A major product in the given reaction should be found. Concept Introduction: The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile. Nucleophilic addition to the β- carbon (conjugate addition) is irreversible. Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Question

Want to see the full answer?

Answer 1

Question

Chapter 17.19, Problem 52P

(a)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(b)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(c)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(d)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

2. Make an ice cube at 1 bar pressure by freezing an amount of liquid water that is 2 cm x 2 cm x 2 cm in volume. The density of liquid water at 0 °C is 1.000 g cm³ and the density of ice at 0 °C is 0.915 g cm³. Note that this difference in density is the reason your water pipes burst if they freeze and why you shouldn't forget to take your bottle of pop out of the freezer if you put it in there to try and cool it down faster. A. What is the work of expansion upon freezing? B. Is work done on the system or by the system?

I have a excitation/emission spectra of a quinine standard solution here, and I'm having trouble interpreting it. the red line is emission the blue line is excitation. i'm having trouble interpreting properly. just want to know if there is any evidence of raman or rayleigh peaks in the spectra.

Give the major product of the following reaction. excess 1. OH, H₂O 1.OH H CH3CH2CH21 H 2. A.-H₂O Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.

Answer 2

Question

Chapter 17.19, Problem 52P

(a)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(b)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(c)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(d)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 17.19, Problem 52P

(a)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(b)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(c)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(d)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 17.19, Problem 52P

(a)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(b)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(c)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(d)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 17.19, Problem 52P

(a)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(b)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(c)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

(d)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Answer 6

Chapter 17.19, Problem 52P

(a)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Answer 7

Chapter 17.19, Problem 52P

(a)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Answer 8

(b)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Answer 9

(b)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Answer 10

(c)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Answer 11

(c)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Answer 12

(d)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Answer 13

(d)

Interpretation Introduction

Interpretation:

A major product in the given reaction should be found.

Concept Introduction:

The resonance gives for α,β- unsaturated carbonyl compound which shoes that the compound has two electrophilic positions are β- carbon and carbonyl carbon. That is a nucleophile can be add either to β- carbon or carbonyl carbon. Conjugate addition and direct addition are depending upon the nature of the nucleophile.

Nucleophilic addition to the β- carbon (conjugate addition) is irreversible.

Nucleophilic addition to the carbonyl carbon (direct addition) is irreversible or reversible. When nucleophile is weak base such as alcohol, an amine or thiol, then direct addition is reversible, because of weak base is worthy leaving group.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 17

Ch. 17.1 - Prob. 1P Ch. 17.1 - Give two names for each of the following:Ch. 17.1 - Name the following:Ch. 17.2 - Prob. 4P Ch. 17.4 - What products are formed when the following...Ch. 17.4 - We saw on the previous page that...Ch. 17.4 - a. How many stereoisomers are obtained from the...Ch. 17.4 - Prob. 9P Ch. 17.4 - Write the mechanism for the reaction of acetyl...Ch. 17.4 - Prob. 11P

Solution Summary: The author explains how the resonance gives for ,- unsaturated carbonyl compound, which shoes that the compound has two electrophilic positions, is a nucleophile.

Want to see the full answer?

Chapter 17 Solutions