The mechanisms for the following reactions should be determined. 1. The acid-base catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine . 2. The acid-base catalyzed hydrolysis of an enamine to a carbonyl compounds and a secondary amine. Concept introduction: The chemical compound containing carbon and nitrogen double bond is known as imine. Enamine is derived by the condensation of an aldehyde or ketone with secondary amine.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.10, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The mechanisms for the following reactions should be determined.

1. The acid-base catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine.

2. The acid-base catalyzed hydrolysis of an enamine to a carbonyl compounds and a secondary amine.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde or ketone with secondary amine.

(b)

Interpretation Introduction

Interpretation:

The reason for the difference in mechanism of two reactions should be given.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde and ketone with secondary amine.

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.10, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The mechanisms for the following reactions should be determined.

1. The acid-base catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine.

2. The acid-base catalyzed hydrolysis of an enamine to a carbonyl compounds and a secondary amine.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde or ketone with secondary amine.

(b)

Interpretation Introduction

Interpretation:

The reason for the difference in mechanism of two reactions should be given.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde and ketone with secondary amine.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.10, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The mechanisms for the following reactions should be determined.

1. The acid-base catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine.

2. The acid-base catalyzed hydrolysis of an enamine to a carbonyl compounds and a secondary amine.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde or ketone with secondary amine.

(b)

Interpretation Introduction

Interpretation:

The reason for the difference in mechanism of two reactions should be given.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde and ketone with secondary amine.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.10, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The mechanisms for the following reactions should be determined.

1. The acid-base catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine.

2. The acid-base catalyzed hydrolysis of an enamine to a carbonyl compounds and a secondary amine.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde or ketone with secondary amine.

(b)

Interpretation Introduction

Interpretation:

The reason for the difference in mechanism of two reactions should be given.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde and ketone with secondary amine.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 17.10, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The mechanisms for the following reactions should be determined.

1. The acid-base catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine.

2. The acid-base catalyzed hydrolysis of an enamine to a carbonyl compounds and a secondary amine.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde or ketone with secondary amine.

(b)

Interpretation Introduction

Interpretation:

The reason for the difference in mechanism of two reactions should be given.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde and ketone with secondary amine.

Answer 6

Chapter 17.10, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The mechanisms for the following reactions should be determined.

1. The acid-base catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine.

2. The acid-base catalyzed hydrolysis of an enamine to a carbonyl compounds and a secondary amine.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde or ketone with secondary amine.

Answer 7

Chapter 17.10, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The mechanisms for the following reactions should be determined.

1. The acid-base catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine.

2. The acid-base catalyzed hydrolysis of an enamine to a carbonyl compounds and a secondary amine.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde or ketone with secondary amine.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reason for the difference in mechanism of two reactions should be given.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde and ketone with secondary amine.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reason for the difference in mechanism of two reactions should be given.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde and ketone with secondary amine.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 17.1 - Prob. 1P Ch. 17.1 - Give two names for each of the following:Ch. 17.1 - Name the following:Ch. 17.2 - Prob. 4P Ch. 17.4 - What products are formed when the following...Ch. 17.4 - We saw on the previous page that...Ch. 17.4 - a. How many stereoisomers are obtained from the...Ch. 17.4 - Prob. 9P Ch. 17.4 - Write the mechanism for the reaction of acetyl...Ch. 17.4 - Prob. 11P

Solution Summary: The author explains the mechanism of acid-base catalyzed hydrolysis of an imine to a carbonyl compound, enamine, and primry amine.

Interpretation:

The reason for the difference in mechanism of two reactions should be given.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde and ketone with secondary amine.

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Chapter 17 Solutions

Solution Summary: The author explains the mechanism of acid-base catalyzed hydrolysis of an imine to a carbonyl compound, enamine, and primry amine.

Interpretation: The reason for the difference in mechanism of two reactions should be given. Concept introduction: The chemical compound containing carbon and nitrogen double bond is known as imine. Enamine is derived by the condensation of an aldehyde and ketone with secondary amine.

Want to see the full answer?

Chapter 17 Solutions

Interpretation:

The reason for the difference in mechanism of two reactions should be given.

Concept introduction:

The chemical compound containing carbon and nitrogen double bond is known as imine.

Enamine is derived by the condensation of an aldehyde and ketone with secondary amine.