
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Question
Chapter 25.6, Problem 2P
Interpretation Introduction
Interpretation:
The mechanism for the reaction between glycerol and ATP results in the formation of glycerol-3-phosphate should be determined.
Concept introduction:
Glycerol:
The catabolism of fat which actually contain 3
Glycerol is polyol compound which is actually the base of all lipids.
Adenosine triphosphate ATP: The main job of ATP is to store energy and release it when cell is in need of energy.
Kinase: It is enzyme which serves as a catalyst in reaction of transferring phosphoryl group into the substrate.
Substrate: The molecule where the reaction takes place with help of enzymes.
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a. Determine whether each of the Followery
Molecules
is in
the R- On the y-
Configuration
1-01"/
1-6-4
Br
4
I
el
Br
b. Draw The Fisher projection For all the
Meso compounds that can
exist FOR
The Following molenle
1- Refer to the monosaccharides below to answer each of the following question(s):
CH₂OH
CHO
CH₂OH
CH₂OH
0
H-
OH
0
0
HO-
H
H-
-OH
HO
H
HO H
H OH
HO- H
CH₂OH
H.
OH
HO
H
HO-
H
CH₂OH
CH₂OH
CH3
a. Sorbose
b. Rhamnose
c. Erythrulose
d. Xylulose
Classify each sugar by type; for example, glucose is an aldohexose.
a. Xylulose is ..
b. Erythrulose is .
c. Sorbose is ..
d. Rhamnose is ..
2- Consider the reaction below to answer the following question(s).
CHO
H
OH
CH₂OH
CH₂OH
HO-
H
HO
HO
+
H.
-OH
HO
OH
HO.
H
OH
OH
H
-OH
H
OH
CH₂OH
Q
Z
a.
Refer to Exhibit 25-11. Place a triangle around the anomeric carbon in compound Q.
Compound Z is:
b.
1. the D-anomer.
2. the a-anomer.
3. the ẞ-anomer.
4. the L-anomer.
c. Which anomer is the LEAST stable?
d. Q and Z are cyclic examples of:
a. acetals
b.
hemiacetals
c. alditols
d.
hemialditols
Chapter 25 Solutions
Organic Chemistry
Ch. 25.6 - Prob. 2PCh. 25.6 - Prob. 3PCh. 25.6 - Why does the OH group add to the -carbon rather...Ch. 25.6 - Prob. 5PCh. 25.6 - How many molecules of NADH are formed from the...Ch. 25.7 - Prob. 7PCh. 25.7 - Prob. 8PCh. 25.7 - The oxidation of glyceraldehyde-3-phosphate to...Ch. 25.7 - Prob. 10PCh. 25.8 - Prob. 11P
Ch. 25.8 - Prob. 12PCh. 25.8 - Prob. 13PCh. 25.8 - Propose a mechanism for the reduction of...Ch. 25.9 - Prob. 15PCh. 25.9 - Prob. 16PCh. 25.10 - Acid-catalyzed dehydration reactions are normally...Ch. 25.10 - Prob. 18PCh. 25.10 - Prob. 19PCh. 25.10 - Acid-catalyzed dehydration reactions are normally...Ch. 25.10 - Prob. 21PCh. 25.10 - Prob. 22PCh. 25.11 - Prob. 23PCh. 25.12 - a. What is the name of the enzyme that converts...Ch. 25.15 - Prob. 25PCh. 25.16 - Prob. 26PCh. 25.16 - Prob. 27PCh. 25.17 - Propose mechanisms for the Claisen condensation...Ch. 25.17 - Prob. 29PCh. 25.17 - Propose a mechanism for the conversion of...Ch. 25.17 - Propose a mechanism for the biosynthesis of...Ch. 25.17 - Propose a mechanism for the conversion of the E...Ch. 25.17 - The fluoro-substitued geranyl pyrophosphate shown...Ch. 25.17 - Prob. 35PCh. 25.18 - Draw the individual 1,2-hydride and 1,2-methyl...Ch. 25 - Prob. 38PCh. 25 - Prob. 39PCh. 25 - Prob. 40PCh. 25 - Prob. 41PCh. 25 - Prob. 42PCh. 25 - Prob. 43PCh. 25 - Prob. 44PCh. 25 - Prob. 45PCh. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Prob. 48PCh. 25 - Prob. 49PCh. 25 - Prob. 50PCh. 25 - Prob. 51PCh. 25 - Prob. 52PCh. 25 - Prob. 53PCh. 25 - Prob. 54PCh. 25 - Prob. 55PCh. 25 - Prob. 56PCh. 25 - Prob. 57PCh. 25 - Prob. 58PCh. 25 - Prob. 59PCh. 25 - Prob. 60PCh. 25 - Prob. 61PCh. 25 - Prob. 62PCh. 25 - UDP-galactose-4-epimerase converts UDP-galactose...Ch. 25 - A student is trying to determine the mechanism for...Ch. 25 - What would be the results of the experiment in...Ch. 25 - Prob. 66PCh. 25 - Propose a mechanism for the biosynthesis of...Ch. 25 - Eudesmol is a sesquiterpene found in eucalyptus....
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