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- Draw the structure of unsaturated carbonyl compound(s) formed when 3-Hydroxy-2,4-diphenyl-butyraldehyde is heatedin i) a basic ii) an acidic solution. iii) Write the complete mechanism for the dehydration reaction that takes place in the basic solution.Draw the mechanism of Acid-Catalyzed Keto–Enol Interconversion.Fill in the missing reagents a-e in the following scheme:
- Propose a mechanism for the reaction of benzyl acetate with methylamine. Label theattacking nucleophile and the leaving group, and draw the transition state in which theleaving group leaves.1. Provide the mechanism of the reaction shown in the picture. 2. Explain why it cannot be done in basic conditions. 3. Why is the enol tautomer favored over the keto tautomer? Ph H3C OH H H3O+/H₂O HO H3C PhDraw the reaction mechanism of the elimination reaction of 2bromobutane with a hydroxide ion acting as the base.
- The Stork reaction is a condensation reaction between an enamine donor and an a,ẞ-unsaturated carbonyl acceptor. The overall reaction consists of a three-step sequence of 1. formation of an enamine from a ketone. 2. Michael addition to an α,ß-unsaturated carbonyl compound, and 3. hydrolysis of the enamine in dilute acid to regenerate the ketone. Consider the Stork reaction between cyclohexanone and propenal. Draw the structure of the product of the enamine formed between cyclohexanone and dimethylamine. ચર્ચ F Correct HC, CH3 ChemDoodle 2 Draw the structure of the Michael addition product. ChemDoodle Jn (F 106 CorrectIsoamyl acetate (also known as isopentyl acetate) is an ester that is referred to as “banana flavor” due to its odor that resembles that of banana. It can be synthesized from isopentyl alcohol and acetic acid via nucleophilic acyl substitution mechanism. Propose a mechanism for the synthesis of isoamyl acetate from acetic acid and isoamyl alcohol.Draw the keto and enol forms of 3,3-dimethylbutan-2-one, circle the more stable tautomer, and propose a mechanism for the conversion of one tautomer to the other in acidic conditions.
