Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 6.12, Problem 35P
What characteristics must the reactant of a stereospecific reaction have?
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Suggest chemical tests to differentiate the pairs of organic compounds given the
reaction for the positive sign. Write observable change for positive sign of reaction
and chemical reaction for compound that will test positive
choices are: permanganate test, lucas test, ferric chloride, tollen's, iodoform, 2,4-
DNP, molisch, benedict's
Chemical Test and
Positive Sign of
Reaction
Test:
Compound
which will Test
Positive
Chemical Reaction
for the Positive
Sign
но.
он
H
dehydration, then
condensation
Positive Sign:
H
H
он
он
ribose
tetrahydrofuran
Describe the stereochemical relationship of products. Is this a stereospecific reaction, why or why not?
What do you mean by Stereochemistry ?
Chapter 6 Solutions
Organic Chemistry (8th Edition)
Ch. 6.1 - Draw the mechanism for the reaction of cyclohexene...Ch. 6.2 - a. How many bond orbitals are avilable for...Ch. 6.2 - Prob. 3PCh. 6.2 - Prob. 4PCh. 6.3 - Prob. 5PCh. 6.4 - Prob. 6PCh. 6.4 - Prob. 7PCh. 6.4 - What alkene should be used to synthesize each of...Ch. 6.5 - The pKa of a protonated alcohol is about 2.5, and...Ch. 6.5 - Prob. 10P
Ch. 6.5 - Prob. 11PCh. 6.6 - a. What is the major product or each or the...Ch. 6.6 - Prob. 14PCh. 6.6 - Prob. 15PCh. 6.7 - What is the major product obtained from the...Ch. 6.8 - Which is more highly regionselective: reaction of...Ch. 6.8 - Prob. 19PCh. 6.9 - What will be the product of the preceding reaction...Ch. 6.9 - Prob. 21PCh. 6.9 - Prob. 22PCh. 6.9 - Prob. 23PCh. 6.9 - What is the product of the addition of 1Cl to...Ch. 6.9 - What will be the major product obtained from the...Ch. 6.9 - Propose a mechanism for the following reaction:Ch. 6.10 - Draw structures for the following: a. 24...Ch. 6.10 - What alkene would you treat with a peroxyacid in...Ch. 6.11 - What products are formed when the following...Ch. 6.11 - Prob. 31PCh. 6.11 - Prob. 32PCh. 6.11 - The following product was obtained from the...Ch. 6.12 - What characteristics must the reactant of a...Ch. 6.13 - Prob. 36PCh. 6.13 - What stereoisomers are obtained from each of the...Ch. 6.13 - Prob. 41PCh. 6.13 - Prob. 42PCh. 6.13 - Prob. 43PCh. 6.13 - Prob. 45PCh. 6.13 - Prob. 46PCh. 6.13 - Prob. 47PCh. 6.13 - Prob. 48PCh. 6.13 - Prob. 49PCh. 6.13 - Prob. 50PCh. 6.14 - Prob. 51PCh. 6.16 - Prob. 53PCh. 6.16 - Explain why 3-methykyclohexene should not be used...Ch. 6 - Prob. 55PCh. 6 - Prob. 56PCh. 6 - Prob. 57PCh. 6 - What is the major product of the reaction of...Ch. 6 - Give two names for each of the following:Ch. 6 - Prob. 60PCh. 6 - What are the products of the following reactions?...Ch. 6 - When 3-methyl-1-butene reacts with HBr, two alkyl...Ch. 6 - Draw curved arrows to show the flow of electrons...Ch. 6 - What reagents are needed to carry out the...Ch. 6 - Prob. 65PCh. 6 - Prob. 66PCh. 6 - Prob. 67PCh. 6 - What is more stable? a. CH3C+HCH3orCH3C+HCH2ClCh. 6 - Prob. 69PCh. 6 - a. Draw the product or products that will be...Ch. 6 - Prob. 71PCh. 6 - The second-order rate constant (in units of M1s1)...Ch. 6 - Which compound has the greater dipole moment?Ch. 6 - Prob. 74PCh. 6 - Prob. 75PCh. 6 - Prob. 76PCh. 6 - Prob. 77PCh. 6 - Prob. 78PCh. 6 - Prob. 79PCh. 6 - Prob. 80PCh. 6 - Prob. 81PCh. 6 - Prob. 82PCh. 6 - Prob. 83PCh. 6 - Prob. 84PCh. 6 - Prob. 85PCh. 6 - Prob. 86PCh. 6 - Draw the products of the following reactions. If...Ch. 6 - Prob. 88PCh. 6 - Prob. 89PCh. 6 - Prob. 90PCh. 6 - Two chemists at Dupont found that lCH2Znl is...Ch. 6 - Prob. 92PCh. 6 - Prob. 93PCh. 6 - What alkene gives the product shown after...Ch. 6 - Prob. 95PCh. 6 - Prob. 96PCh. 6 - Prob. 97PCh. 6 - Prob. 98PCh. 6 - Prob. 99PCh. 6 - Prob. 100PCh. 6 - Propose a mechanism for the following reaction:Ch. 6 - Prob. 102PCh. 6 - Prob. 103P
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- What characterizes a pericyclic reaction?arrow_forwardchoices are: permanganate test, lucas test, ferric chloride, tollen's, iodoform, 2,4-DNP, molisch, benedict'sarrow_forwardSuggest chemical tests to differentiate the following pairs of organic compounds given the chemical reaction for the positive sign. Write the observable change for the positive sign of reaction and the chemical reaction for the compound that will test positive.arrow_forward
- complete the table by suggesting chemical tests to differentiate the following compounds and write the positive sign and the compound that will test positivearrow_forwardThe conversion of butane to 2-methylpropane is an equilibrium process with ΔH° = −2.05 kcal/mol and ΔG° = −0.89 kcal/mol. What is the change in entropy for this conversion? What is the equilibrium constant for this reaction?arrow_forward3,4-Dimethylpent-1-ene has the formula CH2“CH¬CH(CH3)¬CH(CH3)2. When pure (R)-3,4-dimethylpent-1-ene is treated with hydrogen over a platinum catalyst, the product is (S)-2,3-dimethylpentane. How useful is the (R) or (S) designation for predicting the sign of an optical rotation? Can you predict the sign of the rotation of the reactant? Of the product? (Hint from Juliet Capulet: “What’s in a name? That which we call a rose/By any other name would smell as sweet.”arrow_forward
- choices are: permanganate test, lucas test, ferric chloride, tollen's, iodoform, 2,4-DNP, molisch, benedict's A. Suggest chemical tests to differentiate the following pairs of organic compounds given the chemical reaction for the positive sign. Write the observable change for the positive sign of reaction and the chemical reaction for the compound that will test positive. Chemical Test and Positive Sign of Reaction Test: Compound which will Test Positive Chemical Reaction for the Positive Sign он H;C CH, Positive Sign: Su1 halogenation `CH3 2-pentanone OH H3C 2-pentanol Test: он haloform formation H,C Positive Sign: CH3 isopropyl alcohol он 1-propanol Test: OH Positive Sign: complex formation HO, resorcinol benzyl alcohol Test: hydrazone formation Positive Sign: | cyclohexanecarbaldehyde cyclohexenearrow_forwardWhat are the consequences to the formation of carbocation intermediates ?arrow_forwardAnswer all the subparts pertaining to question 4arrow_forward
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