The products for the given reaction should be identified. Concept Introduction: Nucleophilic acyl substitution: The carbonyl group of a carboxylic acid or carboxylic acid derivative can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 54P

(a)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

(b)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Reaction for aldehydes and ketones in presence of primary amine is as follows,

The carbonyl group of a carboxylic acid or carboxylic acid derivative gets converted into imine in presence of primary amine which is depicted as follows,

(c)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

The ketone which is carboxylic acid derivative in presence of NaBH4 and H3O+ tend to give secondary alcohol and the general reaction is as follows,

(d)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

(e)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

(f)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

The carboxylic acid derivatives namely aldehyde and ketones generally gets protected from converted to acetals in presence of diols.

(g)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 54P

(a)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

(b)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Reaction for aldehydes and ketones in presence of primary amine is as follows,

The carbonyl group of a carboxylic acid or carboxylic acid derivative gets converted into imine in presence of primary amine which is depicted as follows,

(c)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

The ketone which is carboxylic acid derivative in presence of NaBH4 and H3O+ tend to give secondary alcohol and the general reaction is as follows,

(d)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

(e)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

(f)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

The carboxylic acid derivatives namely aldehyde and ketones generally gets protected from converted to acetals in presence of diols.

(g)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 54P

(a)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

(b)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Reaction for aldehydes and ketones in presence of primary amine is as follows,

The carbonyl group of a carboxylic acid or carboxylic acid derivative gets converted into imine in presence of primary amine which is depicted as follows,

(c)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

The ketone which is carboxylic acid derivative in presence of NaBH4 and H3O+ tend to give secondary alcohol and the general reaction is as follows,

(d)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

(e)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

(f)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

The carboxylic acid derivatives namely aldehyde and ketones generally gets protected from converted to acetals in presence of diols.

(g)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Expert Solution & Answer

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See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 54P

(a)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

(b)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Reaction for aldehydes and ketones in presence of primary amine is as follows,

The carbonyl group of a carboxylic acid or carboxylic acid derivative gets converted into imine in presence of primary amine which is depicted as follows,

(c)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

The ketone which is carboxylic acid derivative in presence of NaBH4 and H3O+ tend to give secondary alcohol and the general reaction is as follows,

(d)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

(e)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

(f)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

The carboxylic acid derivatives namely aldehyde and ketones generally gets protected from converted to acetals in presence of diols.

(g)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Expert Solution & Answer

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See solution

Answer 5

Chapter 17, Problem 54P

(a)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

(b)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Reaction for aldehydes and ketones in presence of primary amine is as follows,

The carbonyl group of a carboxylic acid or carboxylic acid derivative gets converted into imine in presence of primary amine which is depicted as follows,

(c)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

The ketone which is carboxylic acid derivative in presence of NaBH4 and H3O+ tend to give secondary alcohol and the general reaction is as follows,

(d)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

(e)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

(f)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

The carboxylic acid derivatives namely aldehyde and ketones generally gets protected from converted to acetals in presence of diols.

(g)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Answer 6

Chapter 17, Problem 54P

(a)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Answer 7

Chapter 17, Problem 54P

(a)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Reaction for aldehydes and ketones in presence of primary amine is as follows,

The carbonyl group of a carboxylic acid or carboxylic acid derivative gets converted into imine in presence of primary amine which is depicted as follows,

Answer 9

(b)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

Reaction for aldehydes and ketones in presence of primary amine is as follows,

The carbonyl group of a carboxylic acid or carboxylic acid derivative gets converted into imine in presence of primary amine which is depicted as follows,

Answer 10

(c)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

The ketone which is carboxylic acid derivative in presence of NaBH4 and H3O+ tend to give secondary alcohol and the general reaction is as follows,

Answer 11

(c)

Interpretation Introduction

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

The ketone which is carboxylic acid derivative in presence of NaBH4 and H3O+ tend to give secondary alcohol and the general reaction is as follows,

Answer 12

(d)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Generally reduction of aldehyde gives primary alcohol and reduction of ketone gives secondary alcohol.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

The carboxylic acid derivatives namely aldehyde and ketones generally gets protected from converted to acetals in presence of diols.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

The carboxylic acid derivatives namely aldehyde and ketones generally gets protected from converted to acetals in presence of diols.

Answer 18

(g)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Answer 19

(g)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept Introduction:

Nucleophilic acyl substitution:

The carbonyl group of a carboxylic acid or carboxylic acid derivative is attached to a group that can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Answer 20

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Answer 21

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Answer 22

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Answer 23

Ch. 17.1 - Prob. 1P Ch. 17.1 - Give two names for each of the following:Ch. 17.1 - Name the following:Ch. 17.2 - Prob. 4P Ch. 17.4 - What products are formed when the following...Ch. 17.4 - We saw on the previous page that...Ch. 17.4 - a. How many stereoisomers are obtained from the...Ch. 17.4 - Prob. 9P Ch. 17.4 - Write the mechanism for the reaction of acetyl...Ch. 17.4 - Prob. 11P

The products for the given reaction should be identified. Concept Introduction: Nucleophilic acyl substitution: The carbonyl group of a carboxylic acid or carboxylic acid derivative can be replaced with another group. Therefore, aldehyde and ketone undergoes nucleophilic acyl substitution reactions.

Concept explainers

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

The ketone which is carboxylic acid derivative in presence of NaBH4 and H3O+ tend to give secondary alcohol and the general reaction is as follows,

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Chapter 17 Solutions

Concept explainers

Interpretation: The products for the given reaction should be identified. Concept Introduction: The ketone which is carboxylic acid derivative in presence of NaBH4 and H3O+ tend to give secondary alcohol and the general reaction is as follows,

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Chapter 17 Solutions

Interpretation:

The products for the given reaction should be identified.

Concept Introduction:

The ketone which is carboxylic acid derivative in presence of NaBH4 and H3O+ tend to give secondary alcohol and the general reaction is as follows,