Concept explainers
(a)
Interpretation:
The two chair conformers of cis-1-ethyl-3-methylcyclohexane has to be drawn and also the more stable conformer has to be indicated.
Concept introduction:
Conformers: The different spatial arrangements of the atoms that result from rotation about a single bond is called conformational isomers.
Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.
Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50), it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.
(b)
Interpretation:
The two chair conformers of trans-1-ethyl-2-isopropylcyclohexane has to be drawn.
Concept introduction:
Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.
Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.
Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50), it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.
(c)
Interpretation:
The two chair conformers of trans-1-ethyl-2-methylcyclohexane has to be drawn and also the more stable conformer has to be indicated.
Concept introduction:
Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.
Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.
Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to
(d)
Interpretation:
The two chair conformers of cis-1,2-diethylcyclohexane has to be drawn. Also mention the stable one.
Concept introduction:
Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.
Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.
Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50), it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.
(e)
Interpretation:
The two chair conformers of cis -1-ethyl-3-isopropylcyclohexane has to be drawn. Also mention the stable one.
Concept introduction:
Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.
Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.
Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50), it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.
(f)
Interpretation:
The two chair conformers of cis-1-ethyl-4-isopropylcyclohexane has to be drawn.
Concept introduction:
Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.
Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.
Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50), it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.
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