Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Textbook Question
Chapter 3.13, Problem 45P
Using the data in Table 3.9, calculate the percentage of molecules of cyclohexanol that have the OH group in an equatorial position at 25°C.
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If exactly 3 moles of propanol (C3H8O) is combusted in the presence of excess oxygen (O2) for form carbon dioxide (CO2) and water (H2O), how many moles of water will be produced?
Enter the integer number of moles of H2O, do not enter the unit.
Hint: Since this problem and two problems below rely on this reaction, make sure you balance this reaction very carefully on paper as your first step before doing any calculations. The reaction to be balanced is reaction between C3H8O(l) and O2(g) to produce CO2(g) and H2O(l).
In problem 1.30 letter f my structure is different than the one in the book . I don’t know why
Identify the different functional groups in the following molecules using names from the table below.
(If there are fewer than 3 different functional groups, leave an appropriate number of answer boxes empty.)
a)
b)
HO
Name
Alkene
Arene
Alkyne -c=c-
Halide
Alcohol
Ether
Amine
Structures of Some Common Functional Groups
Structure
Nitrile
X
(X=F, Cl, Br, I)
OH
-C=N;
Nitro
Thiol
Aldehyde
Ketone
Name
Carboxylic Acid
Ester
Amide
Carboxylic Acid Chloride
Structure
SH
X
Yo
0=ú
010
0=U
Chapter 3 Solutions
Organic Chemistry
Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structure of a compound with molecular...Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Prob. 6PCh. 3.1 - Draw the structure for each of the following: a....Ch. 3.1 - Name the following compounds: a. CH3OCH2CH3 b....Ch. 3.2 - Prob. 11PCh. 3.2 - Prob. 12PCh. 3.3 - Prob. 13PCh. 3.3 - Prob. 14P
Ch. 3.3 - Prob. 15PCh. 3.3 - Prob. 16PCh. 3.3 - What is each compounds systematic name?Ch. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 19PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Prob. 23PCh. 3.6 - Prob. 24PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 30PCh. 3.9 - Prob. 31PCh. 3.9 - Prob. 32PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.9 - Prob. 35PCh. 3.9 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - a. Draw all the staggered and eclipsed conformers...Ch. 3.10 - Prob. 38PCh. 3.10 - Using Newman projections, draw the most stable...Ch. 3.11 - The bond angles in a regular polygon with n sides...Ch. 3.11 - Prob. 41PCh. 3.11 - Prob. 42PCh. 3.12 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.13 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.13 - Using the data in Table 3.9, calculate the...Ch. 3.14 - Prob. 46PCh. 3.14 - Which has a higher percentage of the...Ch. 3.14 - For each of the following disubstituted...Ch. 3.14 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 53PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 63PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 66PCh. 3 - Prob. 67PCh. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 69PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Prob. 71PCh. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - Prob. 80PCh. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 85PCh. 3 - Using the data obtained in Problem 85, calculate...
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- Classify the following alcohols as primary, secondary, or tertiary: a. b.CH3CH2CH2CH2OH c.arrow_forwardDraw Lewis structures and condensed structural formulas for the four alcohols with the molecular formula C4H10O. Classify each alcohol as primary, secondary, or tertiary. (Hint: First consider the connectivity of the four carbon atoms; they can be bonded either four in a chain or three in a chain with the fourth carbon as a branch on the middle carbon. Then consider the points at which the iOH group can be bonded to each carbon chain.)arrow_forwardSection 2: Drawing and Nomenclature 11. Draw line-angle formulas for the four alcohols with the molecular formula C4H10O.arrow_forward
- Draw the structural formulas of compounds A, C, D, E and F in the boxes provided above.arrow_forwardDescribe an experiment you will carry out and the result that you will expect to distinguish between the following: Ethanol (Alcohol) 1-bromoethane (Halogenoalkane) Ethanal (aldehyde) Carry out your experiment and identify substances X, Y and Z. The unknown substances provided are Ethanol, 1-bromoethane and Ethanal.arrow_forwardList the name and position for each substituent in this organic molecule on a separate row of the table below: Your answer for the name column should be just one word. In the position column, write the number of the carbon where the substituent is attached to the parent ring (which has been highlighted for you). Note for advanced students: You may assume that the parent ring is numbered in a counter-clockwise fashion with position #1 at the top of this molecule. You can add more rows to the table if you need them. Add Row name B position 0 Garrow_forward
- Arrange these compounds in order of increasing boiling point (values in C are 42, 24, 78, and 118). (a) CH3CH2OH (b) CH3OCH3 (c) CH3CH2CH3 (d) CH3COOHarrow_forwardis this statement correct?arrow_forwardI Review You may want to reference (Pages 399 - 404) Section 12.1 while completing this problem. Enter the IUPAC name for each of the following. Part A OH Spell out the full name of the compound. Submit Request Answer • Part B CH3 ÇH3 CH3-CH-CH2-CH–CH2-OH Spell out the full name of the compound. Submit Request Answer • Part C OH CH2-CH3 Spell out the full name of the compound. Submit Request Answerarrow_forward
- Regarding the three compounds in the previous question which of the following statements is true? Select one: These three compounds are isomers because they have the same molecular formulae. These three compounds are isomers because they have different boiling points. These three compounds are isomers because they have different structures. These three compounds are isomers because they have the same IUPAC name.arrow_forwardWhich intermolecular force(s) do the following pairs of molecules experience? (Consider asking yourself which molecule in each pair is dominant?) Between acetone and ethanol? Between pentane and hexane? Between pentol and water?arrow_forward1. The unknown liquids (A to E) could be any of the five compounds above. From your observations and the discussion, deduce and infer the identification of the unknowns ОН HOʻ CH3OH isopropanol 2-methy-2-propanol or tert-butanol methanol 2-propanone benzaldehyde (just write the name): A is D is B is E is C is 2. Which compound/s would produce positive results with DNPH test? 3. What test will differentiate benzaldehyde from acetone? 4. What test/s will differentiate the 3 alcohols above?arrow_forward
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