Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 14, Problem 47P
Interpretation Introduction

(a)

Interpretation: The given products is to be labeled as 1,2product and 1,4product.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound. Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

Interpretation Introduction

(b)

Interpretation: The given products are to be labeled as kinetic and thermodynamic product.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound. Conjugated diene consists of two double bonds that are separated by a single bond.

Interpretation Introduction

(c)

Interpretation: The reason as to why addition of HCl occurs at the indicated C=C (called an exocyclic double bond), rather than the other C=C (called an endocyclic double bond) is to be explained.

Concept introduction: The reaction of hydrogen halide with alkene results in the formation of alkyl halide. This type of reaction is an electrophilic addition of hydrogen halide.

Electrophilic addition reactions are those in which breaking of pi bond take place to form new sigma bond.

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