EBK ORGANIC CHEMISTRY7th EditionBruice Publisher: VSTISBN: 9780133556186
EBK ORGANIC CHEMISTRY
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Chapter 1 - Remembering General Chemistry: Electronic Structure And BondingChapter 1.1 - The Structure Of An AtomChapter 1.2 - How The Electrons In An Atom Are DistributedChapter 1.3 - Ionic And Covalent BondsChapter 1.4 - How The Structure Of A Compound Is RepresentedChapter 1.5 - Atomic OrbitalsChapter 1.6 - An Introduction To Molecular Orbital TheoryChapter 1.7 - How Single Bonds Are Formed In Organic CompoundsChapter 1.9 - How A Triple Bond Is Formed: The Bonds In EthyneChapter 1.11 - The Bonds In Ammonia And In The Ammonium Ion
Chapter 1.12 - The Bonds In WaterChapter 1.13 - The Bond In A Hydrogen HalideChapter 1.14 - Hybridization And Molecular GeometryChapter 1.15 - Summay: Hybridization, Bond Lengths, Bond Strengths, And Bond AnglesChapter 1.16 - The Dipole Moments Of MoleculesChapter 2 - Acids And Bases: Central To Understanding Organic ChemistryChapter 2.1 - An Introduction To Acids And BasesChapter 2.2 - Pka And PhChapter 2.3 - Organic Acids And BasesChapter 2.4 - How To Predict The Outcome Of An Acid-base ReactionChapter 2.5 - How To Determine The Position Of EquilibriumChapter 2.6 - How The Structure Of An Acid Affects Its Pka ValueChapter 2.7 - How Substituents Affect The Strength Of An AcidChapter 2.8 - An Introduction To Delocalized ElectronsChapter 2.9 - A Summary Of The Factors That Determine Acid StrengthChapter 2.10 - How Ph Affects The Structure Of An Organic CompoundChapter 2.11 - Buffer SolutionsChapter 2.12 - Lewis Acids And BasesChapter 3 - An Introduction To Organic Compounds: Nomenclature, Physical Properties, And Representation Of StructureChapter 3.1 - How Alkyl Substituents Are NamedChapter 3.2 - The Nomenclature Of AlkanesChapter 3.3 - The Nomenclature Of Cycloalkanes • Skeletal StructuresChapter 3.4 - The Nomenclature Of Alkyl HalidesChapter 3.5 - The Nomenclature Of EthersChapter 3.6 - The Nomenclature Of AlcoholsChapter 3.7 - The Nomenclature Of AminesChapter 3.8 - The Structures Of Alkyl Halides, Alcohols, Ethers, And AminesChapter 3.9 - The Physical Properties Of Alkanes, Alkyl Halides, Alcohols, Ethers, And AminesChapter 3.10 - Rotation Occurs About Carbon-carbon Single BondsChapter 3.11 - Some Cycloalkanes Have Angle StrainChapter 3.12 - Conformers Of CyclohexaneChapter 3.13 - Conformers Of Monosubstituted CyclohexanesChapter 3.14 - Conformers Of Disubstituted CyclohexanesChapter 4 - Isomers: The Arrangement Of Atoms In SpaceChapter 4.1 - Cis-trans Isomers Result From Restricted RotationChapter 4.2 - A Chiral Object Has A Nonsuperimposable Mirror ImageChapter 4.3 - An Asymmetric Center Is A Cause Of Chirality In A MoleculeChapter 4.4 - Isomers With One Asymmetric CenterChapter 4.6 - How To Draw EnantiomersChapter 4.7 - Naming Enantiomers By The R,s SystemChapter 4.8 - Chiral Compounds Are Optically ActiveChapter 4.9 - How Specific Rotation Is MeasuredChapter 4.10 - Enantiomeric ExcessChapter 4.11 - Compounds With More Than One Asymmetric CenterChapter 4.12 - Stereoisomers Of Cyclic CompoundsChapter 4.13 - Meso Compounds Have Asymmetric Centers But Are Optically InactiveChapter 4.14 - How To Name Isomers With More Than One Asymmetric CenterChapter 4.15 - How Enantiomers Can Be SeparatedChapter 4.16 - Nitrogen And Phosphorous Atoms Can Be Asymmetric CentersChapter 