Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Textbook Question
Chapter 3.12, Problem 43P
Draw 1,2,3,4,5,6-hexachlorocydohexane with
- a. all the chloro groups in axial positions.
- b. all the chloro groups in equatorial positions.
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9. Provide a systematic name for the following compound?
A. 1,2,4-trimethyl-5-ethylcyclohexane
B. 5-ethyl-1,2,4-trimethylcyclohexane
C. 1-ethyl-2,4,5-trimethylcyclohexane
D. 2,4,5-trimethyl-1-ethylcyclohexane
2
3
What is the IUPAC name of the following compound?
F.
а.
1-ethyl-3-fluoro-2,5-dimethylcyclohexane
O b. 2-ethyl-6-fluoro-1,4-dimethylcyclohexane
c. 3-ethyl-5-fluoro-1,4-dimethylcyclohexane
O d. 3-ethyl-1-fluoro-2,5-dimethylcyclohexane
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nework
CH₂
CH₂CH3
The correct name for the compound given above is
Select one:
O a. 1-propyl-3-ethyl-4-methylbenzene
b.
4-cyclopropyl-2-ethyl-1-methylbenzene
O c. p,o-methylethylcyclopropylbenzene
O d. 1-propyl-3-ethyl-4-methylcyclohexane
Chapter 3 Solutions
Organic Chemistry
Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structure of a compound with molecular...Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Prob. 6PCh. 3.1 - Draw the structure for each of the following: a....Ch. 3.1 - Name the following compounds: a. CH3OCH2CH3 b....Ch. 3.2 - Prob. 11PCh. 3.2 - Prob. 12PCh. 3.3 - Prob. 13PCh. 3.3 - Prob. 14P
Ch. 3.3 - Prob. 15PCh. 3.3 - Prob. 16PCh. 3.3 - What is each compounds systematic name?Ch. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 19PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Prob. 23PCh. 3.6 - Prob. 24PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 30PCh. 3.9 - Prob. 31PCh. 3.9 - Prob. 32PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.9 - Prob. 35PCh. 3.9 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - a. Draw all the staggered and eclipsed conformers...Ch. 3.10 - Prob. 38PCh. 3.10 - Using Newman projections, draw the most stable...Ch. 3.11 - The bond angles in a regular polygon with n sides...Ch. 3.11 - Prob. 41PCh. 3.11 - Prob. 42PCh. 3.12 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.13 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.13 - Using the data in Table 3.9, calculate the...Ch. 3.14 - Prob. 46PCh. 3.14 - Which has a higher percentage of the...Ch. 3.14 - For each of the following disubstituted...Ch. 3.14 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 53PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 63PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 66PCh. 3 - Prob. 67PCh. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 69PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Prob. 71PCh. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - Prob. 80PCh. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 85PCh. 3 - Using the data obtained in Problem 85, calculate...
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- 5. What is the IUPAC name for the structure below? ОН A. 3-ethyl-4-methyl-2-hexanol B. 2-ethyl-1,3-dimethyl-1-heptanol C. 4-ethyl-3,5-dimethyl-5-hexanol D. (1-hydroxyethyl)-3-methylhexanearrow_forwardWhat is the IUPAC name of the following compound? Ме. `Me Me A. 4-Ethyl-2-methyl-1-propylcyclohex-4- ene B. 1-Ethyl-5-methyl-4-propylcyclohex-1- ene C. 2-Ethyl-4-methyl-5-propylcyclohex-1- ene D. 5-Ethyl-1-methyl-2-propylcyclohex-4- enearrow_forward1. Answer the following: a) What is the IUPAC name of the acyclic unbranched alkane that contains six carbons? b) How are structural isomers best defined? i. compounds with the same molecular formula whose atoms are bonded together in different arrangements ii. compounds with the same molecular formula whose atoms are bonded together in the same arrangement, but drawn differently iii. compounds with similar structural formulas, but different numbers of hydrogens iv. none of the above c) Which of the following statements is false concerning line structures of alkanes? i. Each carbon atom has 4 bonds, although they may not all be shown explicitly ii. The lines represent bonds between the carbon atoms. iii. Hydrogen atoms are not shown because they are not present in the molecule iv. none of the abovearrow_forward
- 10. How many true statement(s) in the followings. a. 1,2-Dimethylcyclohexene occurs as E and Z isomers. b. 2,3-Dimethyl-3-hexene occurs as E and Z isomers. c. There are 4 possible E,Z isomers of 1,3-pentadiene.arrow_forwardConsider 1,2-dimethylcyclohexane.a. Draw structures for the cis and trans isomers using a hexagon for the six-membered ring.b. Draw the two possible chair conformations for the cis isomer. Which conformation, if either, is more stable?c. Draw the two possible chair conformations for the trans isomer. Which conformation, if either, is more stable?d. Which isomer, cis or trans, is more stable and why?arrow_forward17. Which of the following structures are constitutional isomers? CH3 CH3 CH3 CH3 H3C II III IV O A.I, II, & II B. I, II, & IV C.I& II D. All are constitutional isomers E. All are configurational isomers 18. What is the IUPAC name of the compound shown below? CH3 CH(CH3)2 H,C H. A. 1,2,3-Trimethylbutane B. 2,3-Dimethylpentane C. 2,3,4-Trimethylpentane D. 2-1sopropylbutane OE 22,3-Trimethylbutane O O OO0arrow_forward
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