Solutions for Chemistry: Principles and Reactions
Problem 1QAP:
Principles of Heat Flow Titanium is a metal used in jet engines. Its specific heat is 0.523 J/g C....Problem 3QAP:
Copper is used in building the integrated circuits, chips, and printed circuit boards for computers....Problem 4QAP:
Mercury was once used in thermometers and barometers. When 46.9 J of heat are absorbed by 100.0 g of...Problem 5QAP:
The specific heat of aluminum is 0.902J/gC. How much heat is absorbed by an aluminum pie tin with a...Problem 6QAP:
Chromium has a specific heat of 0.450J/gC. How much heat is absorbed by 35.0 g of chromium if the...Problem 7QAP:
Magnesium sulfate is often used in first-aid hot packs, giving off heat when dissolved in water. A...Problem 8QAP:
Sodium chloride is added in cooking to enhance the flavor of food. When 10.00 g of NaCl are...Problem 9QAP:
When 375 mL of water (d=1.00g/mL) at 32C are mixed with 125 mL of water at 92C , what is the final...Problem 10QAP:
How many mL of water at 10C (2 significant figures) must be added to 75 mL of water at 35C to obtain...Problem 11QAP:
When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of...Problem 12QAP:
The heat of neutralization, Hneut, can be defined as the amount of heat released (or absorbed), q,...Problem 13QAP:
Fructose is a sugar commonly found in fruit. A sample of fructose, C6H12O6, weighing 4.50 g is...Problem 14QAP:
In earlier times, ethyl ether was commonly used as an anesthetic. It is, however, highly flammable....Problem 15QAP:
Isooctane is a primary component of gasoline and gives gasoline its octane rating. Burning 1.00 mL...Problem 16QAP:
Ethyl alcohol, C2H5OH, is the intoxicating agent in liquor. Burning 1.00 g of ethyl alcohol in an...Problem 17QAP:
Acetic acid, HC2H3O2, is responsible for the sour taste of vinegar. Combustion of acetic acid gives...Problem 18QAP:
Acetylene, C2H2, is used in welding torches. It releases a lot of energy when burned in oxygen. The...Problem 19QAP:
Salicylic acid, C7H6O3, is one of the starting materials in the manufacture of aspirin. When 1.00 g...Problem 20QAP:
Methanol (CH3OH) is also known as wood alcohol and can be used as a fuel. When one mole of methanol...Problem 21QAP:
Nitrogen oxide (NO) has been found to be a key component in many biological processes. It also can...Problem 22QAP:
Small amounts of oxygen gas can be prepared in the laboratory by decomposing potassium chlorate with...Problem 23QAP:
In the late eighteenth century Priestley prepared ammonia by reacting HNO3(g) with hydrogen gas. The...Problem 25QAP:
Strontium metal is responsible for the red color in fireworks. Fireworks manufacturers use strontium...Problem 26QAP:
Nitroglycerin, C3H5(NO3)3(l), is an explosive most often used in mine or quarry blasting. It is a...Problem 27QAP:
A typical fat in the body is glyceryl trioleate, C57H104O6. When it is metabolized in the body, it...Problem 28QAP:
Use the same fat described in Question 27. (a) Write a thermochemical equation for the metabolism of...Problem 29QAP:
Which requires the absorption of a greater amount of heat—vaporizing 100.0 g of benzene or boiling...Problem 31QAP:
A student is asked to calculate the amount of heat involved in changing 10.0 g of liquid bromine at...Problem 32QAP:
Follow the step-wise process outlined in Problem 31 to calculate the amount of heat involved in...Problem 33QAP:
A lead ore, galena, consisting mainly of lead(II) sulfide, is the principal source of lead. To...Problem 34QAP:
A reaction used to produce the silicon for semiconductors from sand (SiO2), can be broken up into...Problem 35QAP:
Given the following thermochemical equations, C2H2(g)+52...Problem 36QAP:
Given the following thermochemical equations: 4B(s)+3O2(g)2B2O3(s)H=2543.8kJ H2(g)+12...Problem 37QAP:
Write thermochemical equations for the decomposition of one mole of the following compounds into the...Problem 38QAP:
