Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 7, Problem 62P
Interpretation Introduction

Interpretation: A stepwise mechanism of the given reaction is to be drawn and an explanation corresponding to the statement that 1-bromohex-2-ene reacts rapidly with a weak nucleophile (CH3OH) under SN1 reaction conditions, even though it is a 1° alkyl halide, is to be stated.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

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1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction. 2600 2400 2200 2000 1800 1600 1400 1200 1000 800 Potential Energy (kJ) 600 400 200 0 -200- -400 -600- -800 (i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s) (ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s) Ea = 1550 kJ Ea = 2240 kJ (iii) Cl (g) + CICO (g) → Cl₂CO (g) Ea = 2350 kJ AH=-950 kJ ΔΗ = 575 ΚΙ AH=-825 kJ a. Draw the potential energy diagram for the reaction. Label the data points for clarity. The potential energy of the reactants is 600 kJ Reaction Progress b. What is the overall chemical equation? c. What is the overall change in enthalpy for the above chemical reaction? d. What is the overall amount of activation energy for the above chemical reaction? e. Which reaction intermediate would be considered a catalyst (if any) and why? f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would you be able to make the reaction reverse itself (i.e. have…

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Organic Chemistry (6th Edition)

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