Organic Chemistry (8th Edition)

8th Edition

ISBN: 9780134042282

Author: Paula Yurkanis Bruice

Publisher: PEARSON

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Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atom…

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Textbook Question

Chapter 4, Problem 93P

Draw structures for the following:

a. (S)-1-bromo-1-ehlorobutane
b. (2R,3R)-2,3-dichloropentane
c. an achiral stereoisomer of 1,2-dimethylcyclohexane
d. a chiral stereoisomer of 1,2-dibromocyclobutane
e. two achiral stereoisomers of 3,4,5-trimethylheptane

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Chapter 4, Problem 92P

Chapter 4, Problem 94P

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Chapter 4 Solutions

Organic Chemistry (8th Edition)

Ch. 4.1 - Prob. 2P Ch. 4.1 - Prob. 3P Ch. 4.1 - Prob. 4P Ch. 4.1 - Prob. 5P Ch. 4.1 - Which of the roll owing compounds have a dipole...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Assign relative priorities to each set of...Ch. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Prob. 10P Ch. 4.2 - Name each of the following:

Ch. 4.2 - Draw the Z isomer of an alkene that has a CH3 and...Ch. 4.3 - Prob. 13P Ch. 4.4 - Prob. 14P Ch. 4.5 - Prob. 16P Ch. 4.6 - Prob. 17P Ch. 4.7 - Prob. 18P Ch. 4.8 - Prob. 20P Ch. 4.8 - Prob. 22P Ch. 4.8 - Prob. 23P Ch. 4.8 - Prob. 24P Ch. 4.8 - Draw a perspective formula for each or the...Ch. 4.8 - Prob. 27P Ch. 4.9 - Prob. 28P Ch. 4.9 - What is the configuration of the following...Ch. 4.9 - Prob. 32P Ch. 4.10 - Prob. 33P Ch. 4.10 - (S)-(+)-Monosodium glutamate (MSG) is a flavor...Ch. 4.11 - Prob. 35P Ch. 4.11 - Prob. 36P Ch. 4.12 - Prob. 38P Ch. 4.12 - Prob. 39P Ch. 4.12 - The stereoisomer of cholesterol found in nature is...Ch. 4.12 - Prob. 41P Ch. 4.13 - 1-Bromo-2-methylcyclopentane has four pairs of...Ch. 4.13 - Prob. 43P Ch. 4.13 - Draw all possible stereoisomers for each of the...Ch. 4.13 - Prob. 45P Ch. 4.13 - Of all the possible cyclooctanes that have one...Ch. 4.13 - Prob. 47P Ch. 4.13 - Prob. 48P Ch. 4.14 - Which of the following compounds has a...Ch. 4.14 - Draw all the stereoisomers for each of the...Ch. 4.15 - Prob. 52P Ch. 4.15 - Name the isomers you drew in Problem 52.Ch. 4.15 - Chloramphenicol is a broad-spectrum antibiotic...Ch. 4.15 - Draw a perspective formula for each of the...Ch. 4.15 - Name the following:Ch. 4.15 - Prob. 57P Ch. 4.15 - Prob. 59P Ch. 4.15 - Convert the perspective formula to a skeletal...Ch. 4.15 - Prob. 62P Ch. 4.16 - Prob. 63P Ch. 4.17 - Limonene exists as two different stereoisomers....Ch. 4 - a. Draw three constitutional isomers with...Ch. 4 - Prob. 65P Ch. 4 - Prob. 66P Ch. 4 - Which of the following has an asymmetric center?...Ch. 4 - Prob. 68P Ch. 4 - Prob. 69P Ch. 4 - Prob. 70P Ch. 4 - Prob. 71P Ch. 4 - Assign relative priorities to each set of...Ch. 4 - Prob. 73P Ch. 4 - Which of the following are optically active?Ch. 4 - Prob. 75P Ch. 4 - Name the following:Ch. 4 - Which of the following has an achiral...Ch. 4 - Using skeletal structures, draw the stereoisomers...Ch. 4 - Prob. 79P Ch. 4 - Citrate synthase, one of the enzymes in the series...Ch. 4 - Prob. 81P Ch. 4 - Prob. 82P Ch. 4 - Prob. 83P Ch. 4 - Prob. 84P Ch. 4 - Prob. 85P Ch. 4 - Prob. 86P Ch. 4 - Prob. 87P Ch. 4 - Prob. 88P Ch. 4 - Prob. 89P Ch. 4 - a. Draw all the isomers with molecular formula...Ch. 4 - Prob. 91P Ch. 4 - Prob. 92P Ch. 4 - Draw structures for the following: a....Ch. 4 - For each of the following structures, draw the...Ch. 4 - Prob. 95P Ch. 4 - Prob. 96P Ch. 4 - Prob. 97P Ch. 4 - a. Using the wedge-and-dash notation, draw the...Ch. 4 - Prob. 99P Ch. 4 - Prob. 100P Ch. 4 - Prob. 101P Ch. 4 - a. Draw the two chair conformers for each of the...Ch. 4 - Prob. 103P Ch. 4 - Is the following compound optically active?Ch. 4 - Prob. 105P

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Draw structures for the following: a. ( S )-1-bromo-1-ehlorobutane b. (2 R ,3 R )-2,3-dichloropentane c. an achiral stereoisomer of 1,2-dimethylcyclohexane d. a chiral stereoisomer of 1,2-dibromocyclobutane e. two achiral stereoisomers of 3,4,5-trimethylheptane

Solution Summary: The author explains the structure of (S) 1-bromo-1-chlorobutane.

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Chapter 4 Solutions