Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 27, Problem 37P
Interpretation Introduction

Interpretation:

The short segment of the polymer obtained by adding 1,4-divinylbenzene to the reaction mixture of peroxide and styrene should be drawn.

Concept Introduction:

Polymers:

Monomers combine together to form polymers.  Monomers are the repeating units of small molecules which link together to form polymers and the process is called as polymerization.

Two types of polymers:

  • Synthetic and biopolymers.
  • DNA is an example for biopolymer and these type of polymers are synthesized by cells.
  • Polymers synthesized by scientists are called synthetic polymers and some examples are nylon, polyester etc.

Two types of synthetic polymers:

  • Chain-growth polymers or addition polymers and Step-growth polymers or Condensation polymers.
  • Chain growth polymers are formed by the monomer addition to the end of a growing chain.
  • Step-growth polymers are formed by combining monomers by removing small molecules of water or alcohol.

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If a peroxide is added to styrene, the polymer known as polystyrene is formed. If a small amount of 1,4-divinylbenzene is added to the reaction mixture, a stronger and more rigid polymer is formed. Draw a short section of this more rigid polymer.
Poly(trimethylene carbamate) is used in high-quality synthetic leather.Draw the products that would be formed if the polymer were completelyhydrolyzed under acidic or basic conditions.
Kodel is a condensation polymer made from terphthalic acid and 1,4-cyclohexandethanol. Write the structure of the resulting polymer.

Chapter 27 Solutions

Organic Chemistry (8th Edition)

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