Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Textbook Question
Chapter 7.12, Problem 24P
Draw the products of each SN1 reaction and indicate the stereochemistry of any stereogenic centers.
a. 
b. 
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The table includes macrostates characterized by 4 energy levels (&) that are
equally spaced but with different degrees of occupation.
a) Calculate the energy of all the macrostates (in joules). See if they all have
the same energy and number of particles.
b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
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In an experiment, the viscosity of water was measured at different
temperatures and the table was constructed from the data obtained.
a) Calculate the activation energy of viscous flow (kJ/mol).
b) Calculate the viscosity at 30°C.
T/°C
0
20
40
60
80
η/cpoise 1,972 1,005 0,656 0,469 0,356
Chapter 7 Solutions
Organic Chemistry (6th Edition)
Ch. 7.1 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7.2 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7.2 - Prob. 3PCh. 7.3 - An sp3 hybridized CCl bond is more polar than an...Ch. 7.4 - Prob. 5PCh. 7.6 - Prob. 6PCh. 7.7 - Prob. 10PCh. 7.8 - Prob. 15PCh. 7.8 - Prob. 16PCh. 7.8 - Prob. 17P
Ch. 7.11 - Prob. 18PCh. 7.11 - Prob. 19PCh. 7.11 - Draw the product of each SN2 reaction and indicate...Ch. 7.11 - Prob. 21PCh. 7.11 - Prob. 22PCh. 7.12 - What happens to the rate of an SN1 reaction under...Ch. 7.12 - Draw the products of each SN1 reaction and...Ch. 7.13 - Classify each carbocation as 1,2, or 3. a. b. c....Ch. 7.15 - Problem 7.30 For each alkyl halide and...Ch. 7.15 - Prob. 30PCh. 7.15 - Prob. 31PCh. 7.15 - Prob. 32PCh. 7.15 - Prob. 33PCh. 7.15 - Prob. 34PCh. 7 - Give the IUPAC name for each compound, including...Ch. 7 - Draw the products of each nucleophilic...Ch. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - 7.53 Consider the following reaction.
Draw a...Ch. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Consider the following SN1 reaction. a.Draw a...Ch. 7 - 7.59 Pick the reactant or solvent in each part...Ch. 7 - Draw the products of each SN1 reaction and...Ch. 7 - Prob. 62PCh. 7 - Prob. 63PCh. 7 - Draw a stepwise, detailed mechanism for the...Ch. 7 - When a single compound contains both a nucleophile...Ch. 7 - Prob. 69PCh. 7 - Prob. 70PCh. 7 - Draw a stepwise, detailed mechanism f or the...Ch. 7 - Prob. 72PCh. 7 - Prob. 78P
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