5 - Alkenes: Structure, Nomenclature, And An Introduction To Reactivity • Thermodynamics And KineticsChapter 5.1 - Molecular Formulas And The Degree Of UnsaturationChapter 5.2 - The Nomenclature Of AlkenesChapter 5.4 - Naming Alkenes Using The E,z SystemChapter 5.6 - How Alkenes React • Curved Arrows Show The Flow Of ElectronsChapter 5.7 - Thermodynamics And KineticsChapter 5.9 - The Difference Between The Rate Of A Reaction And The Rate Constant For A ReactionChapter 5.10 - A Reaction Coordinate Diagram Describes The Energy Changes That Take Place During A ReactionChapter 5.11 - CatalysisChapter 6 - The Reaction Of Alkenes • The Stereochemistry Of Addition ReactionsChapter 6.1 - The Addition Of A Hydrogen Halide To An AlkeneChapter 6.2 - Carbocation Stability Depends On The Number Of Alkyl Groups Attached To The Positively Charged CarbonChapter 6.3 - What Does The Structure Of The Transition State Look Like?Chapter 6.4 - Electrophilic Addition Reactions Are RegioselectiveChapter 6.5 - The Addition Of Water To An AlkeneChapter 6.6 - The Addition Of An Alcohol To An AlkeneChapter 6.7 - A Carbocation Will Rearrange If It Can Form A More Stable CarbocationChapter 6.8 - The Addition Of Borane To An Alkene: Hydroboration-oxidationChapter 6.9 - The Addition Of A Halogen To An AlkeneChapter 6.10 - The Addition Of A Peroxyacid To An AlkeneChapter 6.11 - The Addition Of Ozone To An Alkene: OzonolysisChapter 6.12 - The Addition Of Hydrogen To An AlkeneChapter 6.13 - The Relative Stabilities Of AlkenesChapter 6.14 - Regioselective, Stereoselective, And Stereospecific ReactionsChapter 6.15 - The Stereochemistry Of Electrophilic Addition Reactions Of AlkenesChapter 6.16 - The Stereochemistry Of Enzyme-catalyzed ReactionsChapter 6.17 - Enantiomers Can Be Distinguished By Biological MoleculesChapter 6.18 - Reactions And SynthesisChapter 7 - The Reaction Of Alkynes • An Introduction To Multistep SynthesisChapter 7.1 - The Nomenclature Of AlkynesChapter 7.2 - How To Name A Compound That Has More Than One Functional GroupChapter 7.3 - The Physical Properties Of Unsaturated HydrocarbonsChapter 7.4 - The Structure Of AlkynesChapter 7.6 - The Addition Of Hydrogen Halides And The Addition Of Halogens To An AlkyneChapter 7.7 - The Addition Of Water To An AlkyneChapter 7.8 - The Addition Of Borane To An Alkyne: Hydroboration-oxidationChapter 7.9 - The Addition Of Hydrogen To An AlkyneChapter 7.10 - A Hydrogen Bonded To An Sp Carbon Is "acidic"Chapter 7.12 - An Introduction To Multistep SynthesisChapter 8 - Delocalized Electrons: Their Effect On Stability, Pka, And The Products Of A ReactionChapter 8.1 - Delocalized Electrons Explain Benzene's StructureChapter 8.4 - How To Draw Resonance ContributorsChapter 8.5 - The Predicted Stabilities Of Resonance ContributorsChapter 8.6 - Delocalization Energy Is The Additional Stability Delocalized Electrons Give To A CompoundChapter 8.8 - The Two Criteria For AromaticityChapter 8.9 - Applying The Criteria For AromaticityChapter 8.10 - Aromatic Heterocyclic CompoundsChapter 8.11 - AntiaromaticityChapter 8.12 - A Molecular Orbital Description Of Aromaticity And AntiaromaticityChapter 8.13 - More Examples That Show How Delocalized Electrons Increase StabilityChapter 8.14 - A Molecular Orbital Description Of StabilityChapter 8.15 - How Delocalized Electrons Affect Pka ValuesChapter 8.16 - Delocalized Electrons Can Affect The Product