Interpretation:
The specific rotation of the compound has to be calculated.
Concept introduction:
The pair of Enantiomers has different configurations.
Pair of enantiomers has different optical activity, which means if one will show levorotatory then the other will show dextrorotatory.
The direction and magnitude of rotation of plane-polarized light by an optically compound is measured by using polarimeter.
This rotation of polarized light is specific for a compound at specified temperature and wavelength, so it is called as Specific rotation of that compound.
Specific rotation of compound is calculated by,
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Organic Chemistry (8th Edition)
- The specific rotation, [a]p, for (-)-2-butanol is +14. What is the observed rotation for a solution of 3.3 g of (-)-2-butanol in 10 mL of water in a sample tube having a pathlength of 10 cm? degrees . The observed rotation of a solution of 0.75 g of a compound in 10 mL of water is -6.9 degrees. If the pathlength is 10 cm, what is the specific rotation of the compound?arrow_forwardIf a substance is known to have a specific rotation of +20.0 deg mL/g dm, what is the concentration (in g/mL) of a solution that would give an observed rotation of +10.0 degrees, if the path length of the sample tube was 1.00 dm? Can you do this problem in your head?arrow_forwardplease answerarrow_forward
- How can we decide whether an observed rotation of a solution of an optically active compound is +170° and not actually -190°?arrow_forward1. When 0.247 g of monosodium glutamate (MSG) is dissolved in 10.0 mL of water and placed in a sample cell 10.0 cm in length, the observed rotation at 20°(using the D line of sodium) is +0.632°. Calculate the specific rotation of MSG. 2. When 0.095 g of cholesterol is dissolved in 1.00 mL of ether and placed in a sample cell 10.0 cm in length, the observed rotation at 20°C (using the D line of sodium) is -0.299°.Calculate the specific rotation of cholesterol.3. The specific rotation of L-dopa in water (at 15°C) is -39.5. A chemist prepared a mixture of L-dopa and its enantiomer, and this mixture had a specific rotation of -34. Calculate the % ee of this mixture. 4. The specific rotation of vitamin B7 in water (at 22°C) is +92. A chemist prepared a mixture of vitamin B7 and its enantiomer, and this mixture had a specific rotation of +18. Calculate the % ee of this mixture.arrow_forwardapp:10Tack.co Type here to se OM C O Quin 23 of 30 A solution of a chiral compound was prepared by dissolving 15.67 g in 16.00 mL of solvent. The solution was placed in a tube that is 1.00 dm long. What is the specific rotation of light if the observed rotation was determined experimentally to be +62.41"? ✓ O 1 4 7 2 5 3 6 9 0 DAộ c * ▪ ✪ с x 100 1508227arrow_forward
- The specific rotation of S-Ibuprofen is +54.5o. Which direction would a mixture containing 80% S-Ibuprofen and 10% R-ibuprofen rotate plane polarized light? To the left or to the right?arrow_forwardView Policies Current Attempt in Progress When 0.234 g of monosodium glutamate (MSG) is dissolved in 10.0 mL of water and placed in a sample cell 10.0 cm in length, the observed rotation at 20°(using the D line of sodium) is +0.599°. Calculate the specific rotation of MSG. specific rotation = [a] = i eTexthook and Mediaarrow_forwardThe observed rotation for 100 mL of an aqueous solution containing 50,00 g of sucrose, placed in a 1-decimeter sample tube, is +20°. What is the specific rotation of sucrose? a) + 40 d) - 0.4 b)-4 e) +20 c) + 0.4arrow_forward
- Calculation of Optical rotation.arrow_forwardThe specific rotation of vitamin C ( using the D line of sodium, at 20°C) is +24. Predict what the observed rotation would be for a solution containing 0.100 g of vitamin C dissolved in 10.0 ml of ethanol and placed in a sample cell with a length of 1dm.arrow_forward(S)-2-Bromobutane has a specific rotation of +23.1°. Suppose that a solution is made by dissolving 20.00 g of (S)-2-bromobutane in 1.00 L total solution. What would be the measured rotation of plane-polarized light sent througha 10.00-cm tube containing that solution?arrow_forward
- EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENTOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning