INTREPRETATION: The products obtained from addition of B r 2 to cyclohexene in presence of H 2 O should be determined. CONCEPT INTRODUCTION: Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation. Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom. Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation. Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants. The curved arrows are generally used to indicate the flow of electrons present in the reaction. Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction. In addition reaction of alkenes when two substituents are placed on same side of C = C then it is named as s y n addition if it is placed on opposite sides of C = C it is defined as anti-addition. Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms. Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound. Carbocation: it is carbon ion that bears a positive charge on it. Carbocation stability order:

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Answer 1

Question

Chapter 6.13, Problem 47P

(a)

Interpretation Introduction

INTREPRETATION:

The products obtained from addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

(b)

Interpretation Introduction

INTREPRETATION:

The mechanism for addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

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Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 6.13, Problem 47P

(a)

Interpretation Introduction

INTREPRETATION:

The products obtained from addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

(b)

Interpretation Introduction

INTREPRETATION:

The mechanism for addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

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Answer 3

Question

Chapter 6.13, Problem 47P

(a)

Interpretation Introduction

INTREPRETATION:

The products obtained from addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

(b)

Interpretation Introduction

INTREPRETATION:

The mechanism for addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

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Answer 4

Question

Chapter 6.13, Problem 47P

(a)

Interpretation Introduction

INTREPRETATION:

The products obtained from addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

(b)

Interpretation Introduction

INTREPRETATION:

The mechanism for addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

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Answer 5

Chapter 6.13, Problem 47P

(a)

Interpretation Introduction

INTREPRETATION:

The products obtained from addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

(b)

Interpretation Introduction

INTREPRETATION:

The mechanism for addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

Answer 6

Chapter 6.13, Problem 47P

(a)

Interpretation Introduction

INTREPRETATION:

The products obtained from addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

Answer 7

Chapter 6.13, Problem 47P

(a)

Interpretation Introduction

INTREPRETATION:

The products obtained from addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

Answer 8

(b)

Interpretation Introduction

INTREPRETATION:

The mechanism for addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

Answer 9

(b)

Interpretation Introduction

INTREPRETATION:

The mechanism for addition of Br2 to cyclohexene in presence of H2O should be determined.

CONCEPT INTRODUCTION:

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.

The curved arrows are generally used to indicate the flow of electrons present in the reaction.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

In addition reaction of alkenes when two substituents are placed on same side of C=C then it is named as syn addition if it is placed on opposite sides of C=C it is defined as anti-addition.

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.

Oxidizing Reagents: The chemical agents used to add oxygen or remove hydrogen which finally reduced on oxidizing the other compound.

Carbocation: it is carbon ion that bears a positive charge on it.

Carbocation stability order:

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 6.1 - Draw the mechanism for the reaction of cyclohexene...Ch. 6.2 - a. How many bond orbitals are avilable for...Ch. 6.2 - Prob. 3P Ch. 6.2 - Prob. 4P Ch. 6.3 - Prob. 5P Ch. 6.4 - Prob. 6P Ch. 6.4 - Prob. 7P Ch. 6.4 - What alkene should be used to synthesize each of...Ch. 6.5 - The pKa of a protonated alcohol is about 2.5, and...Ch. 6.5 - Prob. 10P

Solution Summary: The author explains that the products obtained from addition of Br_2 to cyclohexene should be determined.

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Chapter 6 Solutions