Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Question
Chapter 3.9, Problem 30P
Interpretation Introduction
Interpretation:
The smallest straight –chain alkane which is a liquid at room temperature has to be identified.
Concept introduction:
Boiling point of
Bond angle: The bond angle is the angle formed between three atoms at least two bonds.
Polarity: It is a well separation of electric charge leading to a molecule or chemical compounds having an electrical dipole moment. Generally the polar molecules must contain polar bonds due to a different in electronegative between the bonded atoms.
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What is the smallest straight-chain alkane that is a liquid at room temperature (which is about 25 °C)?
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What type of organic molecule is this?
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ketone
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Q1: Draw all of the structural isomers possible for the alkane with the
molecular formula CeH14, and write the naming of all compounds.
Chapter 3 Solutions
Organic Chemistry
Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structure of a compound with molecular...Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Prob. 6PCh. 3.1 - Draw the structure for each of the following: a....Ch. 3.1 - Name the following compounds: a. CH3OCH2CH3 b....Ch. 3.2 - Prob. 11PCh. 3.2 - Prob. 12PCh. 3.3 - Prob. 13PCh. 3.3 - Prob. 14P
Ch. 3.3 - Prob. 15PCh. 3.3 - Prob. 16PCh. 3.3 - What is each compounds systematic name?Ch. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 19PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Prob. 23PCh. 3.6 - Prob. 24PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 30PCh. 3.9 - Prob. 31PCh. 3.9 - Prob. 32PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.9 - Prob. 35PCh. 3.9 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - a. Draw all the staggered and eclipsed conformers...Ch. 3.10 - Prob. 38PCh. 3.10 - Using Newman projections, draw the most stable...Ch. 3.11 - The bond angles in a regular polygon with n sides...Ch. 3.11 - Prob. 41PCh. 3.11 - Prob. 42PCh. 3.12 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.13 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.13 - Using the data in Table 3.9, calculate the...Ch. 3.14 - Prob. 46PCh. 3.14 - Which has a higher percentage of the...Ch. 3.14 - For each of the following disubstituted...Ch. 3.14 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 53PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 63PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 66PCh. 3 - Prob. 67PCh. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 69PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Prob. 71PCh. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - Prob. 80PCh. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 85PCh. 3 - Using the data obtained in Problem 85, calculate...
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- Explain why two different straight-chain alkanes could not be constitutional isomers.arrow_forwardHow does the structure of a cycloalkane differ from that of a straight-chain or branched-chain alkane?arrow_forwardClassify each of the following hydrocarbons as alkanes, alkenes, or alkynes. (a) C12H24 (b) C7H12 (c) C13H28arrow_forward
- . Alkenes and alkynes are characterized by their ability to undergo rapid, complete reactions, by which other atoms attach themselves to the carbon atoms of the double or triple bond.arrow_forwardWhat is meant by the term “unsaturated hydrocarbon”? What structural feature characterizes unsaturated hydrocarbons?arrow_forwardYou are teaching a class in organic chemistry to grade 12 students. Outline the differences in 3 physical properties between alkanes, alcohols, and carboxylic acids. Note: they all have the same hydrocarbon length.arrow_forward
- 4: Draw out the abbreviated structural formula of the following molecules. 4-Methyl-2-hexene 2-Methyl-2-hexene 2-Hexene 5: Draw the structure of 2-Butene, labeling the n bond and all the B bonds. 6: Draw all the structures possible with the formula CSH8.arrow_forward3. In terms of bonds, what would the molecule C3H6 be classified as? Inorganic compound Alkene Alkyne Alkanearrow_forwardIs it possible for alkynes to exhibit cis/trans isomerism? Explain your answer.arrow_forward
- Draw the condensed or line-angle structure for an alkene with the formula C5H10. Name 6 Structural isomers of C5H10. They should three alkene and two cycloalkanearrow_forwardWhat is the molecular formula of a hydrocarbon with M* = 108? (Write the formula with no subscripts, e.g. C4H10.) What is the sum of rings and double bonds in this compound?arrow_forwardAlkenes and alkynes react similarly to each other. Hydrogenation, halogenation, and hydration reactions are all types of addition reactions in which the reagent adds across the multiple bond of the reactant • Hydrogenation is the addition of hydrogen gas in the presence of a catalyst such as platinum, palladium, or nickel. • Halogenation involves a reaction with a halogen such as Cl₂ or Br₂ to produce a dihaloalkane or dihaloalkene product. Hydration reactions take place when alkenes or alkynes react with water in the presence of a strong acid catalyst to yield an alcohol. ▼ Part A Predict the product of the reaction of 1-butene with bromine. Enter the IUPAC name. ▸ View Available Hint(s) Submit ▾ Part B An alkyne undergoes hydrogenation to produce an alkane as follows: 04 RC=CR + 2H₂ Q Pd catalyst alkane Predict the product and draw it. Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all hydrogen atoms. To add an R group, double click an while…arrow_forward
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