(a)
Interpretation:
The product of the given reaction has to be determined.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of an
Organoborane compound:
An alkyl–organoboron compound, an alkenyl–Organoboron compound, or an aryl–Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(a)
Explanation of Solution
When a Iodobenzene is treated with alkene in presence of HeeK Reagent to form the correspondng the benzene product.
(b)
Interpretation:
The product of the given reaction has to be determined.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of an alkene and then joins the fragments.
Organoborane compound:
An alkyl–organoboron compound, an alkenyl–Organoboron compound, or an aryl–Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(b)
Answer to Problem 23P
Explanation of Solution
When a Complex of benzene is treated with ethylene oxide to form the correspondng the alcoholic benzene product.
(c)
Interpretation:
The expected product should be formed by the following reaction.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of sa alkene and then joins the fragments.
Organoborane compound:
An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(c)
Answer to Problem 23P
Explanation of Solution
Chloro benzene is treated with alkyl substituted CuLi reagent to give the corresponding product.
(d)
Interpretation:
The expected product should be formed by the following reaction.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an Orghanoboron reagent.
Heck reaction:
A reaction that breaks the double bond of sa alkene and then joins the fragments.
Organoborane compound:
An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(d)
Answer to Problem 23P
Explanation of Solution
When a Iodobenzene is treated with
(e)
Interpretation:
The expected product should be formed by the following reaction.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of sa alkene and then joins the fragments.
Organoborane compound:
An alkyl – organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(e)
Answer to Problem 23P
Explanation of Solution
When a bromo benzene treated with a brane complecx in presence of Heek reagent to give the corresponding product.
(f)
Interpretation:
The expected product should be formed by the following reaction.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of an alkene and then joins the fragments.
Organoborane compound:
An alkyl–organoboron compound, an alkenyl–Organoboron compound, or an aryl–Organoboron compound:
Coupling reaction:
A reaction that joins two groups with a carbon-carbon bond.
(f)
Answer to Problem 23P
Explanation of Solution
When an
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Organic Chemistry
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