Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 27, Problem 40P
Which Monomer gives a greater yield of
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A particularly strong and rigid polyester used for electronic parts is marketed under the trade name Glyptal. It is a polymer of terephthalic acid and glycerol. Draw a segment of the polymer and explain why it is so strong.
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Draw the structure of the polymer formed from ring-opening metathesis polymerization (ROMP) of each monomer.
Chapter 27 Solutions
Organic Chemistry (8th Edition)
Ch. 27.3 - Prob. 1PCh. 27.3 - Prob. 2PCh. 27.3 - Prob. 3PCh. 27.3 - Prob. 4PCh. 27.3 - Prob. 5PCh. 27.3 - Prob. 6PCh. 27.4 - Prob. 7PCh. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P
Ch. 27.6 - Explain why, when propylene oxide undergoes...Ch. 27.6 - Which monomer and which type of initiator can you...Ch. 27.6 - Prob. 13PCh. 27.8 - Draw a short segment of gutta-percha.Ch. 27.8 - Prob. 15PCh. 27.11 - Prob. 16PCh. 27.11 - Write an equation that explains what happens if a...Ch. 27.11 - What happens to polyester slacks if aqueous NaOH...Ch. 27.11 - a. Propose a mechanism for the formation of the...Ch. 27.11 - Explain why, when a small amount of glycerol is...Ch. 27.12 - Propose a mechanism for the formation of melmac.Ch. 27.12 - Prob. 22PCh. 27.13 - Prob. 23PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Prob. 25PCh. 27 - Prob. 26PCh. 27 - Draw the structure of the monomer or monomers used...Ch. 27 - Prob. 28PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Quiana is a synthetic fabric that feels very much...Ch. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Prob. 33PCh. 27 - Poly(vinyl alcohol) is a polymer used to make...Ch. 27 - Five different repeating units are found in the...Ch. 27 - Prob. 37PCh. 27 - A particularly strong and rigid polyester used for...Ch. 27 - Prob. 39PCh. 27 - Which Monomer gives a greater yield of polymer,...Ch. 27 - Prob. 41PCh. 27 - Prob. 42PCh. 27 - Why do vinyl raincoats become brittle as they get...Ch. 27 - The polymer shown below is synthesized by...Ch. 27 - Prob. 45PCh. 27 - How can head-to-head poly(vinyl bromide) be...Ch. 27 - Delrin (polyoxymethylene) is a tough...
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- Poly(trimethylene carbamate) is used in high-quality synthetic leather.Draw the products that would be formed if the polymer were completelyhydrolyzed under acidic or basic conditions.arrow_forwardPoly(lactic acid) (PLA) has received much recent attention because the lactic acid monomer [CH3CH(OH)COOH] from which it is made can be obtained from carbohydrates rather than petroleum. This makes PLA a more “environmentally friendly” polyester. Draw the structure of PLAarrow_forwardKodel is a condensation polymer made from terphthalic acid and 1,4-cyclohexandethanol. Write the structure of the resulting polymer.arrow_forward
- 2-methylbut-1-ene can form a polymer State the type of polymerisation? Draw the repeating unit for the polymer formed? Type of polymerisation? Repeatingarrow_forwardExplain the effects the addition of glycerol (a triol) will have on the molecular architecture of the following polymerization reactions: a) Condensation polymerization of terephthalic acid + ethylene glycol b) Condensation polymerization of 6-hydroxyhexanoic acidarrow_forwardWhat polymer is formed in this reaction, using polymer notation?arrow_forward
- Classify each polymer below as step-growth or chain-growth. Place the appropriate term in the blank provided. CH₂-CHarrow_forward1. Draw the structure of the monomer that is responsible for the following polymer: -CH,-CH-arrow_forwardA thermosetting material called polyester is made when a carboxylic acid reacts with dialcohol. Write the condensation polymerization with byproduct. The monomers of carboxylic acid and dialcohol are respectively: HO-C -C-OH HO-CH,CH,-OHarrow_forward
- What monomer is used to form poly(vinyl acetate), a polymer used in paints and adhesives?arrow_forwardPoly(lactic acid) (PLA) has received much recent attention because the lactic acid monomer [CH3CH(OH)COOH] from which it is made can be obtained from carbohydrates rather than petroleum. This makes PLA a more “environmentally friendly” polyester. (A more in-depth discussion of green polymer synthesis is presented in Chapter 30.) Draw the structure of PLA.arrow_forwardIn addition to glycolic and lactic acids (Section 31.6B), dissolving sutures can also be prepared from each of the following lactone monomers. Draw the structure of the polymer formed from each monomer. a. polycaprolactone b. polydioxanone E-caprolactone p-dioxanonearrow_forward
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