Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 12.4, Problem 17P
Show how the Suzuki and/or Heck reactions can be used to prepare the following compounds:
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(f) SO:
Best Lewis Structure
3
e group geometry:_
shape/molecular geometry:,
(g) CF2CF2
Best Lewis Structure
polarity:
e group arrangement:_
shape/molecular geometry:
(h) (NH4)2SO4
Best Lewis Structure
polarity:
e group arrangement:
shape/molecular geometry:
polarity:
Sketch (with angles):
Sketch (with angles):
Sketch (with angles):
1.
Problem Set 3b
Chem 141
For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing
bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the
molecule is polar or non-polar (iv)
(a) SeF4
Best Lewis Structure
e group arrangement:_
shape/molecular geometry:
polarity:
(b) AsOBr3
Best Lewis Structure
e group arrangement:_
shape/molecular geometry:
polarity:
Sketch (with angles):
Sketch (with angles):
(c) SOCI
Best Lewis Structure
2
e group arrangement:
shape/molecular geometry:_
(d) PCls
Best Lewis Structure
polarity:
e group geometry:_
shape/molecular geometry:_
(e) Ba(BrO2):
Best Lewis Structure
polarity:
e group arrangement:
shape/molecular geometry:
polarity:
Sketch (with angles):
Sketch (with angles):
Sketch (with angles):
Chapter 12 Solutions
Organic Chemistry
Ch. 12.1 - Prob. 1PCh. 12.2 - Which is more reactive an organolithium compound...Ch. 12.2 - Prob. 3PCh. 12.3 - PROBLEM 6♦
Explain why tertiary alkyl halides...Ch. 12.3 - Muscalure is the sex attractant of the common...Ch. 12.3 - Prob. 8PCh. 12.3 - Prob. 9PCh. 12.3 - Prob. 10PCh. 12.4 - Prob. 13PCh. 12.4 - Prob. 14P
Ch. 12.4 - Prob. 15PCh. 12.4 - Show how the Suzuki and/or Heck reactions can be...Ch. 12.4 - Identify two pairs of an alkyl bromide and an...Ch. 12.5 - Prob. 19PCh. 12.5 - Draw the product of ring-closing metathesis for...Ch. 12.5 - Prob. 22PCh. 12 - Prob. 23PCh. 12 - Prob. 24PCh. 12 - Identify A through H.Ch. 12 - 26. Using the given starting material, any...Ch. 12 - Prob. 27PCh. 12 - Prob. 28PCh. 12 - Prob. 29PCh. 12 - Using ethynyleyclohexane as a starting material...Ch. 12 - Prob. 31PCh. 12 - Using the given starting material, any necessary...Ch. 12 - Prob. 33PCh. 12 - A student added an equivalent of...Ch. 12 - Using the given starting material, any necessary...Ch. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - Bombykol is the sex pheromone of the silk moth....Ch. 12 - Prob. 39PCh. 12 - A dibromide loses only one bromine when it reacts...Ch. 12 - What starting material is required in order to...Ch. 12 - Prob. 42PCh. 12 - Prob. 1PCh. 12 - Prob. 2PCh. 12 - Prob. 3PCh. 12 - Prob. 4P
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