The optically inactive compound for the given molecular formula has to be drawn. Concept introduction: Optical activity of a molecule is the interaction between molecule and plane-polarized light. Molecule having asymmetric center shows optical activity except mesocompounds. Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups. Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral. If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

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Answer 1

Question

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

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Answer 2

Question

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

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Answer 3

Question

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

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Answer 4

Question

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

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Answer 5

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

Answer 6

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Answer 7

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

Answer 12

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Answer 13

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Answer 15

Ch. 4.1 - Prob. 2P Ch. 4.1 - Prob. 3P Ch. 4.1 - Prob. 4P Ch. 4.1 - Prob. 5P Ch. 4.1 - Which of the roll owing compounds have a dipole...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Assign relative priorities to each set of...Ch. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Prob. 10P Ch. 4.2 - Name each of the following:

Solution Summary: The author explains that the optically inactive compound for the given molecular formula has to be drawn.

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