Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 27.5, Problem 8P
Rank the following groups of monomers from most able to least able to undergo anionic
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Chapter 27 Solutions
Organic Chemistry (8th Edition)
Ch. 27.3 - Prob. 1PCh. 27.3 - Prob. 2PCh. 27.3 - Prob. 3PCh. 27.3 - Prob. 4PCh. 27.3 - Prob. 5PCh. 27.3 - Prob. 6PCh. 27.4 - Prob. 7PCh. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P
Ch. 27.6 - Explain why, when propylene oxide undergoes...Ch. 27.6 - Which monomer and which type of initiator can you...Ch. 27.6 - Prob. 13PCh. 27.8 - Draw a short segment of gutta-percha.Ch. 27.8 - Prob. 15PCh. 27.11 - Prob. 16PCh. 27.11 - Write an equation that explains what happens if a...Ch. 27.11 - What happens to polyester slacks if aqueous NaOH...Ch. 27.11 - a. Propose a mechanism for the formation of the...Ch. 27.11 - Explain why, when a small amount of glycerol is...Ch. 27.12 - Propose a mechanism for the formation of melmac.Ch. 27.12 - Prob. 22PCh. 27.13 - Prob. 23PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Prob. 25PCh. 27 - Prob. 26PCh. 27 - Draw the structure of the monomer or monomers used...Ch. 27 - Prob. 28PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Quiana is a synthetic fabric that feels very much...Ch. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Prob. 33PCh. 27 - Poly(vinyl alcohol) is a polymer used to make...Ch. 27 - Five different repeating units are found in the...Ch. 27 - Prob. 37PCh. 27 - A particularly strong and rigid polyester used for...Ch. 27 - Prob. 39PCh. 27 - Which Monomer gives a greater yield of polymer,...Ch. 27 - Prob. 41PCh. 27 - Prob. 42PCh. 27 - Why do vinyl raincoats become brittle as they get...Ch. 27 - The polymer shown below is synthesized by...Ch. 27 - Prob. 45PCh. 27 - How can head-to-head poly(vinyl bromide) be...Ch. 27 - Delrin (polyoxymethylene) is a tough...
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- Discuss TWO (2) most important differences between addition and stepgrowth polymerizations.arrow_forwardOne common type of cation exchange resin is prepared by polymerization of a mixture containing styrene and 1,4-divinylbenzene . The polymer is then treated with concentrated sulfuric acid to sulfonate a majority of the aromatic rings in the polymer. Q.) Explain how this sulfonated polymer can act as a cation exchange resinarrow_forwardTritan is a polymer marketed to consumers looking for BPA-free products. Although the detailed structure of Tritan is protected by patent, it is known to be a polyester (not a polycarbonate) composed of three monomers—dimethyl terephthalate, 2,2,4,4- tetramethylcyclobutane-1,3-diol, and 1,4-cyclohexanedimethanol. Propose a possible structure for Tritan from dimethyl terephthalate and the two diols drawn.arrow_forward
- Consider monomers A–C. (a) Rank the monomers in order of increasingreactivity in cationic polymerization. (b) Rank the monomers in order ofincreasing reactivity in anionic polymerization.arrow_forward1- 2- 3- 4- Two organic compounds react together to form a polymer as shown. HO-CH₂-CH₂-OH + HO-C-CH₂-C-OH-Polymer X+ Product Y O -CH₂-1-0-CH₂- -0-C-CH₂-C-O-CH₂-0-C-CH₂-C---- --CH₂-CH₂-C-0-CH₂-0-C--- i CH, CH O O --0-C-CH₂-C-O-CH₂-CH₂---- O O --C-CH₂-CH₂-C-0-CH₂-CH₂-O-.. O Using the information above complete these statements. Polymer X is number and product Y is a molecule called If you classified this polymerization it would be called (hint: think of one of the products formed) polymerizationarrow_forwardNH2 Dry-erase boards, or whiteboards, in classrooms consist of a network polymer similar to Bakelite that is made from formaldehyde and melamine. (a) Propose a structure for the polymer formed. (b) Why is this type of polymer suitable for use in whiteboards? 'N. H2N `NH2 Melaminearrow_forward
- What is the basic mechanism of an Anionic polymer (acrylic acid based as carbomers) in regards to function and “activation”? How do they work and thicken?arrow_forward(asap)arrow_forwardCompound A is a novel poly(ester amide) copolymer that can be used as a bioabsorbable coating for the controlled release of drugs. A is a copolymer of four monomers, two of which are amino acids or amino acid derivatives. The body’s enzymes recognize the naturally occurring amino acids in the polymer backbone, allowing for controlled enzymatic breakdown of the polymer and steady release of an encapsulated drug. Identify the four monomers used to synthesize A; then use Figure 29.2 to name the two amino acids.Figure 29.2: The 20 naturally occurring amino acidsarrow_forward
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