ORGANIC CHEMISTRY W/ALEKS6th EditionSMITH Publisher: MCG CUSTOMISBN: 9781264905430
ORGANIC CHEMISTRY W/ALEKS
Solutions for ORGANIC CHEMISTRY W/ALEKS
Problem 36P:
2.36 Propranolol is an antihypertensive agent—that is, it lowers blood pressure. (a)
Which proton...Problem 37P:
2.37 Amphetamine is a powerful stimulant of the central nervous system. (a) Which
proton in...Problem 42P:
Draw the products of each proton transfer reaction. Label the acid and base in the starting...Problem 45P:
What is Ka for each compound? Use a calculator when necessary. a. H2SpKa=7.0 b. ClCH2COOHpKa=2.8 c....Problem 46P:
What is the pKa for each compound? a. b. c.Problem 47P:
Which of the following bases are strong enough to deprotonate CH3CH2CH2CCH(pKa=25), so that...Problem 49P:
Draw the products of each reaction. Use the pKa table in Appendix A to decide if the equilibrium...Problem 62P:
Dimethyl ether (CH3OCH3) and ethanol (CH3CH2OH) are isomers, but has (CH3OCH3) a pKa of 40 and...Problem 63P:
2.59 Atenolol is a (beta) blocker, a drug used to treat high blood pressure. Which of
the...Problem 64P:
2.60 Use the principles in Section 2.5 to label the most acidic hydrogen in each drug.
Explain your...Problem 65P:
2.61 Label the three most acidic hydrogen atoms in lactic acid. and
rank them in order of deceasing...Problem 67P:
2.63 Classify each compound as a Lewis base, a Bronsted-Lowry base, both, or neither.
a. b. c. d....Problem 68P:
2.64 Classify each species as a Lewis acid, a Bronsted-Lowry acid, both, or neither.
a. b. C. d....Problem 69P:
Label the Lewis acid and Lewis base in each reaction. Use curv ed arrows to show the movement of...Problem 70P:
2.66 Draw the products of each Lewis acid-base reaction. Label the electrophile and
nucleophile.
a....Problem 74P:
2.70 Hydroxide can react as a Brønsted-Lowry base (and remove a proton), or a
Lewis base (and...Browse All Chapters of This Textbook
Chapter 1 - Structure And BondingChapter 1.1 - The Periodic TableChapter 1.2 - BondingChapter 1.3 - Lewis StructuresChapter 1.4 - IsomersChapter 1.6 - ResonanceChapter 1.7 - Determining Molecular ShapeChapter 1.8 - Drawing Organic StructuresChapter 2 - Acids And BasesChapter 2.1 - Brønsted–lowry Acids And Bases
Chapter 2.2 - Reactions Of Brønsted–lowry Acids And BasesChapter 2.3 - Acid Strength And PkaChapter 2.4 - Predicting The Outcome Of Acid–base ReactionsChapter 2.5 - Factors That Determine Acid StrengthChapter 2.6 - Common Acids And BasesChapter 2.7 - AspirinChapter 2.8 - Lewis Acids And BasesChapter 3 - Introduction To Organic Molecules And Functional GroupsChapter 3.1 - Functional GroupsChapter 3.2 - An Overview Of Functional GroupsChapter 3.4 - Physical PropertiesChapter 3.5 - Application: VitaminsChapter 4 - AlkanesChapter 4.1 - Alkanes—an IntroductionChapter 4.2 - CycloalkanesChapter 4.4 - Naming AlkanesChapter 4.5 - Naming CycloalkanesChapter 4.8 - Properties Of AlkanesChapter 4.9 - Conformations Of Acyclic Alkanes—ethaneChapter 4.10 - Conformations Of ButaneChapter 4.12 - CyclohexaneChapter 4.13 - Substituted CycloalkanesChapter 4.14 - Oxidation Of AlkanesChapter 4.15 - Lipids—partChapter 5 - StereochemistryChapter 5.1 - Starch And CelluloseChapter 5.2 - The Two Major Classes Of IsomersChapter 5.3 - Looking Glass Chemistry—chiral And Achiral MoleculesChapter 5.6 - Labeling Stereogenic Centers With R Or SChapter 5.7 - DisastereomersChapter 5.8 - Meso CompoundsChapter 5.9 - R And S Assignments In Compounds With Two Or More Stereogenic CentersChapter 5.10 - Disubstituted CycloalkanesChapter 5.11 - Isomers—a SummaryChapter 5.12 - Physical Properties Of StereoisomersChapter 6 - Understanding Organic ReactionsChapter 6.2 - Kinds Of Organic ReactionsChapter 6.3 - Bond Breaking