Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 3.14, Problem 46P
Using the data in Table 3.9, calculate the percentage of molecules of cyclohexanol that have the OH group in an equatorial position at 25°C.
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If exactly 3 moles of propanol (C3H8O) is combusted in the presence of excess oxygen (O2) for form carbon dioxide (CO2) and water (H2O), how many moles of water will be produced?
Enter the integer number of moles of H2O, do not enter the unit.
Hint: Since this problem and two problems below rely on this reaction, make sure you balance this reaction very carefully on paper as your first step before doing any calculations. The reaction to be balanced is reaction between C3H8O(l) and O2(g) to produce CO2(g) and H2O(l).
In problem 1.30 letter f my structure is different than the one in the book . I don’t know why
Chapter 3 Solutions
Organic Chemistry (8th Edition)
Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structure of a compound with molecular...Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Prob. 6PCh. 3.1 - Draw the structure for each of the following: a....Ch. 3.1 - Name the following compounds: a. CH3OCH2CH3 b....Ch. 3.2 - Prob. 9PCh. 3.2 - Draw the structure for each of the following: a....Ch. 3.2 - Give each substituent on the nine-carbon chain a...Ch. 3.2 - Prob. 14P
Ch. 3.3 - What is each compounds systematic name?Ch. 3.3 - Prob. 16PCh. 3.3 - Prob. 17PCh. 3.3 - Prob. 18PCh. 3.3 - Prob. 19PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 21PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Prob. 25PCh. 3.6 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Draw condensed and skeletal structures for each of...Ch. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 32PCh. 3.9 - Prob. 33PCh. 3.9 - Prob. 34PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.10 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - Prob. 38PCh. 3.10 - Prob. 39PCh. 3.11 - a. Draw all the staggered and eclipsed conformers...Ch. 3.11 - Prob. 41PCh. 3.11 - Using Newman projections, draw the most stable...Ch. 3.12 - The bond angles in a regular polygon with n sides...Ch. 3.12 - Prob. 44PCh. 3.13 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.14 - Using the data in Table 3.9, calculate the...Ch. 3.14 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.15 - Prob. 48PCh. 3.15 - Which has a higher percentage of the...Ch. 3.15 - a. Draw the more stable chair conformer of...Ch. 3.15 - For each of the following disubstituted...Ch. 3.15 - a. Draw Newman projections of the two conformers...Ch. 3.15 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 56PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 66PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 69PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 72PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - What is each compound s systematic name?Ch. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 88PCh. 3 - Using the data obtained in Problem 85, calculate...Ch. 3 - Draw the conformers for the following...
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- Classify the following alcohols as primary, secondary, or tertiary: a. b.CH3CH2CH2CH2OH c.arrow_forwardIdentify the different functional groups in the following molecules using names from the table below. (If there are fewer than 3 different functional groups, leave an appropriate number of answer boxes empty.) a) b) HO Name Alkene Arene Alkyne -c=c- Halide Alcohol Ether Amine Structures of Some Common Functional Groups Structure Nitrile X (X=F, Cl, Br, I) OH -C=N; Nitro Thiol Aldehyde Ketone Name Carboxylic Acid Ester Amide Carboxylic Acid Chloride Structure SH X Yo 0=ú 010 0=Uarrow_forwardDraw Lewis structures and condensed structural formulas for the four alcohols with the molecular formula C4H10O. Classify each alcohol as primary, secondary, or tertiary. (Hint: First consider the connectivity of the four carbon atoms; they can be bonded either four in a chain or three in a chain with the fourth carbon as a branch on the middle carbon. Then consider the points at which the iOH group can be bonded to each carbon chain.)arrow_forward
- Draw Lewis structures and condensed structural formulas for the four alcohols with the molecular formula C4H10O. Classify each alcohol as primary, secondary, or tertiary.arrow_forwardDraw Lewis structures and condensed structural formulas for the two alcohols with the molecular formula C3H8O. Classify each as primary, secondary, or tertiary.arrow_forwardIndicate which compound in each of the following pairs has the higher value of the specified property, or if the two compounds in a pair have nearly the same value for the property. Supply the compound name or same. A: I. methyl propanoate or II. pentanal: boiling pointB: I. methyl butanoate or II. hexanal: solubility in waterC: I. methyl propanoate or II. 1-pentanol: boiling pointD: I. methyl pentanoate or II. hexanoic acid: solubility in waterE: I. butanoic acid or II. methyl propanoate: boiling pointarrow_forward
- 1. The six compounds below may be the unknowns in the exercise. Draw their structures in the boxes below. (You may have to look up the structure of glucose). Hexane Ethanol Benzaldehyde Cyclohexanone Acetone (Propanone) Glucosearrow_forwardFor which compound containing a heteroatom (an atom other than carbon or hydrogen) does the molecular ion have an even-numbered mass? For which does it have an odd-numbered mass? Q.)An alcohol with the molecular formula CnH2n+1OHarrow_forwardSection 2: Drawing and Nomenclature 11. Draw line-angle formulas for the four alcohols with the molecular formula C4H10O.arrow_forward
- Write a balanced equation for the complete combustion of 2,3-dimethylbutane. Use the molecular formula for the alkane (C before H) and the smallest possible integer coefficients.arrow_forwardWrite the systematic (IUPAC) name for each of the following organic molecules: structure OH CH3 C CH3 CH3 CH₂ CH3 CH3CH2C–CH2–CH2C−CH2CH3 CH3 CH2 OH CH3 CH3-CH₂ OH CH₂ CH3 CH3—CH,—CH–CH2–CH2–CH–CH2–CH-CH2CH3 namearrow_forward1. Consider the solubility and boiling point of the following pair of compounds: n-butyl alcohol and diethyl ether. The boiling points for the compounds are 118 °C and 35 °C respectively. The solubility for both compounds is the same (8g/100g water). Explain this observation for (i) boiling point disparity; (ii) solubility similarity a. H-bonds form in diethyl ether; n-butyl alcohol forms H-bonds in water b. H-bonds form in n-butyl alcohol; diethyl ether forms H-bonds in water c. H-bonds in n-butyl alcohol; Both compounds form H-bonds in water d. Both compounds form H-bonds; Both compounds form H-bonds in water 2. Account for the bond angle differences between (i) H-C-H (109.5°) in methane and H-S-H (90°); H-C-H (109.5°) and H-O-H (107.5°) in water. a. The H-S-H has two lone pairs; The H-O-H has two lone pairs b. The H-S-H has no hybridization at p-orbitals; The H-O-H has two lone pairs c. The H-S-H has two lone pairs; The H-O-H has no hybridization…arrow_forward
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