The product obtained from the given reaction should be identified. Concept introduction: Reactions of aldehydes and ketones with peroxides: Aldehydes and ketones reacts with conjugate base of peroxides to form carboxylic acids and esters respectively. This reaction is called as Baeyer-Villiger oxidation.

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17.15, Problem 48P

(a)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate base of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(b)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(c)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(d)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

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1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…

Please draw, not just describe!

can you draw each step on a piece of a paper please this is very confusing to me

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17.15, Problem 48P

(a)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate base of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(b)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(c)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(d)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17.15, Problem 48P

(a)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate base of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(b)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(c)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(d)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17.15, Problem 48P

(a)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate base of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(b)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(c)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(d)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 17.15, Problem 48P

(a)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate base of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(b)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(c)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

(d)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Answer 6

Chapter 17.15, Problem 48P

(a)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate base of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Answer 7

Chapter 17.15, Problem 48P

(a)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate base of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The product obtained from the given reaction should be identified.

Concept introduction:

Reactions of aldehydes and ketones with peroxides:

Aldehydes and ketones reacts with conjugate bas of peroxides to form carboxylic acids and esters respectively.

This reaction is called as Baeyer-Villiger oxidation.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 17.1 - Prob. 1P Ch. 17.1 - Give two names for each of the following:Ch. 17.1 - Name the following:Ch. 17.2 - Prob. 4P Ch. 17.4 - What products are formed when the following...Ch. 17.4 - We saw on the previous page that...Ch. 17.4 - a. How many stereoisomers are obtained from the...Ch. 17.4 - Prob. 9P Ch. 17.4 - Write the mechanism for the reaction of acetyl...Ch. 17.4 - Prob. 11P

Solution Summary: The author explains how aldehydes and ketones react with conjugate bas of peroxides to form carboxylic acids and esters.

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Chapter 17 Solutions