And Bond MakingChapter 6.4 - Bond Dissociation EnergyChapter 6.5 - ThermodynamicsChapter 6.6 - Enthalpy And EntropyChapter 6.7 - Energy DiagramsChapter 6.8 - Energy Diagram For A Two-step Reaction MechanismChapter 6.9 - KineticsChapter 6.10 - CatalystsChapter 7 - Alkyl Halides And Nucleophilic SubstitutionChapter 7.1 - Introduction To Alkyl HalidesChapter 7.2 - NomenclatureChapter 7.3 - Properties Of Alkyl HalidesChapter 7.4 - Interesting Alkyl HalidesChapter 7.6 - General Features Of Nucleophilic SubstitutionChapter 7.7 - The Leaving GroupChapter 7.8 - The NucleophileChapter 7.11 - The Sn2 MechanismChapter 7.12 - The Sn1 MechanismChapter 7.13 - Carbocation StabilityChapter 7.15 - When Is The Mechanism Sn1 Or Sn2?Chapter 8 - Alkyl Halides And Elimination ReactionsChapter 8.1 - General Features Of EliminationChapter 8.2 - Alkenes—the Products Of Elimination ReactionsChapter 8.4 - The E2 MechanismChapter 8.5 - The Zaitsev RuleChapter 8.6 - The E1 MechanismChapter 9 - Alcohols, Ethers, And Related CompoundsChapter 9.1 - IntroductionChapter 9.3 - NomenclatureChapter 9.6 - Preparation Of Alcohols, Ethers, And EpoxidesChapter 9.8 - Dehydration Of Alcohols To AlkenesChapter 9.11 - Conversion Of Alcohols To Alkyl Halides With HxChapter 9.12 - Conversion Of Alcohols To Alkyl Halides With Socl2 And Pbr3Chapter 9.13 - Tosylate—another Good Leaving GroupChapter 9.14 - Reaction Of Ethers With Strong AcidChapter 9.15 - Thiols And SulfidesChapter 9.16 - Reactions Of EpoxidesChapter 10 - Alkenes And Addition ReactionsChapter 10.1 - IntroductionChapter 10.2 - Calculating Degrees Of UnsaturationChapter 10.3 - NomenclatureChapter 10.6 - Lipids—partChapter 10.7 - Preparation Of AlkenesChapter 10.9 - Hydrohalogenation—electrophilic Addition Of HxChapter 10.10 - Markovnikov’s RuleChapter 10.11 - Stereochemistry Of Electrophilic Addition Of HxChapter 10.12 - Hydration—electrophilic Addition Of WaterChapter 10.13 - Halogenation—addition Of HalogenChapter 10.14 - Stereochemistry Of HalogenationChapter 10.15 - Halohydrin FormationChapter 10.16 - Hydroboration–oxidationChapter 10.17 - Keeping Track Of ReactionsChapter 10.18 - Alkenes In Organic SynthesisChapter 11 - Alkynes And SynthesisChapter 11.1 - IntroductionChapter 11.2 - NomenclatureChapter 11.3 - Properties Of AlkynesChapter 11.5 - Preparation Of AlkynesChapter 11.6 - Introduction To Alkyne ReactionsChapter 11.7 - Addition Of Hydrogen HalidesChapter 11.8 - Addition Of HalogenChapter 11.9 - Addition Of WaterChapter 11.10 - Hydroboration–oxidationChapter 11.11 - Reaction Of Acetylide AnionsChapter 12 - Oxidation And ReductionChapter 12.1 - IntroductionChapter 12.3 - Reduction Of AlkenesChapter 12.4 - Application: Hydrogenation Of OilsChapter 12.5 - Reduction Of AlkynesChapter 12.6 - The Reduction Of Polar C–x Σ BondsChapter 12.8 - EpoxidationChapter 12.9 - DihydroxylationChapter 12.10 - Oxidative Cleavage Of AlkenesChapter 12.11 - Oxidative Cleavage Of AlkynesChapter 12.12 - Oxidation Of AlcoholsChapter 12.13 - Green ChemistryChapter 12A - Mass SpectrometryChapter 12A.1 - Mass Spectrometry And The Molecular IonChapter 12A.2 - Alkyl Halides And The M + 2 PeakChapter 12A.3 - FragmentationChapter 12C - Nuclear Magnetic Resonance SpectroscopyChapter 12C.1 - An Introduction To Nmr SpectroscopyChapter 12C.2 - 1h Nmr: Number Of SignalsChapter 12C.3 - 1h Nmr: Position Of SignalsChapter 12C.4 - The Chemical Shifts Of Protons On Sp2 And Sp Hybridized CarbonsChapter 12C.5 - 1h Nmr: Intensity Of SignalsChapter 12C.6 - 1h Nmr: Spin–spin SplittingChapter 12C.7 - More-complex Examples Of SplittingChapter 12C.8 - Spin–spin Splitting In AlkenesChapter 12C.9 - Other Facts About 1h Nmr SpectroscopyChapter 12C.10 - Using 1h Nmr To Identify An UnknownChapter 13 - Radical ReactionsChapter 13.1 - IntroductionChapter 13.2 - General Features Of Radical ReactionsChapter 13.3 - Halogenation Of AlkanesChapter 13.4 - The Mechanism Of HalogenationChapter 13.5 - Chlorination Of Other AlkanesChapter 13.6 - Chlorination Versus BrominationChapter 13.7 - Halogenation As A Tool In Organic SynthesisChapter 13.8 - The Stereochemistry Of Halogenation ReactionsChapter 14 - Conjugation, Resonance, And DienesChapter 14.1 - ConjugationChapter 14.2 - Resonance And Allylic CarbocationsChapter 14.3 - Common Examples Of ResonanceChapter 14.4 - The Resonance HybridChapter 14.8 - The Carbon–carbon Σ Bond Length In Buta-1,3-dieneChapter 14.9 - Stability Of Conjugated DienesChapter 14.10 - Electrophilic Addition: 1,2- Versus 1,4-additionChapter 14.11 - Kinetic Versus Thermodynamic ProductsChapter 14.12 - The Diels–alder ReactionChapter 15 - Benzene And Aromatic CompoundsChapter 15.2 - The Structure Of BenzeneChapter 15.3 - Nomenclature Of Benzene DerivativesChapter 15.6 - Benzene’s Unusual StabilityChapter 15.8 - Examples Of Aromatic CompoundsChapter 16 - Reactions Of Aromatic CompoundsChapter 16.1 - Electrophilic Aromatic SubstitutionChapter 16.2 - The General MechanismChapter 16.3 - HalogenationChapter 16.4 - Nitration And SulfonationChapter 16.5 - Friedel–crafts Alkylation And Friedel–crafts AcylationChapter 16.6 - Substituted BenzenesChapter 16.7 - Electrophilic Aromatic Substitution Of Substituted BenzenesChapter 16.9 - Orientation Effects In Substituted BenzenesChapter 16.10 - Limitations On Electrophilic Substitution Reactions With Substituted BenzenesChapter 16.11 - Disubstituted BenzenesChapter 16.12 - Synthesis Of Benzene DerivativesChapter 16.13 - Nucleophilic Aromatic SubstitutionChapter 17 - Introduction To Carbonyl Chemistry; Organometallic Reagents; Oxidation And ReductionChapter 17.1 - IntroductionChapter 17.2 - General Reactions Of Carbonyl CompoundsChapter 17.4 - Reduction Of Aldehydes And KetonesChapter 17.5 - The Stereochemistry Of Carbonyl ReductionChapter 17.7 - Reduction Of Carboxylic Acids And Their DerivativesChapter 17.8 - Oxidation Of AldehydesChapter 17.9 - Organometallic ReagentsChapter 17.10 - Reaction Of Organometallic Reagents With Aldehydes And KetonesChapter 17.11 - Retrosynthetic Analysis Of Grignard ProductsChapter 17.12 - Protecting GroupsChapter 17.13 - Reaction Of Organometallic Reagents With Carboxylic Acid DerivativesChapter 17.14 - Reaction Of Organometallic Reagents With Other CompoundsChapter 18 - Aldehydes And Ketones—nucleophilic AdditionChapter 18.1 - IntroductionChapter 18.2 - NomenclatureChapter 18.5 - Preparation Of Aldehydes And KetonesChapter 18.9 - The Wittig ReactionChapter 18.10 - Addition Of 1° AminesChapter 18.11 - Addition Of 2° AminesChapter 18.12 - Addition Of H2o—hydrationChapter 18.13 - Addition Of Alcohols—acetal FormationChapter 20 - Carboxylic Acids And Their Derivatives—nucleophilic Acyl SubstitutionChapter 20.1 - IntroductionChapter 20.2 - Structure And BondingChapter 20.3 - NomenclatureChapter 20.4 - Physical And Spectroscopic PropertiesChapter 20.7 - Reactions Of Acid ChloridesChapter 20.8 - Reactions Of AnhydridesChapter 20.9 - Reactions Of Carboxylic AcidsChapter 20.10 - Reactions Of EstersChapter 21 - Substitution Reactions Of Carbonyl Compounds At The α CarbonChapter 21.2 - EnolsChapter 21.3 - EnolatesChapter 21.4 - Enolates Of Unsymmmetrical Carbonyl CompoundsChapter 21.5 - Racemization At The α CarbonChapter 21.7 - Halogenation At The α CarbonChapter 21.8 - Direct Enolate AlkylationChapter 21.9 - Malonic Ester SynthesisChapter 21.10 - Acetoacetic Ester SynthesisChapter 22 - Carbonyl Condensation ReactionsChapter 22.1 - The Aldol ReactionChapter 22.2 - Crossed Aldol ReactionsChapter 22.4 - Intramolecular Aldol ReactionsChapter 22.5 - The Claisen ReactionChapter 22.6 - The Crossed Claisen And Related ReactionsChapter 22.7 - The Dieckmann ReactionChapter 22.8 - The Michael ReactionChapter 23 - AminesChapter 23.2 - Structure And BondingChapter 23.3 - NomenclatureChapter 23.4 - Physical And Spectroscopic PropertiesChapter 23.6 - Preparation Of AminesChapter 23.8 - Amines As BasesChapter 23.9 - Relative Basicity Of Amines And Other CompoundsChapter 23.10 - Amines As NucleophilesChapter 23.11 - Hofmann EliminationChapter 23.12 - Reactions Of Amines With Nitrous AcidChapter 23.13 - Substitution Reactions Of Aryl Diazonium SaltsChapter 24 - Carbon–carbon Bond-forming Reactions In Organic SynthesisChapter 24.1 - Coupling Reactions Of Organocuprate ReagentsChapter 24.2 - Suzuki ReactionChapter 24.4 - Carbenes And Cyclopropane SynthesisChapter 24.5 - Simmons–smith ReactionChapter 24.6 - MetathesisChapter 25 - Pericyclic ReactionsChapter 25.1 - Types Of Pericyclic ReactionsChapter 25.2 - Molecular OrbitalsChapter 25.3 - Electrocyclic ReactionsChapter 25.4 - Cycloaddition ReactionsChapter 25.5 - Sigmatropic RearrangementsChapter 25.6 - Summary Of Rules For Pericyclic ReactionsChapter 26 - CarbohydratesChapter 26.2 - MonosaccharidesChapter 26.3 - The Family Of D-aldosesChapter 26.4 - The Family Of D-ketosesChapter 26.6 - The Cyclic Forms Of MonosaccharidesChapter 26.7 - GlycosidesChapter 26.8 - Reactions Of Monosaccharides At The Oh GroupsChapter 26.9 - Reactions At The Carbonyl Group—oxidation And ReductionChapter 26.10 - Reactions At The Carbonyl Group—adding Or Removing One Carbon AtomChapter 26.11 - DisaccharidesChapter 26.12 - PolysaccharidesChapter 26.13 - Other Important Sugars And Their DerivativesChapter 27 - Amino Acids And ProteinsChapter 27.1 - Amino AcidsChapter 27.2 - Synthesis Of Amino AcidsChapter 27.3 - Separation Of Amino AcidsChapter 27.4 - Enantioselective Synthesis Of Amino AcidsChapter 27.5 - PeptidesChapter 28 - Synthetic PolymersChapter 28.1 - IntroductionChapter 28.2 - Chain-growth Polymers—addition PolymersChapter 28.3 - Anionic Polymerization Of EpoxidesChapter 28.5 - Natural And Synthetic RubbersChapter 28.6 - Step-growth Polymers—condensation PolymersChapter 28.7 - Polymer Structure And PropertiesChapter 28.8 - Green Polymer SynthesisChapter 28.9 - Polymer Recycling And DisposalChapter 29 - Lipids 1292 (available Online)Chapter 29.2 - WaxesChapter 29.3 - TriacylglycerolsChapter 29.7 - TerpenesChapter 29.8 - Steroids
Sample Solutions for this Textbook
We offer sample solutions for ORGANIC CHEMISTRY W/ALEKS homework problems. See examples below:
Chapter 1, Problem 40PChapter 2, Problem 36PChapter 3, Problem 31PChapter 4, Problem 34PThe given ball-and-stick model of ezetimibe is shown below. Figure 1 In the ball-and-stick model of...Chapter 6, Problem 26PChapter 7, Problem 39PChapter 8, Problem 24PChapter 9, Problem 36P
Chapter 10, Problem 32PChapter 12, Problem 28PChapter 12A, Problem 15PChapter 12C, Problem 36PThe compounds with same chemical formula but have different arrangement of atoms in space is known...Chapter 15, Problem 20PIn the given ball and stick model of A and B, black balls represent carbon atoms, white balls...Chapter 18, Problem 37PChapter 21, Problem 30PThe given ball and stick model of the pair of compounds is shown as, Figure 1 According to the given...The given compound A is, Figure 3 Black coloured atoms have four bonds. So, these are the carbon...Chapter 26, Problem 36PChapter 27, Problem 27PThe given molecule is Figure 1 The blue coloured ball has three bonds. So, this is the nitrogen...Chapter 29, Problem 18P
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