Of A ReactionChapter 8.17 - Reactions Of DienesChapter 8.18 - Thermodynamic Versus Kinetic ControlChapter 8.19 - The Diels-alder Reaction Is A 1,4-addition ReactionChapter 8.20 - Retrosynthetic Analysis Of The Diels-alder ReactionChapter 9 - Substitution Reactions Of Alkyl HalidesChapter 9.1 - The Mechanism For An Sn2 ReactionChapter 9.2 - Factors That Affect Sn2 ReactionsChapter 9.3 - The Mechanism For An Sn1 ReactionChapter 9.4 - Factors That Affect Sn1 ReactionsChapter 9.5 - Benzylic Halides, Allylic Halides, Vinylic Halides, And Aryl HalidesChapter 9.6 - Competition Between Sn2 And Sn1 ReactionsChapter 9.7 - The Role Of The Solvent In Sn1 And Sn2 ReactionsChapter 9.8 - Intermolecular Versus Intramolecular ReactionsChapter 9.9 - Methylating Agents Used By Chemists Versus Those Used By CellsChapter 10 - Elimination Reactions Of Alkyl Halides● Competition Between Substitution And EliminationChapter 10.2 - An E2 Reaction Is RegioselectiveChapter 10.3 - The E1 ReactionChapter 10.4 - Benzylic And Allylic HalidesChapter 10.5 - Competition Between E1 And E2 ReactionsChapter 10.6 - E1 And E2 Reactions Are StereoselectiveChapter 10.7 - Elimination From Substituted CyclohexanesChapter 10.8 - A Kinetic Isotope Effect Can Help Determine A MechanismChapter 10.9 - Competition Between Substitution And EliminationChapter 10.10 - Substitution And Elimination Reactions In SynthesisChapter 10.11 - Approaching The ProblemChapter 11 - Reactions Of Alcohols, Ethers, Epoxides, Amines, And ThiolsChapter 11.1 - Nucleophilic Substitution Reactions Of Alcohols: Forming Alkyl HalidesChapter 11.2 - Other Methods Used To Convert Alcohols Into Alkyl HalidesChapter 11.3 - Converting An Alcohol Into A Sulfonate EsterChapter 11.4 - Elimination Reactions Of Alcohols: DehydrationChapter 11.5 - Oxidation Of AlcoholsChapter 11.6 - Nucleophilic Substitution Reactions Of EthersChapter 11.7 - Nucleophilic Substitution Reactions Of EpoxidesChapter 11.8 - Arene OxidesChapter 11.9 - Amines Do Not Undergo Substitution Or Elimination ReactionsChapter 11.10 - Quaternary Ammonium Hydroxides Undergo Elimination ReactionsChapter 11.11 - Thiols, Sulfides, And Sulfonium SaltsChapter 12 - Organometallic CompoundsChapter 12.1 - Organolithium And Organomagnesium CompoundsChapter 12.2 - TransmetallationChapter 12.3 - OrganocupratesChapter 12.4 - Palladium-catalyzed Coupling ReactionsChapter 12.5 - Alkene MetathesisChapter 13 - Radicals • Reactions Of AlkanesChapter 13.2 - The Chlorination And Bromination Of AlkanesChapter 13.3 - Radical Stability Depends On The Number Of Alkyl Groups Attached To The Carbon With The Unpaired ElectronChapter 13.4 - The Distribution Of Products Depends On Probability And ReactivityChapter 13.5 - The Reactivity-selectivity PrincipleChapter 13.6 - Formation Of Explosive PeroxidesChapter 13.7 - The Addition Of Radicals To An AlkeneChapter 13.8 - The Stereochemistry Of Radical Substitution And Radical Addition ReactionsChapter 13.9 - Radical Substitution Of Benzylic And Allylic HydrogensChapter 13.10 - More Practice With Multistep SynthesisChapter 13.11 - Radical Reactions Occur In Biological SystemsChapter 14 - Mass Spectrometry, Infrared Spectroscopy, And Ultraviolet/visible SpectroscopyChapter 14.1 - Mass SpectrometryChapter 14.2 - The Mass Spectrum • FragmentationChapter 14.3 - Using The M/z Value Of The Molecular Ion To Calculate The Molecular FormulaChapter 14.4 - Isotopes In Mass SpectrometryChapter 14.5 - High-resolution Mass Spectrometry Can Reveal Molecular FormulasChapter 14.6 - The Fragmentation Patterns Of Functional GroupsChapter 14.9 - Spectroscopy And The Electromagnetic SpectrumChapter 14.13 - The Position Of Absorption BandsChapter 14.14 - The Position And Shape Of An Absorption Band Is Affected By Electron Delocalization, Electron Donation And Withdrawal, And Hydrogen BondingChapter 14.15 - The Absence Of Absorption BandsChapter 14.16 - Some Vibrations Are Infrared InactiveChapter 14.17 - How To Interpret An Infrared SpectrumChapter 14.19 - The Beer-lambert LawChapter 14.20 - The Effect Of Conjugation On ΛmaxChapter 14.21 - The Visible Spectrum And ColorChapter 14.22 - Some Uses Of Uv/vis SpectroscopyChapter 15 - Nmr SpectroscopyChapter 15.1 - An Introduction To Nmr SpectroscopyChapter 15.4 - The Number Of Signals In An 1h Nmr SpectrumChapter 15.5 - The Chemical Shift Tells How Far The Signal Is From The Reference SignalChapter 15.6 - The Relative Positions Of 1h Nmr SignalsChapter 15.7 - The Characteristic Values Of Chemical ShiftsChapter 15.8 - Diamagnetic AnisotropyChapter 15.9 - The Integration Of Nmr Signals Reveals The Relative Number Of Protons Causing Each SignalChapter 15.10 - The Splitting Of Signals Is Described By The N+1 RuleChapter 15.11 - What Causes Splitting?Chapter 15.12 - More Examples Of 1h Nmr SpectraChapter 15.13 - Coupling Constants Identify Coupled ProtonsChapter 15.14 - Splitting Diagrams Explain The Multiplicity Of A SignalChapter 15.15 - Diastereotopic Hydrogens Are Not Chemically EquivalentChapter 15.17 - Protons Bonded To Oxygen And NitrogenChapter 15.20 - 13c Nmr SpectroscopyChapter 15.22 - Two-dimensional Nmr SpectroscopyChapter 16 - Reactions Of Carboxylic Acids And Carboxylic DerivativesChapter 16.1 - The Nomenclature Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 16.2 - The Structures Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 16.4 - Fatty Acids Are Long-chain Carboxylic AcidsChapter 16.5 - How Carboxylic Acids And Carboxylic Acid Derivatives ReactChapter 16.6 - The Relative Reactivities Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 16.7 - The General Mechanism For Nucleophilic Addition-elimination ReactionsChapter 16.8 - The Reactions Of Acyl ChloridesChapter 16.9 - The Reactions Of EstersChapter 16.10 - Acid-catalyzed Ester Hydrolysis And TransesterificationChapter 16.11 - Hydroxide-ion-promoted Ester HydrolysisChapter 16.12 - How The Mechanism For Nucleophilic Addition-elimination Was ConfirmedChapter 16.13 - Fats And Oils Are TriglyveridesChapter 16.14 - Reactions Of Carboxylic AcidsChapter 16.15 - Reactions Of AmidesChapter 16.16 - Acid-catalyzed Amide Hydrolysis And AlcoholysisChapter 16.18 - The Hydrolysis Of An Imide: A Way To Synthesize Primary AminesChapter 16.19 - NitrilesChapter 16.20 - Acid AnhydridesChapter 16.21 - Dicarboxylic AcidsChapter 16.22 - How Chemists Activate Carboxylic AcidsChapter 17 - Reactions Of Aldehydes And Ketones • More Reactions Of Carboxylic Acid Derivatives • Reactions Of Α,β-unsaturated Carbonyl CompoundsChapter 17.1 - The Nomenclature Of Aldehydes And KetonesChapter 17.2 - The Relative Reactivities Of Carbonyl CompoundsChapter 17.4 - The Reactions Of Carbonyl Compounds With Gringard ReagentsChapter 17.5 - The Reactions Of Carbonyl Compounds With Acetylide IonsChapter 17.6 - The Reactions Of Aldehydes