The polymerization of 2,2-dimethyloxirane should be described by anionic mechanism. Concept Introduction: Anionic polymerization: Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium. Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

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Answer 1

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.6, Problem 10P

(a)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by anionic mechanism.

Concept Introduction:

Anionic polymerization:

Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium.

Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

(b)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by cationic mechanism.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 2

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.6, Problem 10P

(a)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by anionic mechanism.

Concept Introduction:

Anionic polymerization:

Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium.

Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

(b)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by cationic mechanism.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.6, Problem 10P

(a)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by anionic mechanism.

Concept Introduction:

Anionic polymerization:

Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium.

Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

(b)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by cationic mechanism.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.6, Problem 10P

(a)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by anionic mechanism.

Concept Introduction:

Anionic polymerization:

Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium.

Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

(b)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by cationic mechanism.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 5

Chapter 27.6, Problem 10P

(a)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by anionic mechanism.

Concept Introduction:

Anionic polymerization:

Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium.

Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

(b)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by cationic mechanism.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 6

Chapter 27.6, Problem 10P

(a)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by anionic mechanism.

Concept Introduction:

Anionic polymerization:

Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium.

Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

Answer 7

Chapter 27.6, Problem 10P

(a)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by anionic mechanism.

Concept Introduction:

Anionic polymerization:

Initiator will be a nucleophile which reacts with the monomer to form a propagating site that is an anion and the initiator can be compounds like sodium amide or butyllithium.

Nucleophile will attack on the alkene and the alkene contains a substituent that can withdraw electrons by resonance.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by cationic mechanism.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The polymerization of 2,2-dimethyloxirane should be described by cationic mechanism.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 27.3 - Prob. 1P Ch. 27.3 - Prob. 2P Ch. 27.3 - Prob. 3P Ch. 27.3 - Prob. 4P Ch. 27.3 - Prob. 5P Ch. 27.3 - Prob. 6P Ch. 27.4 - Prob. 7P Ch. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P

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Chapter 27 Solutions