(a) Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated. Concept introduction: The strong nucleophiles that open epoxide ring are − OH, − OR , − CN, − SR, HC ≡ C − , and NH 3 . The reaction takes place through an S N 2 mechanism. The mechanism of overall reaction involves two steps.

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Answer 1

Question

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

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Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.

Answer 2

Question

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

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Answer 3

Question

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

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Answer 4

Question

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

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Answer 5

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Answer 6

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Answer 7

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 9.1 - Problem 9.1 Label each ether and alcohol in...Ch. 9.3 - Give the IUPAC name for each compound.Ch. 9.3 - Problem 9.3 Give the structure corresponding to...Ch. 9.3 - Name each of the following ethers.Ch. 9.3 - Name each epoxide. a. (two ways) b. c. (two...Ch. 9.6 - Problem 9.8 Draw the organic product of each...Ch. 9.6 - Prob. 9P Ch. 9.6 - Problem 9.10 Draw the products of each reaction. ...Ch. 9.8 - Problem 9.11 Draw the products formed when each...Ch. 9.8 - Prob. 12P

Solution Summary: The author explains that the product of given reaction is drawn and the stereochemistry at any stereogenic center is indicated.

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