Write thermochemical equations for the formation of one mole of the following compounds from the...Problem 39QAP:
Given 2Al2O3(s)4Al(s)+3O2(g)H=3351.4kJ (a) What is the heat of formation of aluminum oxide? (b) What...Problem 40QAP:
Given 2Cr2O3(s)4Cr(s)+3O2(g)H=+2269.4kJ (a) What is the heat of formation of chromium(III) oxide?...Problem 41QAP:
Limestone, CaCO3, when subjected to a temperature of 900C in a kiln, decomposes to calcium oxide and...Problem 42QAP:
When hydrazine reacts with oxygen, nitrogen gas and steam are formed. (a) Write a thermochemical...Problem 44QAP:
Use Table 8.3 to obtain H for the following chemical equations: (a) Zn(s)+2 H+(aq)Zn2+(aq)+H2(g) (b)...Problem 45QAP:
Use the appropriate tables to calculate H for (a) the reaction between copper(II) oxide and carbon...Problem 46QAP:
Use the appropriate tables to calculate H for (a) the reaction between MgC03(s) and a strong acid to...Problem 47QAP:
When one mole of nitroglycerine, C3H5(NO3)3(l) decomposes, nitrogen, oxygen, carbon dioxide, and...Problem 48QAP:
When one mole of calcium carbonate reacts with ammonia, solid calcium cyanamide, CaCN2, and liquid...Problem 49QAP:
Chlorine trifluoride is a toxic, intensely reactive gas. It was used in World War II to make...Problem 50QAP:
When one mole of ethylene gas, C2H4, reacts with fluorine gas, hydrogen fluoride and carbon...Problem 51QAP:
Glucose, C6H12O6(s), (H f =1275.2kJ/mol) is converted to ethyl alcohol, C2H5OH(l), and carbon...Problem 52QAP:
When ammonia reacts with dinitrogen oxide gas (H f =82.05kJ/mol), liquid water and nitrogen gas are...Problem 53QAP:
How many kJ are equal to 3.27 L atm of work?Problem 54QAP:
How many L atm are equal to 12.2 kJ of work?Problem 55QAP:
Find (a) E when a gas absorbs 18 J of heat and has 13 J of work done on it. (b) q when 72 J of work...Problem 56QAP:
Calculate (a) q when a system does 54 J of work and its energy decreases by 72 J. (b) E for a gas...Problem 57QAP:
Consider the following reaction in a vessel with a movable piston. R(g)+T(g)X(g)As the reaction...Problem 58QAP:
Consider the following reaction in the vessel described in Question 57. A(g)+B(g)C(s)For this...Problem 60QAP:
For the vaporization of one mole of bromine at 59C, determine (a) H (Table 8.2) (b) PV(c) EProblem 61QAP:
Consider the combustion of propane, C3H8, the fuel that is commonly used in portable gas barbeque...Problem 62QAP:
Consider the combustion of one mole of methyl alcohol, CH3OH(l), which yields carbon dioxide gas and...Problem 63QAP:
Butane gas, C4H10, is sold to campers as bottled fuel. Its density at 25C and 1.00 atm is 2.38 g/L....Problem 64QAP:
The BTU (British thermal unit) is the unit of energy most commonly used in the United States. One...Problem 65QAP:
Natural gas companies in the United States use the therm as a unit of energy. One therm is 1105 BTU....Problem 67QAP:
Given the following reactions, N2H4(l)+O2(g)N2(g)+2H2O(g)H=534.2kJ H2(g)+12 O2(g)H2O(g)H=241.8kJ...Problem 68QAP:
In World War II, the Germans made use of otherwise unusable airplane parts by grinding them up into...Problem 70QAP:
Consider the reaction between methane and oxygen producing carbon dioxide and water. Suppose that...Problem 71QAP:
Consider burning ethane gas, C2H6 in oxygen (combustion) forming CO2 and water. (a) How much energy...Problem 72QAP:
On complete combustion at constant pressure, a 1.00-L sample of a gaseous mixture at 0C and 1.00 atm...Problem 73QAP:
Microwave ovens convert radiation to energy. A microwave oven uses radiation with a wavelength of...Problem 74QAP:
In 2010, 3.30109 gallons of gasoline were consumed in the United States. The following assumptions...Problem 75QAP:
Some solar-heated homes use large beds of rocks to store heat. (a) How much heat is absorbed by...Problem 76QAP:
Consider a solution prepared by dissolving 10.00 g of NaOH in 1.00 L of water. (a) When the solid...Problem 77QAP:
Draw a cylinder with a movable piston containing six molecules of a liquid. A pressure of 1 atm is...Problem 79QAP:
