Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 27.12, Problem 22P
Interpretation Introduction
Interpretation:
A structure for Bakelite has to be proposed.
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Bakelite, a durable plastic used for the casing of early radios and TVs, was the first of the thermosetting polymers. It is a highly cross-linked polymer formed from the acid-catalyzed polymerization of phenol and formaldehyde. Because it is much darker than Melmac, Bakelite’s range of colors is limited. Propose a structure for Bakelite.
Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of
applications. It is produced via chain-growth polymerization from the monomer propylene. Poiypropylene belongs to the group of
polyolefins and is partialy crystalline and non-polar.
CH,
-CH,CH-CH,CH–CH,CH-CH,CH-CH,CH-CH,CH-
ÇH,
ÇH,
CH,
CH,
Draw the syndiotactic and isotactic forms of PP.
11. In condensation polymerization the by
product formed is
Choose
Охудen
Nitrogen
Water
Hydrogen
Chapter 27 Solutions
Organic Chemistry (8th Edition)
Ch. 27.3 - Prob. 1PCh. 27.3 - Prob. 2PCh. 27.3 - Prob. 3PCh. 27.3 - Prob. 4PCh. 27.3 - Prob. 5PCh. 27.3 - Prob. 6PCh. 27.4 - Prob. 7PCh. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P
Ch. 27.6 - Explain why, when propylene oxide undergoes...Ch. 27.6 - Which monomer and which type of initiator can you...Ch. 27.6 - Prob. 13PCh. 27.8 - Draw a short segment of gutta-percha.Ch. 27.8 - Prob. 15PCh. 27.11 - Prob. 16PCh. 27.11 - Write an equation that explains what happens if a...Ch. 27.11 - What happens to polyester slacks if aqueous NaOH...Ch. 27.11 - a. Propose a mechanism for the formation of the...Ch. 27.11 - Explain why, when a small amount of glycerol is...Ch. 27.12 - Propose a mechanism for the formation of melmac.Ch. 27.12 - Prob. 22PCh. 27.13 - Prob. 23PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Prob. 25PCh. 27 - Prob. 26PCh. 27 - Draw the structure of the monomer or monomers used...Ch. 27 - Prob. 28PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Quiana is a synthetic fabric that feels very much...Ch. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Prob. 33PCh. 27 - Poly(vinyl alcohol) is a polymer used to make...Ch. 27 - Five different repeating units are found in the...Ch. 27 - Prob. 37PCh. 27 - A particularly strong and rigid polyester used for...Ch. 27 - Prob. 39PCh. 27 - Which Monomer gives a greater yield of polymer,...Ch. 27 - Prob. 41PCh. 27 - Prob. 42PCh. 27 - Why do vinyl raincoats become brittle as they get...Ch. 27 - The polymer shown below is synthesized by...Ch. 27 - Prob. 45PCh. 27 - How can head-to-head poly(vinyl bromide) be...Ch. 27 - Delrin (polyoxymethylene) is a tough...
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Similar questions
- Polyvinyl acetate (PVA), a component of adhesives like wood glue or school glue, PVA forms by addition polymerization. Draw the monomer. Include all HH atoms.arrow_forwardWhat monomer(s) are used to prepare each polymer or copolymer?arrow_forwardPoly(vinyl alcohol), a hydrophilic polymer used in aqueous adhesives, is made by polymerizing vinyl acetate and then hydrolyzing the ester linkages. We have seen that basic hydrolysis destroys the Dacron polymer. Poly(vinyl acetate) is converted to poly(vinyl alcohol) by a basic hydrolysis of the ester groups. Why doesn’t the hydrolysis destroy the poly(vinyl alcohol)polymer?arrow_forward
- The structure of propylene is shown. This alkene undergoes addition polymerization to form polypropylene, a thermoplastic polymer with many different applications.arrow_forward7. When asymmetric alkenes polymerize (such as chloroethene to produce PVC), the pendant group like chlorine can be arranged in different ways. An arrangement in which the -Cl groups are arranged on the same side of the polymer chain is called a(n) , a. Atactic b. Isotactic arrangement. c. Syndiotactic d. Sporadic 8. Kevlar is a type of polymer which has a great resistance to tear. Its application includes its use in making bulletproof vests and radial tires. The two monomers used to make Kevlar are the following: H H H-O- c-0-H H-N- -N-H Monomer One Monomer Two When these two monomers join a. A molecule of CO2 will be eliminated and an ester linkage will form b. Nothing will be eliminated and the two monomers will be linked through a hydrogen to hydrogen bond c. A water molecule will be eliminated and a peptide linkage will be formed d. Nothing will be eliminated. The two monomers will be linked by a carbon-carbon bond.arrow_forwardDraw the structure of PEF, polyethylene furanoate, a condensation polymer formed from furandicarboxylic acid and ethylene glycol. PEF, which can be synthesized from precursors that are obtained from renewable resources, has many of the same properties as polyethylene terephthalate (PET).arrow_forward
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