
(a)
Interpretation:
The product of stereoisomers that formed in the given reaction should be given.
Concept introduction:
Isomer:
The compound is having same molecular formula but arrangement of the atom is different is called isomer.
In the nucleophilic substitution reaction, the
In
The rate determination step is formation of carbocation.
The stability order of carbocation is,
Tertiary > Secondary > Primary
Therefore, tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation. Primary alcohol is less stable therefore it won’t undergoes
In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary
(b)
Interpretation:
The product of stereoisomers that formed in the given reaction should be given.
Concept introduction:
Isomer:
The compound is having same molecular formula but arrangement of the atom is different is called isomer.
In the nucleophilic substitution reaction, the rate of reaction depends only on one reactant, which is involved in reaction is called unimolecular nucleophilic substitution reaction.
In
The rate determination step is formation of carbocation.
The stability order of carbocation is,
Tertiary > Secondary > Primary
Therefore, tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation. Primary alcohol is less stable therefore it won’t undergoes
In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary
(c)
Interpretation:
The product of stereoisomers that formed in the given reaction should be given.
Concept introduction:
Isomer:
The compound is having same molecular formula but arrangement of the atom is different is called isomer.
In the nucleophilic substitution reaction, the rate of reaction depends only on one reactant, which is involved in reaction is called unimolecular nucleophilic substitution reaction.
In
The rate determination step is formation of carbocation.
The stability order of carbocation is,
Tertiary > Secondary > Primary
Therefore, tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation. Primary alcohol is less stable therefore it won’t undergoes
In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary
(d)
Interpretation:
The product of stereoisomers that formed in the given reaction should be given.
Concept introduction:
Isomer:
The compound is having same molecular formula but arrangement of the atom is different is called isomer.
In the nucleophilic substitution reaction, the rate of reaction depends only on one reactant, which is involved in reaction is called unimolecular nucleophilic substitution reaction.
In
The rate determination step is formation of carbocation.
The stability order of carbocation is,
Tertiary > Secondary > Primary
Therefore, tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation. Primary alcohol is less stable therefore it won’t undergoes
In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary

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Chapter 10 Solutions
Organic Chemistry (8th Edition)
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- Can I please get the graph 1: Concentration vs. Density?arrow_forwardOrder the following series of compounds from highest to lowest reactivity to electrophilic aromatic substitution, explaining your answer: 2-nitrophenol, p-Toluidine, N-(4-methylphenyl)acetamide, 4-methylbenzonitrile, 4-(trifluoromethyl)benzonitrile.arrow_forwardOrdene la siguiente serie de compuestos de mayor a menor reactividad a la sustitución aromática electrofílica, explicando su respuesta: ácido bencenosulfónico, fluorobenceno, etilbenceno, clorobenceno, terc-butilbenceno, acetofenona.arrow_forward
- Can I please get all final concentrations please!arrow_forwardState the detailed mechanism of the reaction of benzene with isopropanol in sulfuric acid.arrow_forwardDo not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction. For the decomposition reaction of N2O5(g): 2 N2O5(g) · 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 -> NO2 + NO3_(K1) NO2 + NO3 →> N2O5 (k-1) → NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Give the expression for the acceptable rate. (A). d[N₂O] dt = -1 2k,k₂[N205] k₁+k₂ d[N₂O5] (B). dt =-k₁[N₂O₂] + k₁[NO2][NO3] - k₂[NO2]³ (C). d[N₂O] dt =-k₁[N₂O] + k₁[N205] - K3 [NO] [N205] (D). d[N2O5] =-k₁[NO] - K3[NO] [N₂05] dtarrow_forward
- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 20.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFor the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.arrow_forwardFor the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning

