Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 7.12, Problem 23P

What happens to the rate of an S N 1 reaction under each of the following conditions?

a. [ RX ] is tripled, and [ Nu ] stays the same.

b. Both [ RX ] and [ Nu ] are tripled.

c. [ RX ] is halved, and [ Nu ] stays the same.

d. [ RX ] is halved, and [ Nu ] is doubled.

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1. The reaction shown below has a rate law equation of rate = k[PtL3X+]. What would happen to the rate if the concentration of both [PtL3X]+ and Y- are doubled?  A.There will be no change in the rate.  B.The rate will be halved. C.The rate will be doubled. D.The rate will be quadrupled.
The rate equation for the reaction of CH3CH2Br with −OH is: rate = k[CH3CH2Br][−OH]. What effect does the indicated concentration change have on the overall rate of the reaction? a. tripling the concentration of CH3CH2Br only b. tripling the concentration of −OH only c. tripling the concentration of both CH3CH2Br and −OH
8. Given the following rate law, how does the rate of reaction change if the concentration of Y is doubled? Rate = k [X][Y]² A. The rate of reaction will increase by a factor of 2. B. The rate of reaction will increase by a factor of 4. C. The rate of reaction will increase by a factor of 5. D. The rate of reaction will decrease by a factor of 2. E. The rate of reaction will remain unchanged.

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Organic Chemistry (6th Edition)

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