Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Textbook Question
Chapter 8, Problem 57QAP
Consider the following reaction in a vessel with a movable piston.
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(a) The following synthesis of the molecule shown in the circle has a major problem. What is this problem? (2
pts)
1) HBr
(no peroxides)
2) H-
NaNH2
Br
3) NaNH,
4) CH3Br
5) H2, Pd
(b) Starting with the molecule shown below and any other materials with two carbons or less, write out an
alternate synthesis of the circled molecule. More than one step is needed. Indicate the reagent(s) and the major
product in all the steps in your synthesis. (5 pts)
2024 Fall Term (1) Organic Chemistry 1 (Lec)
CHEM 22204 02[6386] (Hunter College)
(c) Using the same starting material as in part (b) and any other materials win two carpons or less, write out
syntheses of the circled molecules shown below. More than one step is needed in each case. Indicate the
reagent(s) and the major product in all the steps in your synthesis. You may use reactions and products from
your synthesis in part (b). (5 pts)
alt
ons for
Free Response Questions
FRQ 1:
0/5
To spectrophotometrically determine the mass percent of cobalt in an ore containing cobalt and
some inert materials, solutions with known [Co?) are prepared and absorbance of each of the
solutions is measured at the wavelength of optimum absorbance. The data are used to create a
calibration plot, shown below.
0.90-
0.80-
0.70
0.60
0.50
0.40-
0.30
0.20-
0.10-
0.00-
0.005
0.010
Concentration (M)
0.015
A 0.630 g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted
with water to a final volume of 50.00 ml. Assume that all the cobalt in the ore sample is converted to
Co2+(aq).
a. What is the [Co2] in the solution if the absorbance of a sample of the solution is 0.74?
13
✗
b. Calculate the number of moles of Co2+(aq) in the 50.00 mL solution.
0.008 mols Co
Please correct answer and don't used hand raiting
Chapter 8 Solutions
Chemistry: Principles and Reactions
Ch. 8 - Principles of Heat Flow Titanium is a metal used...Ch. 8 - Prob. 2QAPCh. 8 - Copper is used in building the integrated...Ch. 8 - Mercury was once used in thermometers and...Ch. 8 - The specific heat of aluminum is 0.902J/gC. How...Ch. 8 - Chromium has a specific heat of 0.450J/gC. How...Ch. 8 - Magnesium sulfate is often used in first-aid hot...Ch. 8 - Sodium chloride is added in cooking to enhance the...Ch. 8 - When 375 mL of water (d=1.00g/mL) at 32C are mixed...Ch. 8 - How many mL of water at 10C (2 significant...
Ch. 8 - When one mol of KOH is neutralized by sulfuric...Ch. 8 - The heat of neutralization, Hneut, can be defined...Ch. 8 - Fructose is a sugar commonly found in fruit. A...Ch. 8 - In earlier times, ethyl ether was commonly used as...Ch. 8 - Isooctane is a primary component of gasoline and...Ch. 8 - Ethyl alcohol, C2H5OH, is the intoxicating agent...Ch. 8 - Acetic acid, HC2H3O2, is responsible for the sour...Ch. 8 - Acetylene, C2H2, is used in welding torches. It...Ch. 8 - Salicylic acid, C7H6O3, is one of the starting...Ch. 8 - Methanol (CH3OH) is also known as wood alcohol and...Ch. 8 - Nitrogen oxide (NO) has been found to be a key...Ch. 8 - Small amounts of oxygen gas can be prepared in the...Ch. 8 - In the late eighteenth century Priestley prepared...Ch. 8 - Prob. 24QAPCh. 8 - Strontium metal is responsible for the red color...Ch. 8 - Nitroglycerin, C3H5(NO3)3(l), is an explosive most...Ch. 8 - A typical fat in the body is glyceryl trioleate,...Ch. 8 - Use the same fat described in Question 27. (a)...Ch. 8 - Which requires the absorption of a greater amount...Ch. 8 - Which evolves more heat—freezing 100.0 g of...Ch. 8 - A student is asked to calculate the amount of heat...Ch. 8 - Follow the step-wise process outlined in Problem...Ch. 8 - A lead ore, galena, consisting mainly of lead(II)...Ch. 8 - A reaction used to produce the silicon for...Ch. 8 - Given the following thermochemical equations,...Ch. 8 - Given the following thermochemical equations:...Ch. 8 - Write thermochemical equations for the...Ch. 8 - Write thermochemical equations for the formation...Ch. 8 - Given 2Al2O3(s)4Al(s)+3O2(g)H=3351.4kJ (a) What is...Ch. 8 - Given 2Cr2O3(s)4Cr(s)+3O2(g)H=+2269.4kJ (a) What...Ch. 8 - Limestone, CaCO3, when subjected to a temperature...Ch. 8 - When hydrazine reacts with oxygen, nitrogen gas...Ch. 8 - Use Table 8.3 to obtain AHO for the following...Ch. 8 - Use Table 8.3 to obtain H for the following...Ch. 8 - Use the appropriate tables to calculate H for (a)...Ch. 8 - Use the appropriate tables to calculate H for (a)...Ch. 8 - When one mole of nitroglycerine, C3H5(NO3)3(l)...Ch. 8 - When one mole of calcium carbonate reacts with...Ch. 8 - Chlorine trifluoride is a toxic, intensely...Ch. 8 - When one mole of ethylene gas, C2H4, reacts with...Ch. 8 - Glucose, C6H12O6(s), (H f =1275.2kJ/mol) is...Ch. 8 - When ammonia reacts with dinitrogen oxide gas (H f...Ch. 8 - How many kJ are equal to 3.27 L atm of work?Ch. 8 - How many L atm are equal to 12.2 kJ of work?Ch. 8 - Find (a) E when a gas absorbs 18 J of heat and has...Ch. 8 - Calculate (a) q when a system does 54 J of work...Ch. 8 - Consider the following reaction in a vessel with a...Ch. 8 - Consider the following reaction in the vessel...Ch. 8 - Determine the difference between H and E at 25C...Ch. 8 - For the vaporization of one mole of bromine at...Ch. 8 - Consider the combustion of propane, C3H8, the fuel...Ch. 8 - Consider the combustion of one mole of methyl...Ch. 8 - Butane gas, C4H10, is sold to campers as bottled...Ch. 8 - The BTU (British thermal unit) is the unit of...Ch. 8 - Natural gas companies in the United States use the...Ch. 8 - Prob. 66QAPCh. 