3COHd. CH3COCle. CH3COCH2CO2Hf. HO2CCH(OH)CO2Harrow_forwardSummarize the nomenclature rules for alkanes, alkenes, alkynes, and aromatic compounds. Correct the following false statements regarding nomenclature of hydrocarbons. a. The root name for a hydrocarbon is based on the shortest continuous chain of carbon atoms. b. The suffix used to name all hydrocarbons is -ane. c. Substituent groups are numbered so as to give the largest numbers possible. d. No number is required to indicate the positions of double or triple bonds in alkenes and alkynes. e. Substituent groups get the lowest number possible in alkenes and alkynes. f. The ortho- term in aromatic hydrocarbons indicates the presence of two substituent groups bonded to carbon- 1 and carbon-3 in benzene.arrow_forwardIn 1874, Dutch chemist Jacobus van't Hoff (1852–1911) and French chemist Joseph Le Bel (1847–1930) independently deduced that a carbon atom bonded to four atoms assumes a tetrahedral geometry. Prior to that time, it was believed that tetravalent carbons assumed a square planar geometry. One piece of evidence that can be used to support a tetrahedral geometry is the fact that molecules with the general formula CX2Y2 (where X and Y are either a hydrogen or a halogen atom) are always polar. Explain how this supports a tetrahedral geometry and rules out a square planar geometry. Square planar geometry Tetrahedral geometryarrow_forward
- Convert each skeletal structure to a complete structure with all C's and H's drawn in. Add lone pairs on all heteroatoms. 1. Cyclooctane 2. Lindane CI CI CI- CI 3. Menthanol OH CH3- CH(CH3)2arrow_forwardNaming and Drawing Organic Molecules Drawing a skeletal structure from a condensed structure Draw a skeletal ("line") structure of this molecule: CH CH₂ CH3-CH CH-CH₂ CH2 CH-CH-CH-CH2-CH2-CH2-CH₂ Click and drag to start drawing a structure. Explanation Check ח' MacBook Air D: G € C 4/5 Julianna ah ©2024 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Accessibilityarrow_forwardB.3 Isomers of C6H14 elgmo Complete the following table with the four isomers of the alkane C6H14. The first isomer is done for you: Give the IUPAC name of each. Hint: two isomers have one branch and two isomers have two branches and none of the isomers are ringed systems. Complete Structural Formula H H H H нн Нн Н-с-с-с-С-с-с-Н Ī Ī I I H. H H H H H Name: Hexane Complotn Ctrund 5.arrow_forward
- II. Write the line bond and condensed structures of the following Akanes. Alkane 5-ethyl-3-methyldecane 1-ethyl-3-methylcyclooctane 3-cyclopropyl-3-methylheptane 3-cyclopropyl-3-methylheptane Line Bond structure Condensed Structure Leave this blank Leave this blankarrow_forwardThere are 17 constitutional isomers with the molecular formula of C5H13N. Draw all 17 of these isomers as skeletal structures and give the SMILES for each.arrow_forward8. Draw the line bond structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. Line bond structure: Condensed structure: Skeletal formula: 9. Draw the line bond structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. Line bond structure: Condensed structure: Skeletal formula:arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
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