(a) Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability. Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure. The delocalization of electrons results in the formation resonance structure.

Question

6. Match each of the lettered items in the column on the left with the most appropriate numbered item(s) in the column on the right. Some of the numbered items may be used more than once and some not at all. a. Z = 37 1. b. Mn 2. C. Pr element in period 5 and group 14 element in period 5 and group 15 d. S e. [Rn] 7s¹ f. d block metal 3. highest metallic character of all the elements 4. paramagnetic with 5 unpaired electrons 5. 4f36s2 6. isoelectronic with Ca²+ cation 7. an alkaline metal 8. an f-block element

Answer 1

Question

Chapter 14.4, Problem 7P

Interpretation Introduction

(a)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(b)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(c)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(d)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

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6. Match each of the lettered items in the column on the left with the most appropriate numbered item(s) in the column on the right. Some of the numbered items may be used more than once and some not at all. a. Z = 37 1. b. Mn 2. C. Pr element in period 5 and group 14 element in period 5 and group 15 d. S e. [Rn] 7s¹ f. d block metal 3. highest metallic character of all the elements 4. paramagnetic with 5 unpaired electrons 5. 4f36s2 6. isoelectronic with Ca²+ cation 7. an alkaline metal 8. an f-block element

Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.

Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1

Answer 2

Question

Chapter 14.4, Problem 7P

Interpretation Introduction

(a)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(b)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(c)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(d)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

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Answer 3

Question

Chapter 14.4, Problem 7P

Interpretation Introduction

(a)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(b)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(c)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(d)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

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Answer 4

Question

Chapter 14.4, Problem 7P

Interpretation Introduction

(a)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(b)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(c)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(d)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

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Answer 5

Chapter 14.4, Problem 7P

Interpretation Introduction

(a)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(b)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(c)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Interpretation Introduction

(d)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Answer 6

Chapter 14.4, Problem 7P

Interpretation Introduction

(a)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Answer 7

Chapter 14.4, Problem 7P

Interpretation Introduction

(a)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Answer 8

Interpretation Introduction

(b)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Answer 9

Interpretation Introduction

(b)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Answer 10

Interpretation Introduction

(c)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Answer 11

Interpretation Introduction

(c)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Answer 12

Interpretation Introduction

(d)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Answer 13

Interpretation Introduction

(d)

Interpretation: The second resonance structure for given species and its hybrid is to be drawn. The two resonance structure and the hybrid are to be ranked in order of increasing stability.

Concept introduction: Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. These resonance structure combine together to give resonance hybrid that is lower in energy and is the most stable structure.

The delocalization of electrons results in the formation resonance structure.

Answer 14

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Ch. 14.1 - Prob. 2P Ch. 14.2 - Problem 16.3 Draw a second resonance structure for...Ch. 14.2 - Prob. 4P Ch. 14.2 - Problem 16.5 Farnesyl diphosphate is synthesized...Ch. 14.3 - Prob. 6P Ch. 14.4 - Prob. 7P Ch. 14.4 - Prob. 8P Ch. 14.8 - Problem 16.12 Using hybridization, predict how the...Ch. 14.8 - Problem 16.13 Use resonance theory to explain why...Ch. 14.9 - Prob. 15P

Solution Summary: The author illustrates how the second resonance structure for given species and its hybrid is to be drawn.

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