Which statement(s) is/are true about bond enthalpy? (a) The bond energy for a triple bond between A...Problem 80QAP:
Equal masses of liquid A, initially at 100C, and liquid B, initially at 50C, are combined in an...Problem 81QAP:
Determine whether the statements given below are true or false. Consider an endothermic process...Problem 82QAP:
An exothermic reaction is carried out in a coffee-cup calorimeter. Which of the following statements...Problem 83QAP:
Determine whether the statements given below are true or false. Consider enthalpy (H). (a) It is a...Problem 84QAP:
Microwave ovens emit microwave radiation that is absorbed by water. The absorbed radiation is...Problem 85QAP:
On a hot day, you take a six-pack ot a on a pcmc, cooling it with ice. Each empty (aluminum) can...Problem 87QAP:
The thermite reaction was once used to weld rails: 2Al(s)+Fe2O3(s)Al2O3(s)+2Fe(s)(a) Using heat of...Problem 88QAP:
A sample of sucrose, C12H22O11, is contaminated by sodium chloride. When the contaminated sample is...Browse All Chapters of This Textbook
Chapter 1 - Matter And MeasurementsChapter 2 - Atoms, Molecules, And IonsChapter 3 - Mass Relations In Chemistry; StoichiometryChapter 4 - Reactions In Aqueous SolutionChapter 5 - GasesChapter 6 - Electronic Structure And The Periodic TableChapter 7 - Covalent BondingChapter 8 - ThermochemistryChapter 9 - Liquids And SolidsChapter 10 - Solutions
Chapter 11 - Rate Of ReactionChapter 12 - Gaseous Chemical EquilibriumChapter 13 - Acids And BasesChapter 14 - Equilibria In Acid-base SolutionsChapter 15 - Complex Ion And Precipitation EquilibriaChapter 16 - Spontaneity Of ReactionChapter 17 - ElectrochemistryChapter 18 - Nuclear ReactionsChapter 19 - Complex IonsChapter 20 - Chemistry Of The MetalsChapter 21 - Chemistry Of The NonmetalsChapter 22 - Organic ChemistryChapter 23 - Organic Polymers, Natural And Synthetic
Book Details
Discover all of the fundamental topics of general chemistry with this brief, reader-oriented book. Chemistry: Principles and Reactions, 8e, provides a clear, concise presentation based on the authors' more than 50 years of combined teaching experience. The book includes graded and concept-driven examples as well as examples that focus on molecular reasoning and understanding, as well as "Chemistry: Beyond the Classroom" essays that demonstrate the relevance of the concepts and highlight some of the most up-to-date uses of chemistry. A strong, enhanced art program helps readers visualize chemical concepts. Integrated end-of-chapter questions and Key Concepts correlate to OWLv2, the number 1 online homework and tutorial system for chemistry.
Sample Solutions for this Textbook
We offer sample solutions for Chemistry: Principles and Reactions homework problems. See examples below:
Chapter 1, Problem 1QAPChapter 1, Problem 27QAPChapter 1, Problem 28QAPChapter 2, Problem 1QAPChapter 2, Problem 27QAPChapter 2, Problem 28QAPChapter 2, Problem 36QAPChapter 2, Problem 37QAPChapter 2, Problem 38QAP
Given structural formula- In above structural formula, CH3 group is attached with acetic acid group...Methane is a member of Alkane family that has only 1 carbon atom and general formula for molecular...Chemical name of molecule = silicon disulfide In this chemical compound: Least electronegative atom...Potassium and strontium are metals. Potassium is present in group 1 known as alkali metal group in...Chapter 3, Problem 1QAPChapter 3, Problem 13QAPChapter 3, Problem 18QAPChapter 3, Problem 25QAPChapter 3, Problem 47QAPChapter 3, Problem 48QAPChapter 3, Problem 51QAPChapter 3, Problem 52QAPChapter 3, Problem 74QAPChapter 3, Problem 94QAPChapter 4, Problem 1QAPChapter 4, Problem 7QAPChapter 4, Problem 8QAPChapter 4, Problem 9QAPChapter 4, Problem 10QAPChapter 4, Problem 63QAPChapter 4, Problem 74QAPVolume of a gas in a container is equal to the volume of the container. Conversion