Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 27.3, Problem 4P
Interpretation Introduction

Interpretation:

The mechanism for the formation of a segment of poly vinyl chloride that contains three units of vinyl chloride and is initiated by hydrogen peroxide should be given.

Concept Introduction:

Polymers:

Monomers combine together to form polymers.  Monomers are the repeating units of small molecules which link together to form polymers and the process is called as polymerization.

Two types of polymers:

  • Synthetic and biopolymers.
  • DNA is an example for biopolymer and these type of polymers are synthesized by cells.
  • Polymers synthesized by scientists are called synthetic polymers and some examples are nylon, polyester etc.

Two types of synthetic polymers:

  • Chain-growth polymers or addition polymers and Step-growth polymers or Condensation polymers.
  • Chain growth polymers are formed by the monomer addition to the end of a growing chain.
  • Step-growth polymers are formed by combining monomers by removing small molecules of water or alcohol.

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Students have asked these similar questions
Draw the mechanism for the production of Nylon, identify the new linkage that has formed as a result of polymerization. What is the name of this linkage in organic chemistry?
Research in the “unzipping” of poly(vinyl chloride) indicates that certain defects in the polymer contribute to the rate of unzipping. These defects are arrangements of atoms that are different from the arrangements in the repeating unit shown in the condensed formula. Researchers have found that defects involving allylic chlorides and tertiary chlorides, specifically, promote the reaction. Review the mechanism for the unzipping and explain this observation.
Show the differences between the chain-growth and step-growth mechanisms of polymerization.

Chapter 27 Solutions

Organic Chemistry (8th Edition)

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