Answered: a. H3C CH3 H, 1.0 equiv. Br2

Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter15: Solutions

Section: Chapter Questions

Problem 3CR

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Cyclopropane mixed in the proper ratio with oxygen can be used as an anesthetic. At 755 mm Hg and 25C, it has a density of 1.71 g/L. (a) What is the molar mass of cyclopropane? (b) Cyclopropane is made up of 85.7% C and 14.3% H. What is the molecular formula of cyclopropane?
About 5 billion kilograms of benzene, C6H6, are made each year. Benzene is used as a starting material for many other compounds and as a solvent (although it is also a carcinogen, and its use is restricted). One compound that can be made from benzene is cyclohexane, C6H12. C6H6() + 3 H2(g) C6H12() rH = 206.7 kJ/mol-rxn; rS = 361.5 J/K mol-rxn Is this reaction predicted to be product-favored at equilibrium at 25 C? Is the reaction enthalpy- or entropy-driven?
A power plant is driven by the combustion of a complex fossil fuel having the formula C11H7S. Assume the air supply is composed of only N2 and O2 with a molar ratio of 3.76:1.00, and the N2 remains unreacted. In addition to the water produced, the fuels C is completely combusted to CO2 and its sulfur content is converted to SO2. In order to evaluate gases emitted at the exhaust stacks for environmental regulation purposes, the nitrogen supplied with the air must also be included in the balanced reactions. a Including the N2 supplied m the air, write a balanced combustion equation for the complex fuel assuming 100% stoichiometric combustion (i.e., when there is no excess oxygen in the products and the only C-containing product is CO2). Except in the case of N2, use only integer coefficients. b Including N2 supplied in the air, write a balanced combustion equation for the complex fuel assuming 120% stoichiometric combustion (i.e., when excess oxygen is present in the products and the only C-containing product is CO2). Except in the case of use only integer coefficients c Calculate the minimum mass (in kg) of air required to completely combust 1700 kg of C11H7S. d Calculate the air/fuel mass ratio, assuming 100% stoichiometric combustion. e Calculate the air/fuel mass ratio, assuming 120% stoichiometric combustion.
1LDA 2) 10. Br OH GMH,SO,/A NH2 11. NH2 12.
O CI 1. AlCl3 2. H₂O
요 Eto OEt 1. EtMgBr(xs) 2. H3O* HO
What is the relationship of the following molecules: 1.Enantiomers 2.Diastomers 3. Identical A
J= M = i 0: = 1. NaBH4 2. dilute H* N 1. K 2. L 1.03 2. S(CH3)2 K= H3CO H3CO. M N = P = 1. NaNH2 2. Br CI L= O P 1. CN- 2. Na (s), NH3 (1), cold
Is this an Endothermic Sn1 diagram?
H3CO. 'CI AICI3 KMNO4 H20 Br Br AIBR3 AICI,
d. Br DBU е. FOC(CH3)3 Br
g. h. wit $ Ph Br li NaOCH, CH₂OH (cold, short time) 1. LDA 2 Br OCH₂ & 1. NaOCH₂ CH₂OH 2. BrCH₂CH₂CH₂ 3. H+, H₂O, heat 1. PPh 2. BuLi 3. NaOEt OEt EtOH NaOCH, CH₂OH (warmup, long time)

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