factor for gallon...The force exerted by gas over a unit surface of area is called pressure of gas. The expression of...As per the given table we have to find the moles and grams of propane gas. First let us calculate...The gas 1 is taken as CO2 and gas 2 as H2 . For both the gases pressure, volume and temperatures are...Below is the expression of ideal gas equation: PV = nRT .......... (1) Here, volume i.e. V, pressure...The gas present in bulb A is N2 and bulb is NH3 . The moles of N2 and NH3 is 1 mol each. In both...Chapter 5, Problem 86QAPThe given tanks are as follows: Here, circles represent CH4 gas, square represents oxygen and...The pressure, volume and temperature of both tanks A and B is 1.38 atm, 750 ml or 0.750 L, and 25 0C...By burning sulfur with oxygen sulfur trioxide can be prepared 2S(s) + 3O2(g) → 2SO3(g) In the 5 g of...Chapter 6, Problem 1QAPChapter 6, Problem 27QAPChapter 6, Problem 28QAPChapter 6, Problem 39QAPChapter 6, Problem 40QAPChapter 6, Problem 42QAPChapter 6, Problem 49QAPChapter 6, Problem 50QAPChapter 6, Problem 67QAPCalculate the total number of valence electrons in molecule CCl4: Total number of valence electrons...Chapter 7, Problem 4QAPChapter 7, Problem 5QAPChapter 7, Problem 6QAPGiven Information: The molecule is Cl2. Here thetotal valence electrons are: 2×7(Cl)=14 and the...Given Information: The ion is BrO-. Here, the total valence electrons are: 7(Br)+6(O)+1(charge)=14....Chapter 7, Problem 17QAPChapter 7, Problem 18QAPChapter 8, Problem 1QAPChapter 8, Problem 5QAPChapter 8, Problem 6QAPChapter 8, Problem 16QAPChapter 8, Problem 35QAPChapter 8, Problem 43QAPChapter 8, Problem 44QAPChapter 8, Problem 72QAPChapter 8, Problem 76QAPChapter 8, Problem 87QAPGiven: P1 = 254 mm Hg T1 = 57 0C = (57+273) K = 330 K T2 = 35 0C = (35+273) K = 308 K and T2 = 45 0C...Chapter 9, Problem 3QAPGiven Information: The phase diagram of compound X is as follows: The triple point is defined as the...Chapter 9, Problem 18QAPNitrogen monoxide ( NO ) The number of valence electrons of both species. Nitrogen (N) has 5 valence...Chapter 9, Problem 61QAPGiven: The volume of one atom is 43πr3 and the volume of the cell is s3. The percentage of the total...Given: Volume = 10.0 L Mass of hydrogen gas = 0.400 g Mass of oxygen gas = 3.2 g Reaction:...Chapter 9, Problem 78QAPChapter 10, Problem 1QAPChapter 10, Problem 9QAPChapter 10, Problem 10QAPChapter 10, Problem 17QAPChapter 10, Problem 18QAPChapter 10, Problem 33QAPChapter 10, Problem 34QAPGiven, Temperature =22 °C Convert temperature from Celsius to Kelvin as follows: T=(22+273) K=295 K...Chapter 10, Problem 40QAPChapter 11, Problem 1QAPChapter 11, Problem 17QAPChapter 11, Problem 19QAPChapter 11, Problem 20QAPChapter 11, Problem 21QAPChapter 11, Problem 22QAPChapter 11, Problem 25QAPChapter 11, Problem 26QAPChapter 11, Problem 27QAPChapter 11, Problem 28QAPGiven Information: Here the chemical reaction is: 2NO(g) + O2(g) → 2NO2(g) Experiment No....Chapter 12, Problem 1QAPThe reaction of the system is as follows: 2A(g)+B(g)→3C(g) The given incomplete data is as follows:...Chapter 12, Problem 10QAPChapter 12, Problem 11QAPChapter 12, Problem 12QAPChapter 12, Problem 14QAPChapter 12, Problem 16QAPChapter 12, Problem 69QAPChapter 12, Problem 71QAPChapter 13, Problem 1QAPChapter 13, Problem 9QAPThe given species is Zn(H2O)3OH+. On reaction with water, it can act as an acid by donating hydrogen...The given species is (CH3)3N. On reaction with water, it can act as a base by accepting hydrogen ion...Chapter 13, Problem 51QAPChapter 13, Problem 52QAPChapter 13, Problem 59QAPChapter 13, Problem 61QAPChapter 13, Problem 62QAPChapter 13, Problem 67QAPChapter 13, Problem 74QAPChapter 13, Problem 98QAPChapter 14, Problem 1QAPChapter 14, Problem 6QAPChapter 14, Problem 9QAPChapter 14, Problem 10QAPChapter 14, Problem 32QAPChapter 14, Problem 34QAPChapter 14, Problem 36QAPChapter 14, Problem 50QAPChapter 14, Problem 