8 - Given the following reactions,...Ch. 8 - In World War II, the Germans made use of otherwise...Ch. 8 - Prob. 69QAPCh. 8 - Consider the reaction between methane and oxygen...Ch. 8 - Consider burning ethane gas, C2H6 in oxygen...Ch. 8 - On complete combustion at constant pressure, a...Ch. 8 - Microwave ovens convert radiation to energy. A...Ch. 8 - In 2010, 3.30109 gallons of gasoline were consumed...Ch. 8 - Some solar-heated homes use large beds of rocks to...Ch. 8 - Consider a solution prepared by dissolving 10.00 g...Ch. 8 - Draw a cylinder with a movable piston containing...Ch. 8 - Redraw the cylinder in Question 77 after work has...Ch. 8 - Which statement(s) is/are true about bond...Ch. 8 - Equal masses of liquid A, initially at 100C, and...Ch. 8 - Determine whether the statements given below are...Ch. 8 - An exothermic reaction is carried out in a...Ch. 8 - Determine whether the statements given below are...Ch. 8 - Microwave ovens emit microwave radiation that is...Ch. 8 - On a hot day, you take a six-pack ot a on a pcmc,...Ch. 8 - Prob. 86QAPCh. 8 - The thermite reaction was once used to weld rails:...Ch. 8 - A sample of sucrose, C12H22O11, is contaminated by...Ch. 8 - A wad of steel wool (specific heat=0.45J/gC) at...Ch. 8 - Consider a metal ion A2+ and its nitrate salt, In...
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- 8:07 AM Wed Dec 18 Final Exam 2024 copy Home Insert Draw Page Layout Formulas Data Review AA 田 General A G fx Alexis Cozort ☑ ⚫ 61% A B D E F H K M N P R S T U 3+ 10 125 mM that yielded peak heights of Aa = 9 1-(a)A sample solution was examined under XRF to quantify the analyte Ce³+. Find the response factor F, when standardized concentration of analyte [Ce³+]A = concentration of internal standard S i.e. [In³*]s = 151 mM was spiked with standardized 1600 and As = 3015 respectively? 11 12 (i)Define F, F = Aa As [A] [S] + X 13 (*Define with variables) 4000 14 15 (ii)Calculate F, F = numeral (You will use the F value in part 1-(b) below) As 16 (*Calculate with numerals) 17 18 1-(b)To determine the unknown conc of analyte [Ce³+], a volume of 15 mL of internal standard S having a concentration [In³+]s = 0.264 M 19 20 was added to 45 mL of unknown, and the mixture was diluted to 100 mL in a volumetric flask. XRF analysis yielded a spectrum, Figure-1, where peak heights A and As are…arrow_forwardAll structural types of Boron hydrides exhibit B-B, B-H-B and B-H bonds. Correct?arrow_forwardN-nitrosodimethylamine (NDMA) is a suspected carcinogen that can form via reactions between dimethylamine (DMA) and monochloramine (NH2Cl). The relevant elementary reactions and the corresponding rate constants are as shown below. Reaction Rate constant (M¹s¹) DMA + NH2Cl = DMCA + NH3 k =1.4×10-1, kr = 5.83×10-3 1.28×10-3 DMA + NH2Cl → UDMH UDMH + NH2Cl → NDMA -> 1.11×10-1 If the initial concentrations of DMA and NH2Cl are given, you should be able to predict the concentrations of all species at any given reaction time. Please write down the rate equations for DMA, NH2C1, DMCA, UDMH and NDMA.arrow_forward
- You wish to add enough NaOCl (sodium hypochlorite) to a 150 m³ swimming pool to provide a dose of 5.0 mg/L TOTOCI as Cl2. (a) How much NaOCI (kg) should you add? (Note: the equivalent weight of NaOCl is based on the reaction: NaOCl + 2H + 2 e→CI + Na +H₂O.) (10 pts) (atomic weight: Na 23, O 16, C1 35.5) (b) The pH in the pool after the NaOCl addition is 8.67. To improve disinfection, you want at least 90% of the TOTOCI to be in the form of HOCI (pKa 7.53). Assuming that HOCI/OCI is the only weak acid/base group in solution, what volume (L) of 10 N HCl must be added to achieve the goal? (15 pts) Note that part a) is a bonus question for undergraduate students. If you decide not to work on this part of the question, you many assume TOTOCI = 7×10-5 M for part b).arrow_forwardPart A 2K(s)+Cl2(g)+2KCI(s) Express your answer in grams to three significant figures. Part B 2K(s)+Br2(1)→2KBr(s) Express your answer in grams to three significant figures. Part C 4Cr(s)+302(g)+2Cr2O3(s) Express your answer in grams to three significant figures. Part D 2Sr(s)+O2(g) 2SrO(s) Express your answer in grams to three significant figures. Thank you!arrow_forwardA solution contains 10-28 M TOTCO3 and is at pH 8.1. How much HCI (moles per liter of solution) is required to titrate the solution to pH 7.0? (H2CO3: pKa1=6.35, pKa2=10.33)arrow_forward
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