Concept explainers
(a)
Interpretation: The diene that has the larger heat of hydrogenation is to be identified.
Concept introduction: Diene is a hydrocarbon that contains two
Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.
The example that shows the basic difference between conjugated diene and isolated diene is shown below.
Figure 1
The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.
(b)
Interpretation: The diene that has the larger heat of hydrogenation is to be identified.
Concept introduction: Diene is a hydrocarbon that contains two
Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.
The example that shows the basic difference between conjugated diene and isolated diene is shown below.
Figure 1
The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.
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Chapter 14 Solutions
Organic Chemistry (6th Edition)
- Identify the missing organic reactants in the following reaction: X + Y H+ two steps Note: This chemical equation only focuses on the important organic molecules in the reaction. Additional inorganic or small-molecule reactants or products (like H2O) are not shown. In the drawing area below, draw the skeletal ("line") structures of the missing organic reactants X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. Х :arrow_forwardDraw the mechanism of friedel-crafts acylation using acetyl chloride of m-Xylenearrow_forwardI need help naming these in IUPACarrow_forward
- H R Part: 1/2 :CI: is a/an electrophile Part 2 of 2 Draw the skeletal structure of the product(s) for the Lewis acid-base reaction. Include lone pairs and formal charges (if applicable) on the structures. 4-7: H ö- H Skip Part Check X :C1: $ % L Fi Click and drag to start drawing a structure. MacBook Pro & ㅁ x G 0: P Add or increase positive formal cha Save For Later Submit ©2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centearrow_forwardDraw the friedel-crafts acylation mechanism of m-Xylenearrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
- 1. Base on this experimental results, how do you know that the product which you are turning in is methyl 3-nitrobenzoate(meta substituted product ) rather than either of the other two products? 2. What observation suggests that at least a small amount of one or both of the other two isomers are in the mother liquor?arrow_forwardExplain Huckel's rule.arrow_forwardhere is my question can u help me please!arrow_forward
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