74QAPChapter 15, Problem 1QAPChapter 15, Problem 32QAPChapter 15, Problem 34QAPChapter 15, Problem 55QAPThe equation of reaction of iron (II) sulfate with barium hydroxide is shown as follows:...Reason for correct option/s: b. The equation of Ag(NH3)2+ with strong acid is- Ag(NH3)2+(aq)+2H+(aq)...The equilibrium reaction of Mg(OH)2 is as follows: Mg(OH)2(s)⇌Mg2+(aq)+2OH−. The solubility product...Given the reaction is as follows: Zn(NH3)42+(aq)+4OH−(aq)⇌ Zn(OH)42−(aq)+4NH3(aq) For this reaction...Chapter 16, Problem 1QAPChapter 16, Problem 17QAPGiven process is: 4NH3 (g)+5O2(g)→4NO(g)+6H2O(g) The mathematical expression for the standard...Chapter 16, Problem 20QAPGiven process is: 2Cr (s)+3CO2(g)→Cr2O3(s)+3CO(g) The mathematical expression for the standard...Given process is: 2HNO3(l)+3H2S(g)→4H2O(l) + 2NO(g)+3S(s) The mathematical expression for the...Chapter 16, Problem 25QAPChapter 16, Problem 26QAPThe chemical equation corresponding to the reaction between iron ore and hydrogen is given as:...The given reaction is: MnO2(s) ⇌ Mn(s) + O2(g) For the above reaction, the ΔG0 value can be deduced...Given: ΔHf0(H2SO4) = -902.9 kJS0(H2SO4) = 17.14 J/K The dissociation of H2 SO4 can be expressed as...Chapter 17, Problem 1QAPChapter 17, Problem 5QAPChapter 17, Problem 6QAPSO2(g) + I2(aq)→SO3(g) + I-(aq) Determining the oxidation numbers: The oxidation number of I in I2...Chapter 17, Problem 8QAPChapter 17, Problem 9QAPChapter 17, Problem 37QAPChapter 17, Problem 39QAPChapter 17, Problem 73QAPChapter 17, Problem 74QAPChapter 17, Problem 100QAPChapter 18, Problem 1QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Chapter 18, Problem 19QAPThe reaction in which the change in atomic numbers, energy states and mass number of nuclei takes...Given information: Half-life of uranium = 7×108 years The given equation is:...In the given compound, [Fe(C2O4)2(NH3)Cl3-] Oxalate is denoted by the symbol ‘ox’ and its chemical...A ligand is an atom or a group of atoms or an anion having an unshared pair of electrons and thus it...A ligand is an atom or a group of atoms or an anion that has an unshared pair of electrons and thus...Cadmium is a 4d transition metal element and its atomic number is 48. Its electronic configuration...Chapter 19, Problem 41QAPIn case of transition metal cations, the electrons that are present beyond the noble gas are in...Chapter 20, Problem 1QAPChapter 20, Problem 23QAPChapter 20, Problem 24QAPChapter 20, Problem 39QAPGiven Information: (1) A solution of potassium dichromate is made basic with sodium hydroxide. The...The compound has three elements and anion is periodate ion that is, IO4− because in naming of acid...The reaction of sulphate ion (SO42−) to form sulfur dioxide is as follows: SO42−(aq)⇌SO2(g) Balance...Iodine is oxidized to iodate. I2(s)⇌IO3−(aq) Balance the above reaction. Balance all atoms except...Chapter 21, Problem 18QAPAt 25°C, reaction of bromine is: Br2(I)+H2O ⇌ H+(aq)+Br−(aq)+HBrO(aq) Initial concentration: C 0 0 0...Chapter 21, Problem 53QAPChapter 21, Problem 61QAPBalance the reaction as follows: Consider oxidation and reduction reaction separately as given...Chapter 22, Problem 1QAPChapter 22, Problem 25QAPChapter 22, Problem 26QAPChapter 22, Problem 27QAPChapter 22, Problem 28QAPThe dissolved hydrochloric acid first dissociates into its ionic forms under the aqueous medium as...Chapter 22, Problem 60QAPTetrachloroethylene polymer consists of number of monomer unit of 1,1,2,2-tetrachloroethylene. The...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...If all the polymers contain the same number of monomer units, the molar mass of polymers can be...Cellulose is a polyssaccharide which consists of several units of glucose joined through glycosidic...Chapter 23, Problem 29QAPThe given amino acid is alanine which has the following structure: The structures of the respective...
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