Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 25, Problem 46P
Interpretation Introduction
Interpretation:
The carbon position that contains carboxyl group in pyruvate which is formed from glucose should be identified.
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 25 Solutions
Organic Chemistry
Ch. 25.6 - Prob. 2PCh. 25.6 - Prob. 3PCh. 25.6 - Why does the OH group add to the -carbon rather...Ch. 25.6 - Prob. 5PCh. 25.6 - How many molecules of NADH are formed from the...Ch. 25.7 - Prob. 7PCh. 25.7 - Prob. 8PCh. 25.7 - The oxidation of glyceraldehyde-3-phosphate to...Ch. 25.7 - Prob. 10PCh. 25.8 - Prob. 11P
Ch. 25.8 - Prob. 12PCh. 25.8 - Prob. 13PCh. 25.8 - Propose a mechanism for the reduction of...Ch. 25.9 - Prob. 15PCh. 25.9 - Prob. 16PCh. 25.10 - Acid-catalyzed dehydration reactions are normally...Ch. 25.10 - Prob. 18PCh. 25.10 - Prob. 19PCh. 25.10 - Acid-catalyzed dehydration reactions are normally...Ch. 25.10 - Prob. 21PCh. 25.10 - Prob. 22PCh. 25.11 - Prob. 23PCh. 25.12 - a. What is the name of the enzyme that converts...Ch. 25.15 - Prob. 25PCh. 25.16 - Prob. 26PCh. 25.16 - Prob. 27PCh. 25.17 - Propose mechanisms for the Claisen condensation...Ch. 25.17 - Prob. 29PCh. 25.17 - Propose a mechanism for the conversion of...Ch. 25.17 - Propose a mechanism for the biosynthesis of...Ch. 25.17 - Propose a mechanism for the conversion of the E...Ch. 25.17 - The fluoro-substitued geranyl pyrophosphate shown...Ch. 25.17 - Prob. 35PCh. 25.18 - Draw the individual 1,2-hydride and 1,2-methyl...Ch. 25 - Prob. 38PCh. 25 - Prob. 39PCh. 25 - Prob. 40PCh. 25 - Prob. 41PCh. 25 - Prob. 42PCh. 25 - Prob. 43PCh. 25 - Prob. 44PCh. 25 - Prob. 45PCh. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Prob. 48PCh. 25 - Prob. 49PCh. 25 - Prob. 50PCh. 25 - Prob. 51PCh. 25 - Prob. 52PCh. 25 - Prob. 53PCh. 25 - Prob. 54PCh. 25 - Prob. 55PCh. 25 - Prob. 56PCh. 25 - Prob. 57PCh. 25 - Prob. 58PCh. 25 - Prob. 59PCh. 25 - Prob. 60PCh. 25 - Prob. 61PCh. 25 - Prob. 62PCh. 25 - UDP-galactose-4-epimerase converts UDP-galactose...Ch. 25 - A student is trying to determine the mechanism for...Ch. 25 - What would be the results of the experiment in...Ch. 25 - Prob. 66PCh. 25 - Propose a mechanism for the biosynthesis of...Ch. 25 - Eudesmol is a sesquiterpene found in eucalyptus....
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