And Ketones With Cyanide IonChapter 17.7 - The Reactions Of Carbonyl Compounds With Hydride IonChapter 17.8 - More About Reduction ReactionsChapter 17.9 - Chemoselective ReactionsChapter 17.10 - The Reactions Of Aldehydes And Ketones With AminesChapter 17.11 - The Reactions Of Aldehydes And Ketones With WaterChapter 17.12 - The Reactions Of Aldehydes And Ketones With AlcoholsChapter 17.13 - Protecting GroupsChapter 17.15 - The Reaction Of Aldehydes And Ketones With A PeroxyacidChapter 17.17 - Disconnections, Synthons, And Synthetic EquivalentsChapter 17.18 - Nucleophilic Addition To Α,β-unsaturated Aldehydes And KetonesChapter 17.19 - Nucleophilic Addition To Α,β-unsaturated Carboxylic Acid DerivativesChapter 18 - Reactions At The Α-carbon Of Carbonyl CompoundsChapter 18.1 - The Aciidity Of An Α-hydrogenChapter 18.2 - Keto-enol TautomersChapter 18.3 - Keto-enol InterconversionChapter 18.4 - Halogenation Of The Α-carbon Of Aldehydes And KetonesChapter 18.5 - Halogenation Of The Α-carbon Of Carboxylic Acids: The Hell-volhard-zelinski ReactionChapter 18.6 - Forming An Enolate IonChapter 18.7 - Alkylating The Α-carbon Of Carbonyl CompoundsChapter 18.8 - Alkylating And Acylating The Α-carbon Using An Enamine IntermediateChapter 18.9 - Alkylating The Β-carbon: The Michael ReactionChapter 18.10 - An Aldol Addition Forms Β-hydroxyaldehydes Or Β-hydroxyketonesChapter 18.11 - The Dehydration Of Aldol Addition Products Forms Α,β-unsaturated Aldehydes And KetonesChapter 18.12 - A Crossed Aldol AdditionChapter 18.13 - A Claisen Condensation Forms A Β-keto EsterChapter 18.14 - Other Crossed CondensationsChapter 18.15 - Intramolecular Condensations And Intramolecular Aldol AdditionsChapter 18.16 - The Robinson AnnulationChapter 18.17 - Carboxylic Acids With A Carbonyl Group At The 3-position Can Be DecarboxylatedChapter 18.18 - The Malonic Ester Synthesis: A Way To Synthesize A Carboxylic AcidChapter 18.19 - The Acetoacetic Ester Synthesis: A Way To Synthesize A Methyl KetoneChapter 18.20 - Making New Carbon-carbon BondsChapter 18.21 - Reactions At The Α-carbon In Living SystemsChapter 19 - Reactions Of Benzene And Substituted BenzenesChapter 19.1 - The Nomenclature Of Monosubstituted BenzenesChapter 19.2 - How Benzene ReactsChapter 19.4 - The Halogenation Of BenzeneChapter 19.6 - The Sulfonation Of BenzeneChapter 19.7 - The Friedel-crafts Acylation Of BenzeneChapter 19.8 - The Friedel-crafts Alkylation Of BenzeneChapter 19.10 - Using Coupling Reactions To Alkylate BenzeneChapter 19.12 - How Some Substituents On A Benzene Ring Can Be Chemically ChangedChapter 19.13 - The Nomenclature Of Disubstituted And Polysubstituted BenzenesChapter 19.14 - The Effect Of Substituents On ReactivityChapter 19.15 - The Effect Of Substituents On OrientationChapter 19.16 - The Effect Of Substituents Oh PkaChapter 19.18 - Additional Considerations Regarding Substituent EffectsChapter 19.19 - The Synthesis Of Monosubstituted And Disubstituted BenzenesChapter 19.20 - The Synthesis Of Trisubstituted BenzenesChapter 19.21 - The Synthesis Of Substituted Benzenes Using Arenediazonium SaltsChapter 19.22 - The Arenediazonium Ion As An ElectrophileChapter 19.23 - The Mechanism For The Reaction Of Amines With Nitrous AcidChapter 19.24 - Nucleophilic Aromatic Substitution: An Addition-elimination ReactionChapter 19.25 - The Synthesis Of Cyclic CompoundsChapter 20 - More About Amines • Reactions