Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 27.8, Problem 15P
(a)
Interpretation Introduction
Interpretation:
The three segment of 1,4-polymerized product of 1,3-butadiene has to be drawn.
Concept introduction:
Monomers combine together to form polymers. Monomers are the repeating units of small molecules which link together to form polymers and the process is called as
Two types of polymers:
- Synthetic and biopolymers.
- DNA is an example for biopolymer and these type of polymers are synthesized by cells.
- Polymers synthesized by scientists are called
synthetic polymers and some examples are nylon, polyester etc.
Two types of synthetic polymers:
- Chain-growth
polymers or addition polymers and Step-growthpolymers or Condensation polymers. - Chain growth polymers are formed by the monomer addition to the end of a growing chain.
- Step-growth polymers are formed by combining monomers by removing small molecules of water or alcohol.
(b)
Interpretation Introduction
Interpretation:
The three segment of 1,2-polymerized product of 1,3-butadiene has to be drawn.
Concept introduction:
Polymers:
Monomers combine together to form polymers. Monomers are the repeating units of small molecules which link together to form polymers and the process is called as polymerization.
Two types of polymers:
- Synthetic and biopolymers.
- DNA is an example for biopolymer and these type of polymers are synthesized by cells.
- Polymers synthesized by scientists are called synthetic polymers and some examples are nylon, polyester etc.
Two types of synthetic polymers:
- Chain-growth polymers or addition polymers and Step-growth polymers or Condensation polymers.
- Chain growth polymers are formed by the monomer addition to the end of a growing chain.
- Step-growth polymers are formed by combining monomers by removing small molecules of water or alcohol.
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Draw three segments of the polymer that is formed from 1,2-polymerization of 1,3-butadiene.
Polypropene results from the polymerization of
H
H
A. CH-C
B. CH-C
c. CH-c
ĆN
D. CH-C
E. CH-C
Multiple Choice
18. Draw the alkene monomer from which the following polymer was made.
CIH CIH CI H
-c-c-c-c-c-c-
||||||
HHHHHH
19. Assign an IUPAC name to each of the following substituted benzene compounds. Use the ortho,-
meta- and para-prefix system. (watch for toluene!)
Br
b.
F
a.
Br
CH₂
Chapter 27 Solutions
Organic Chemistry (8th Edition)
Ch. 27.3 - Prob. 1PCh. 27.3 - Prob. 2PCh. 27.3 - Prob. 3PCh. 27.3 - Prob. 4PCh. 27.3 - Prob. 5PCh. 27.3 - Prob. 6PCh. 27.4 - Prob. 7PCh. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P
Ch. 27.6 - Explain why, when propylene oxide undergoes...Ch. 27.6 - Which monomer and which type of initiator can you...Ch. 27.6 - Prob. 13PCh. 27.8 - Draw a short segment of gutta-percha.Ch. 27.8 - Prob. 15PCh. 27.11 - Prob. 16PCh. 27.11 - Write an equation that explains what happens if a...Ch. 27.11 - What happens to polyester slacks if aqueous NaOH...Ch. 27.11 - a. Propose a mechanism for the formation of the...Ch. 27.11 - Explain why, when a small amount of glycerol is...Ch. 27.12 - Propose a mechanism for the formation of melmac.Ch. 27.12 - Prob. 22PCh. 27.13 - Prob. 23PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Prob. 25PCh. 27 - Prob. 26PCh. 27 - Draw the structure of the monomer or monomers used...Ch. 27 - Prob. 28PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Quiana is a synthetic fabric that feels very much...Ch. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Prob. 33PCh. 27 - Poly(vinyl alcohol) is a polymer used to make...Ch. 27 - Five different repeating units are found in the...Ch. 27 - Prob. 37PCh. 27 - A particularly strong and rigid polyester used for...Ch. 27 - Prob. 39PCh. 27 - Which Monomer gives a greater yield of polymer,...Ch. 27 - Prob. 41PCh. 27 - Prob. 42PCh. 27 - Why do vinyl raincoats become brittle as they get...Ch. 27 - The polymer shown below is synthesized by...Ch. 27 - Prob. 45PCh. 27 - How can head-to-head poly(vinyl bromide) be...Ch. 27 - Delrin (polyoxymethylene) is a tough...
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