Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 27, Problem 35P
Five different repeating units are found in the
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Chapter 27 Solutions
Organic Chemistry (8th Edition)
Ch. 27.3 - Prob. 1PCh. 27.3 - Prob. 2PCh. 27.3 - Prob. 3PCh. 27.3 - Prob. 4PCh. 27.3 - Prob. 5PCh. 27.3 - Prob. 6PCh. 27.4 - Prob. 7PCh. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P
Ch. 27.6 - Explain why, when propylene oxide undergoes...Ch. 27.6 - Which monomer and which type of initiator can you...Ch. 27.6 - Prob. 13PCh. 27.8 - Draw a short segment of gutta-percha.Ch. 27.8 - Prob. 15PCh. 27.11 - Prob. 16PCh. 27.11 - Write an equation that explains what happens if a...Ch. 27.11 - What happens to polyester slacks if aqueous NaOH...Ch. 27.11 - a. Propose a mechanism for the formation of the...Ch. 27.11 - Explain why, when a small amount of glycerol is...Ch. 27.12 - Propose a mechanism for the formation of melmac.Ch. 27.12 - Prob. 22PCh. 27.13 - Prob. 23PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Prob. 25PCh. 27 - Prob. 26PCh. 27 - Draw the structure of the monomer or monomers used...Ch. 27 - Prob. 28PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Quiana is a synthetic fabric that feels very much...Ch. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Prob. 33PCh. 27 - Poly(vinyl alcohol) is a polymer used to make...Ch. 27 - Five different repeating units are found in the...Ch. 27 - Prob. 37PCh. 27 - A particularly strong and rigid polyester used for...Ch. 27 - Prob. 39PCh. 27 - Which Monomer gives a greater yield of polymer,...Ch. 27 - Prob. 41PCh. 27 - Prob. 42PCh. 27 - Why do vinyl raincoats become brittle as they get...Ch. 27 - The polymer shown below is synthesized by...Ch. 27 - Prob. 45PCh. 27 - How can head-to-head poly(vinyl bromide) be...Ch. 27 - Delrin (polyoxymethylene) is a tough...
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- What polymer is formed when CH2=CHCO2H (acrylic acid) is polymerized toform poly(acrylic acid)?arrow_forwardKodel is a condensation polymer made from terephthalic acid and 1,4-cyclohexanedimethanol. Write the structure of the resulting polymer.arrow_forwardPoly(lactic acid) (PLA) has received much recent attention because the lactic acid monomer [CH3CH(OH)COOH] from which it is made can be obtained from carbohydrates rather than petroleum. This makes PLA a more “environmentally friendly” polyester. Draw the structure of PLAarrow_forward
- Explain the effects the addition of glycerol (a triol) will have on the molecular architecture of the following polymerization reactions: a) Condensation polymerization of terephthalic acid + ethylene glycol b) Condensation polymerization of 6-hydroxyhexanoic acidarrow_forwardDraw a pair of compounds that would react to give the polymer shownarrow_forward1.Consider the polymerization of the following monomers: H2N- -NH2 CI (a) Draw the repeat unit of the resulting polymer. (b) Identify the two structural units comprising the repeat unit. Aramids are produced using the reaction of a benzene-1,4-diamine and a terephthaloyl dichloride.arrow_forward
- explain the process by which alkenes begin the polymerization process, and how the process continues explain why the bonds of polymers made from alkenes are so stable.arrow_forwardDraw three segments of the polymer that is formed from 1,2-polymerization of 1,3-butadiene.arrow_forward18. Draw the alkene monomer from which the following polymer was made. CIH CIH CI H -c-c-c-c-c-c- |||||| HHHHHH 19. Assign an IUPAC name to each of the following substituted benzene compounds. Use the ortho,- meta- and para-prefix system. (watch for toluene!) Br b. F a. Br CH₂arrow_forward
- What polymers are formed from each monomer?arrow_forwardfind the molecular formula of alkyne when it is known that a mass of 10.8 grams of alkyne completely adds 64 grams of bromine.Alkine forms precipitates when treated with Ag + ammonia solution. After finding the molecular formula of alkyne write the polymerization reaction with three monomer units.arrow_forwardNomex, another aromatic polyamide (compare aramid), is prepared by polymerization of 1,3-benzenediamine and the diacid chloride of 1,3-benzenedicarboxylic acid. The physical properties of the polymer make it suitable for high-strength, high-temperature applications such as parachute cords and jet aircraft tires. Draw a structural formula for the repeating unit of Nomex. H,N. NH2 CI polymerization Nomex 1,3-Benzenediamine 1,3-Benzene- dicarbonyl chloridearrow_forward
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