Of Heterocyclic CompoundsChapter 20.1 - More About Amine NomenclatureChapter 20.2 - More About The Acid-base Properties Of AminesChapter 20.3 - Amines React As Bases And As NucleophilesChapter 20.5 - Aromatic Five-membered-ring HeterocyclesChapter 20.6 - Aromatic Six-membered-ring HeterocyclesChapter 20.7 - Some Amine Heterocycles Have Important Roles In NatureChapter 21 - The Organic Chemistry Of CarbohydratesChapter 21.1 - The Classification Of CarbohydratesChapter 21.2 - The D And L NotationChapter 21.3 - The Configurations Of The AldosesChapter 21.4 - The Configurations Of The KetosesChapter 21.5 - The Reactions Of Monosaccharides In Basic SolutionsChapter 21.6 - The Oxidation-reduction Reactions Of MonosaccharidesChapter 21.7 - Lengthening The Chain: The Kiliani-fischer SynthesisChapter 21.8 - Shortening The Chain: The Wohl DegradationChapter 21.9 - The Stereochemistry Of Glucose: The Fischer ProofChapter 21.10 - Monosaccharides Form Cyclic HemiacetalsChapter 21.11 - Glucose Is The Most Stable AldohexoseChapter 21.15 - DisaccharidesChapter 21.16 - PolysaccharidesChapter 21.17 - Some Naturally Occuring Compounds Derived From CarbohydratesChapter 21.18 - Carbohydrates On Cell SurfacesChapter 22 - The Organic Chemistry Of Amino Acids, Peptides, And ProteinsChapter 22.1 - The Nomenclature Of Amino AcidsChapter 22.2 - The Configuration Of Amino AcidsChapter 22.3 - The Acid-base Properties Of Amino AcidsChapter 22.4 - The Isoelectric PointChapter 22.5 - Separating Amino AcidsChapter 22.6 - The Synthesis Of Amino AcidsChapter 22.7 - The Resolution Of Racemic Mixtures Of Amino AcidsChapter 22.8 - Peptide Bonds And Disulfide BondsChapter 22.9 - Some Interesting PeptidesChapter 22.10 - The Strategy Of Peptide Bond Synthesis: N-protection And C-activationChapter 22.11 - Automated Peptide SynthesisChapter 22.13 - How To Determine The Primary Structure Of A Polypeptide Or ProteinChapter 22.14 - Secondary StructureChapter 22.15 - Tertiary StructureChapter 22.16 - Quaternary StructureChapter 23 - Catalysis In Organic Reactions And In Enzymatic ReactionsChapter 23.2 - Acid CatalysisChapter 23.3 - Base CatalysisChapter 23.5 - Metal-ion CatalysisChapter 23.6 - Intramolecular ReactionsChapter 23.7 - Intramolecular CatalysisChapter 23.9 - The Mechanisms For Two Enzyme-catalyzed Reactions That Are Reminiscent Of Acid-catalyzed Amide HydrolysisChapter 23.10 - The Mechanism For An Enzyme-catalyzed Reaction That Involves Two Sequential Sn2 ReactionsChapter 23.11 - The Mechansim For An Enzyme-catalyzed Reaction That Is Reminiscent Of The Base-catalyzed Enediol RearrangementChapter 23.12 - The Mechanism For An Enzyme-catalyzed Reaction That Is Reminiscent Of An Aldol AdditionChapter 24 - The Organic Chemistry Of The Coenzymes, Compounds Derived From VitaminsChapter 24.1 - Niacin: The Vitamin Needed For Many Redox ReactionsChapter 24.2 - Riboflavin: Another Vitamin Used In Redox ReactionsChapter 24.3 - Vitamin B1: The Vitamin Needed For Acyl Group TransferChapter 24.5 - Vitamin B6: The Vitamin Needed For Amino Acid TransformationsChapter 24.6 - Vitamin B12: The Vitamin Needed For Certain IsomerizationsChapter 24.7 - Folic Acid: The Vitamin Needed For One-carbon TransferChapter 24.8 - Vitamin K: The Vitamin Needed For Carboxylation Of GlutamateChapter 25 - The Organic Chemistry Of The Metabolic Pathways • Terpene BiosynthesisChapter 25.6 - The Catabolism Of FatsChapter 25.7 - The Catabolism Of CarbohydratesChapter 25.8 - The Fats Of PyruvateChapter 25.9 - The Catabolism Of ProteinsChapter 25.10 - The Citric Acid CycleChapter 25.11 - Oxidative PhosphorylationChapter 25.12 - AnabolismChapter 25.15 - Amino Acid BiosynthesisChapter 25.16 - Terpenes Contain Carbon Atoms In Multiples Of FiveChapter 25.17 - How Terpenes Are BiosynthesizedChapter 25.18 - How Nature Synthesizes CholesterolChapter 26 - The Chemistry Of The Nucleic AcidsChapter 26.1 - Nucleosides And NucleotidesChapter 26.2 - Other Important NucleotidesChapter 26.3 - Nucleic Acids Are Composed Of Nucleotide SubunitsChapter 26.4 - Why Dna Does Not Have A 2'-oh GroupChapter 26.5 - The Biosynthesis Of Dna Is Called ReplicationChapter 26.7 - The Biosynthesis Of Rna Is Called TranscriptionChapter 26.9 - The Biosynthesis Of Proteins Is Called TranslationChapter 26.10 - Why Dna Contains Thymine Instead Of UracilChapter 26.12 - How The Base Sequence Of Dna Is DeterminedChapter 27 - Synthetic PolymersChapter 27.2 - Chain-growth PolymersChapter 27.4 - Polymerization Of Dienes • The Manufacture Of RubberChapter 27.7 - Classes Of Step-growth PolymersChapter 27.8 - Physical Properties Of PolymersChapter 27.10 - Biodegradable PolymersChapter 28 - Pericyclic ReactionsChapter 28.1 - There Are Three Kinds Of Pericyclic ReactionsChapter 28.2 - Molecular Orbitals And Orbital SymmetryChapter 28.3 - Electrocyclic ReactionsChapter 28.4 - Cycloaddition ReactionsChapter 28.5 - Sigmatropic RearrangementsChapter 28.6 - Pericyclic Reactions In Biological SystemsChapter 28.7 - Summary Of The Selection Rules For Pericyclic Reactions
Sample Solutions for this Textbook
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The Lewis structure of dihydrogen carbonate, H2CO3 is drawn as Hydrogen, carbon and oxygen are...Chapter 2, Problem 47PChapter 3, Problem 1PChapter 4, Problem 1PChapter 5, Problem 36PFirst, H+ from HBr attacks carbon with 1H in C=C results to give tertiary carbo cation which then...Chapter 7, Problem 27PReason for correct options: The above compounds all have delocalized electrons, which undergo...DDE (dichlorodiphenyldichloroethylene) is a chemical compound forms as a result of loss of hydrogen...
Chapter 10, Problem 35PThe given Compound (A) is reaction with methane sulfonyl chloride which gives compound (B). This...When a Iodobenzene is treated with alkene in presence of HeeK Reagent to form the correspondng the...N-bromosuccinimide (NBS) is used for the allylic bromination through radical reaction. Bromination...Chapter 14, Problem 43PThe set of chemically equivalent protons in a compound produces a separate signal in 1H NMR. There...The structure of the compound can be drawn if the name is given and vice-versa. The name of the...Chapter 17, Problem 53PThe name given compound ethyl acetoacetate ends with ate. This means the given compound must contain...Chapter 19, Problem 46PChapter 20, Problem 21PThe product obtained when D-galactose reacts with nitric acid is as follows, Figure 1 HNO3 oxidizes...Diethyl ether is a non-polar solvent, so it solubilize neutral or compounds having some single...Chapter 23, Problem 1PChapter 24, Problem 1PAdenosine triphosphate (ATP) is an chemical compound which is involved in many purposes. The process...Chapter 26, Problem 19PChapter 27, Problem 25PChapter 28, Problem 23P
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